Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents

doi:10.1016/j.cjche.2021.04.031

中国化学工程学报 ›› 2022, Vol. 44 ›› Issue (4): 205-211.DOI: 10.1016/j.cjche.2021.04.031

Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents

Linlan Wu¹, Zhengxin Jiao², Suhang Xun², Minqiang He¹, Lei Fan³, Chao Wang², Wenshu Yang¹, Wenshuai Zhu¹, Huaming Li¹

1 School of Chemistry and Chemical Engineering, Institute for Energy Research, Jiangsu University, Zhenjiang 212013, China;
2 School of Environment and Safety Engineering, Institute of Environmental Health and Ecological Security, Jiangsu University, Zhenjiang 212013, China;
3 School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

收稿日期:2021-01-29 修回日期:2021-04-18 出版日期:2022-04-28 发布日期:2022-06-18
通讯作者: Minqiang He,E-mail:hemq@ujs.edu.cn;Wenshuai Zhu,E-mail:zhuws@ujs.edu.cn
基金资助:
This work was financially supported by the National Natural Science Foundation of China (No. 21808091), Natural Science Foundation of Jiangsu Province (Nos. BK20200896, BK20190243), Key Laboratory of Tropical Medicinal Plant Chemistry of Ministry of Education, Hainan Normal University (20150376), China Postdoctoral Foundation (No. 2020M671365), and the Student Innovation and Entrepreneurship Training Program (202010299457X).

Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents

Linlan Wu¹, Zhengxin Jiao², Suhang Xun², Minqiang He¹, Lei Fan³, Chao Wang², Wenshu Yang¹, Wenshuai Zhu¹, Huaming Li¹

1 School of Chemistry and Chemical Engineering, Institute for Energy Research, Jiangsu University, Zhenjiang 212013, China;
2 School of Environment and Safety Engineering, Institute of Environmental Health and Ecological Security, Jiangsu University, Zhenjiang 212013, China;
3 School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Received:2021-01-29 Revised:2021-04-18 Online:2022-04-28 Published:2022-06-18
Contact: Minqiang He,E-mail:hemq@ujs.edu.cn;Wenshuai Zhu,E-mail:zhuws@ujs.edu.cn
Supported by:
This work was financially supported by the National Natural Science Foundation of China (No. 21808091), Natural Science Foundation of Jiangsu Province (Nos. BK20200896, BK20190243), Key Laboratory of Tropical Medicinal Plant Chemistry of Ministry of Education, Hainan Normal University (20150376), China Postdoctoral Foundation (No. 2020M671365), and the Student Innovation and Entrepreneurship Training Program (202010299457X).

摘要/Abstract

摘要： A series of novel binary deep eutectic solvents (DESs) composed of choline chloride (ChCl) and formic acid (HCOOH) with different molar ratios have been successfully synthesized and applied in extractive desulfurization (EDS). Keggin-type polyoxometallate ionic liquid [TTPh]₃PW₁₂O₄₀ was prepared and used as catalyst to enhance the EDS capacity by means of photocatalytic oxidative process. Both of the DESs and [TTPh]₃PW₁₂O₄₀ ionic liquid catalyst were characterized in detail by Fourier transform infrared spectroscopy spectra (FT-IR), elemental analysis, and X-ray photoelectron spectroscopy (XPS). It was found that the molar ratios of ChCl:HCOOH had a major impact on desulfurization performance, and the optimal desulfurization capacity 96.5% was obtained by ChCl/5HCOOH. Besides dibenzothiophene (DBT), the desulfurization efficiencies of 4-methylbenzothiophene (4-MDBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT), two kinds of DBT derivatives, were also investigated under the same experimental conditions. Moreover, the free radical scavenging experiments manifested that superoxide radical (·O₂^-) and hole (h⁺) played important roles in the desulfurization system. After further analysis of the oxidation products by gas chromatography-mass spectrometry (GC–MS), the possible reaction mechanism was proposed. Thus, photocatalytic oxidative has been proved to be one of the efficient approaches for enhancing the extractive desulfurization performance in DES.

关键词: Deep eutectic solvents, Extractive desulfurization, Ionic liquid, Photocatalytic oxidative, Aerobic, Fuel

Abstract: A series of novel binary deep eutectic solvents (DESs) composed of choline chloride (ChCl) and formic acid (HCOOH) with different molar ratios have been successfully synthesized and applied in extractive desulfurization (EDS). Keggin-type polyoxometallate ionic liquid [TTPh]₃PW₁₂O₄₀ was prepared and used as catalyst to enhance the EDS capacity by means of photocatalytic oxidative process. Both of the DESs and [TTPh]₃PW₁₂O₄₀ ionic liquid catalyst were characterized in detail by Fourier transform infrared spectroscopy spectra (FT-IR), elemental analysis, and X-ray photoelectron spectroscopy (XPS). It was found that the molar ratios of ChCl:HCOOH had a major impact on desulfurization performance, and the optimal desulfurization capacity 96.5% was obtained by ChCl/5HCOOH. Besides dibenzothiophene (DBT), the desulfurization efficiencies of 4-methylbenzothiophene (4-MDBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT), two kinds of DBT derivatives, were also investigated under the same experimental conditions. Moreover, the free radical scavenging experiments manifested that superoxide radical (·O₂^-) and hole (h⁺) played important roles in the desulfurization system. After further analysis of the oxidation products by gas chromatography-mass spectrometry (GC–MS), the possible reaction mechanism was proposed. Thus, photocatalytic oxidative has been proved to be one of the efficient approaches for enhancing the extractive desulfurization performance in DES.

Key words: Deep eutectic solvents, Extractive desulfurization, Ionic liquid, Photocatalytic oxidative, Aerobic, Fuel

Linlan Wu, Zhengxin Jiao, Suhang Xun, Minqiang He, Lei Fan, Chao Wang, Wenshu Yang, Wenshuai Zhu, Huaming Li. Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents[J]. 中国化学工程学报, 2022, 44(4): 205-211.

参考文献

[1] M. Zhang, J.Q. Liu, H.P. Li, Y.C. Wei, Y.J. Fu, W.Y. Liao, L.H. Zhu, G.Y. Chen, W.S. Zhu, H.M. Li, Tuning the electrophilicity of vanadium-substituted polyoxometalate based ionic liquids for high-efficiency aerobic oxidative desulfurization, Appl. Catal. B:Environ., 271 (2020) 118936
[2] M.Y. Chi, T. Su, L.L. Sun, Z.G. Zhu, W.P. Liao, W.Z. Ren, Y.C. Zhao, H.Y. Lü, Biomimetic oxygen activation and electron transfer mechanism for oxidative desulfurization, Appl. Catal. B:Environ., 275 (2020) 119134
[3] G.J. Yang, J. Han, Y. Liu, Z.Y. Qiu, X.X. Chen, The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions, Chin. J. Chem. Eng., 28 (2020) 2227-2234
[4] W. Jiang, K. Zhu, H.P. Li, L.H. Zhu, M.Q. Hua, J. Xiao, C. Wang, Z.Z. Yang, G.Y. Chen, W.S. Zhu, H.M. Li, S. Dai, Synergistic effect of dual Brønsted acidic deep eutectic solvents for oxidative desulfurization of diesel fuel, Chem. Eng. J., 394 (2020) 124831
[5] G. Ye, Y.L. Gu, W. Zhou, W. Xu, Y.Y. Sun, Synthesis of defect-rich titanium terephthalate with the assistance of acetic acid for room-temperature oxidative desulfurization of fuel oil, ACS Catal., 10 (2020) 2384-2394
[6] X.Q. Zhao, C.F. Yang, M.K. Lu, Y. Shi, G. Qian, X.G. Zhou, X.Z. Duan, Coupling non-isothermal trickle-bed reactor with catalyst pellet models to understand the reaction and diffusion in gas oil hydrodesulfurization, Chin. J. Chem. Eng., 28 (2020) 1095-1106
[7] S.H. Xun, Q.T. Ti, L.L. Wu, M.Q. He, C. Wang, L.L. Chen, W.S. Yang, L.H. Zhu, W.S. Zhu, H.M. Li, Few layer g-C₃N₄ dispersed quaternary phosphonium ionic liquid for highly efficient catalytic oxidative desulfurization of fuel, Energ. Fuel., 34 (2020) 12379-12387
[8] M. Zhang, J.Q. Liu, J.P. Yang, X. Chen, M. Wang, H.P. Li, W.S. Zhu, H.M. Li, Molybdenum-containing dendritic mesoporous silica spheres for fast oxidative desulfurization in fuel, Inorg. Chem. Front., 6 (2019) 451-458
[9] M.A. Rezvani, S. Khandan, N. Sabahi, H. Saeidian, Deep oxidative desulfurization of gas oil based on sandwich-type polysilicotungstate supported beta-cyclodextrin composite as an efficient heterogeneous catalyst, Chin. J. Chem. Eng., 27 (2019) 2418-2426
[10] K.X. Lee, H. Wang, S. Karakalos, G. Tsilomelekis, J.A. Valla, Adsorptive desulfurization of 4,6-dimethyldibenzothiophene on bimetallic mesoporous Y zeolites:Effects of Cu and Ce composition and configuration, Ind. Eng. Chem. Res., 58 (2019) 18301-18312
[11] J.W. Wang, Z. Song, X.X. Li, H.Y. Cheng, L.F. Chen, Z.W. Qi, Toward rational functionalization of ionic liquids for enhanced extractive desulfurization:Computer-aided solvent design and molecular dynamics simulation, Ind. Eng. Chem. Res., 59 (2020) 2093-2103
[12] P.I. Cano, J. Brito, F. Almenglo, M. Ramírez, J.M. Gómez, D. Cantero, Influence of trickling liquid velocity, low molar ratio of nitrogen/sulfur and gas-liquid flow pattern in anoxic biotrickling filters for biogas desulfurization, Biochem. Eng. J., 148 (2019) 205-213
[13] N.X. Lv, L.H. Sun, L.L. Chen, Y.J. Li, J.R. Zhang, P.W. Wu, H.P. Li, W.S. Zhu, H.M. Li, The mechanism of thiophene oxidation on metal-free two-dimensional hexagonal boron nitride, Phys. Chem. Chem. Phys., 21 (2019) 21867-21874
[14] H. Lee, S. Kang, Y. Jin, D. Jung, K. Park, K. Li, J. Lee, Systematic investigation of the extractive desulfurization of fuel using deep eutectic solvents from multifarious aspects, Fuel, 264 (2020) 116848
[15] Y.F. Guo, C.Y. Gao, K.G. Yang, Z.J. Wang, Y.H. Duan, S.X. Feng, H. Xu, Mild and deep oxidative extraction desulfurization using dual-function imidazolium peroxydisulfate ionic liquid, Energ. Fuel., 33 (2019) 10728-10733
[16] A.S. Morshedy, S.M. Taw, K.M. Hashem, D.M. Abd El-Aty, A.A. Galhoum, M.S. Mostafa, E. Guibal, The production of clean diesel fuel by facile sun light photocatalytic desulfurization process using Cd-based diacetate as a novel liquid photocatalyst, Journal of Cleaner Production, 279 (2021) 123629
[17] S.H. Xun, Q.T. Ti, Z.X. Jiao, L.L. Wu, M.Q. He, L.L. Chen, L.H. Zhu, W.S. Zhu, H.M. Li, Dispersing TiO₂ nanoparticles on graphite carbon for an enhanced catalytic oxidative desulfurization performance, Ind. Eng. Chem. Res., 59 (2020) 18471-18479
[18] N. Ghorbani, G. Moradi, Oxidative desulfurization of model and real oil samples using Mo supported on hierarchical alumina-silica:Process optimization by Box-Behnken experimental design, Chin. J. Chem. Eng., 27 (2019) 2759-2770
[19] J.L. Wang, D.S. Zhao, K.X. Li, Oxidative desulfurization of dibenzothiophene using ozone and hydrogen peroxide in ionic liquid, Energ. Fuel., 24 (2010) 2527-2529
[20] S.H. Xun, W. Jiang, T. Guo, M.Q. He, R.L. Ma, M. Zhang, W.S. Zhu, H.M. Li, Magnetic mesoporous nanospheres supported phosphomolybdate-based ionic liquid for aerobic oxidative desulfurization of fuel, J. Colloid Interface Sci., 534 (2019) 239-247
[21] M. Masoomi, M. Bagheri, A. Morsali, Application of two cobalt-based metal-organic frameworks as oxidative desulfurization catalysts, Inorg. Chem., 54 (2015) 11269-11275
[22] C. Wang, W. Jiang, H.X. Chen, L.H. Zhu, J. Luo, W.S. Yang, G.Y. Chen, Z.G. Chen, W.S. Zhu, H.M. Li, Pt nanoparticles encapsulated on V₂O₅ nanosheets carriers as efficient catalysts for promoted aerobic oxidative desulfurization performance, Chinese J. Catal., 42 (2021) 557-562
[23] X.W. Lu, X.Z. Li, J.C. Qian, N.M. Miao, C. Yao, Z.G. Chen, Synthesis and characterization of CeO₂/TiO₂ nanotube arrays and enhanced photocatalytic oxidative desulfurization performance, J. Alloys Compd., 661 (2016) 363-371
[24] X.Z. Li, W. Zhu, X.W. Lu, S.X. Zuo, C. Yao, C.Y. Ni, Integrated nanostructures of CeO₂/attapulgite/g-C₃N₄ as efficient catalyst for photocatalytic desulfurization:Mechanism, kinetics and influencing factors, Chem. Eng. J., 326 (2017) 87-98
[25] G. Zhang, J.J. Ren, B.L. Liu, M. Tian, H.W. Zhou, J.S. Zhao, In situ hydrothermal preparation and photocatalytic desulfurization performance of metallophthalocyanine sensitized SnO₂, Inorg. Chim. Acta, 471 (2018) 782-787
[26] C.J. Clarke, W.-C. Tu, O. Levers, A. Bröhl, J.P. Hallett, Green and sustainable solvents in chemical processes, Chem. Rev., 118 (2018) 747-800
[27] A.P. Abbott, G. Capper, D.L. Davies, R.K. Rasheed, V. Tambyrajah, Novel solvent properties of choline chloride/urea mixtures, Chem. Commun., 9 (2003) 70-71
[28] S.C. Cunha, J.O. Fernandes, Extraction techniques with deep eutectic solvents, TrAC Trends in Analytical Chemistry, 105 (2018) 225-239
[29] L.L. Sun, T. Su, J.J. Xu, D.M. Hao, W.P. Liao, Y.C. Zhao, W.Z. Ren, C.L. Deng, H.Y. Lü, Aerobic oxidative desulfurization coupling of Co polyanion catalysts and p-TsOH-based deep eutectic solvents through a biomimetic approach, Green Chem., 21 (2019) 2629-2634
[30] J.J. Xu, Z.G. Zhu, T. Su, W.P. Liao, C.L. Deng, D.M. Hao, Y.C. Zhao, W.Z. Ren, H.Y. Lü, Green aerobic oxidative desulfurization of diesel by constructing an Fe-Anderson type polyoxometalate and benzene sulfonic acid-based deep eutectic solvent biomimetic cycle, Chinese J. Catal., 41 (2020) 868-876
[31] N. Pasha, N. Lingaiah, R. Shiva, Zirconium exchanged phosphotungstic acid catalysts for esterification of levulinic acid to ethyl levulinate, Catal. Lett., 149 (2019) 2500-2507
[32] G.W. Wang, Y.B. Shen, X.L. Wu, L. Wang, Solvent-free hydroalkylation of olefins with 1,3-diketones catalyzed by phosphotungstic acid, Tetrahedron Lett., 49 (2008) 5090-5093
[33] K.X. Li, L.S. Yan, Z.X. Zeng, S.L. Luo, X.B. Luo, X.M. Liu, H.Q. Guo, Y.H. Guo, Fabrication of H₃PW₁₂O₄₀-doped carbon nitride nanotubes by one-step hydrothermal treatment strategy and their efficient visible-light photocatalytic activity toward representative aqueous persistent organic pollutants degradation, Appl. Catal. B:Environ., 156-157 (2014) 141-152
[34] L. Duan, L.L. Dou, L. Guo, P. Li, E.H. Liu, Comprehensive evaluation of deep eutectic solvents in extraction of bioactive natural products, ACS Sustain. Chem. Eng., 4 (2016) 2405-2411
[35] C. Wang, Y.K. Yi, H.P. Li, P.W. Wu, M.T. Li, W. Jiang, Z.G. Chen, H.M. Li, W.S. Zhu, S. Dai, Rapid gas-assisted exfoliation promises V₂O₅ nanosheets for high performance lithium-sulfur batteries, Nano Energy, 67 (2020) 104253
[36] W.S. Zhu, C. Wang, H.P. Li, P.W. Wu, S.H. Xun, W. Jiang, Z.G. Chen, Z. Zhao, H.M. Li, One-pot extraction combined with metal-free photochemical aerobic oxidative desulfurization in deep eutectic solvent, Green Chem., 17 (2015) 2464-2472
[37] W. Jiang, H. Jia, H.P. Li, L.H. Zhu, R.M. Tao, W.S. Zhu, H.M. Li, S. Dai, Boric acid-based ternary deep eutectic solvent for extraction and oxidative desulfurization of diesel fuel, Green Chem., 21 (2019) 3074-3080
[38] P.D. Muley, J.K. Mobley, X.J. Tong, B. Novak, J. Stevens, D. Moldovan, J. Shi, D. Boldor, Rapid microwave-assisted biomass delignification and lignin depolymerization in deep eutectic solvents, Energ. Conversion Manage., 196 (2019) 1080-1088
[39] X.L. Xue, W. Zhao, B.C. Ma, Y. Ding, Efficient oxidation of sulfides catalyzed by a temperature-responsive phase transfer catalyst[(C₁₈H₃₇)₂(CH₃)₂N]₇PW₁₁O₃₉ with hydrogen peroxide, Catal. Commun., 29 (2012) 73-76
[40] S.H. Xun, W.S. Zhu, Y.H. Chang, H.P. Li, M. Zhang, W. Jiang, D. Zheng, Y.J. Qin, H.M. Li, Synthesis of supported SiW₁₂O₄₀-based ionic liquid catalyst induced solvent-free oxidative deep-desulfurization of fuels, Chem. Eng. J., 288 (2016) 608-617
[41] X.Y. Zeng, X.Y. Xiao, J.Y. Chen, H.L. Wang, Electron-hole interactions in choline-phosphotungstic acid boosting molecular oxygen activation for fuel desulfurization, Appl. Catal. B:Environ., 248 (2019) 573-586
[42] X.J. Kong, S.X. Wu, L.Y. Liu, S. Li, J.H. Liu, Continuous synthesis of ethyl levulinate over Cerium exchanged phosphotungstic acid anchored on commercially silica gel pellets catalyst, Mol. Catal., 439 (2017) 180-185
[43] H.F. Wang, C.Y. Wang, Y.F. Yang, M. Zhao, Y.J. Wang, H₃PW₁₂O₄₀/mpg-C₃N₄ as an efficient and reusable bifunctional catalyst in one-pot oxidation-Knoevenagel condensation tandem reaction, Catal. Sci. Technol., 7 (2017) 405-417
[44] J.H. Liu, S.Y. Xie, Z.B. Geng, K.K. Huang, L. Fan, W.L. Zhou, L.X. Qiu, D.L. Gao, L. Ji, L.M. Duan, L.H. Lu, W.F. Li, S.Z. Bai, Z.R. Liu, W. Chen, S.H. Feng, Y.G. Zhang, Carbon nitride supramolecular hybrid material enabled high-efficiency photocatalytic water treatments, Nano Lett., 16 (2016) 6568-6575
[45] S. Otsuki, T. Nonaka, N. Takashima, W.H. Qian, A. Ishihara, T. Imai, T. Kabe, Oxidative desulfurization of light gas oil and vacuum gas oil by oxidation and solvent extraction, Energ. Fuel., 14 (2000) 1232-1239
[46] H.P. Li, W.S. Zhu, S.W. Zhu, J.X. Xia, Y.H. Chang, W. Jiang, M. Zhang, Y.W. Zhou, H.M. Li, The selectivity for sulfur removal from oils:An insight from conceptual density functional theory, AIChE J., 62 (2016) 2087-2100
[47] P.W. Wu, Y.C. Wu, L.L. Chen, J. He, M.Q. Hua, F.X. Zhu, X.Z. Chu, J. Xiong, M.Q. He, W.S. Zhu, H.M. Li, Boosting aerobic oxidative desulfurization performance in fuel oil via strong metal-edge interactions between Pt and h-BN, Chem. Eng. J., 380 (2020) 122526
[48] H. Najafian, F. Manteghi, F. Beshkar, M. Salavati-Niasari, Fabrication of nanocomposite photocatalyst CuBi₂O₄/Bi₃ClO₄ for removal of acid brown 14 as water pollutant under visible light irradiation, J. Hazard. Mater., 361 (2019) 210-220
[49] X.W. Li, B. Wang, Y.H. Huang, J. Di, J.X. Xia, W.S. Zhu, H.M. Li, Boosting photocatalytic degradation of RhB via interfacial electronic effects between Fe-based ionic liquid and g-C₃N₄, Green Energy Environ., 4 (2019) 198-206
[50] S.H. Xun, D. Zheng, S. Yin, Y.J. Qin, M. Zhang, W. Jiang, W.S. Zhu, H.M. Li, TiO₂ microspheres supported polyoxometalate-based ionic liquids induced catalytic oxidative deep-desulfurization, RSC Adv., 6 (2016) 42402-42412

Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents

Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents

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