Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

doi:10.1016/j.cjche.2021.08.009

中国化学工程学报 ›› 2022, Vol. 48 ›› Issue (8): 36-43.DOI: 10.1016/j.cjche.2021.08.009

Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

Min Lu¹, Mengxuan Liu¹, Chunli Xu¹, Yu Yin¹, Lei Shi², Hong Wu², Aihua Yuan¹, Xiao-Ming Ren³, Shaobin Wang⁴, Hongqi Sun²

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. School of Engineering, Edith Cowan University, Joondalup, WA 6027, Australia;
3. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China;
4. School of Chemical Engineering and Advanced Materials, The University of Adelaide, Adelaide, SA 5005, Australia

收稿日期:2021-05-13 修回日期:2021-07-30 出版日期:2022-08-28 发布日期:2022-09-30
通讯作者: Yu Yin,E-mail:season_july@just.edu.cn;Aihua Yuan,E-mail:aihua.yuan@just.edu.cn;Hongqi Sun,E-mail:h.sun@ecu.edu.au
基金资助:
We would like to show our great appreciation for funding support from National Natural Science Foundation of China (51602133) and State Key Laboratory of Materials-Oriented Chemical Engineering (KL19-05). The authors also express thanks for taking TEM images from the Centre for Microscopy, Characterization and Analysis (CMCA) of the University of Western Australia.

Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

Min Lu¹, Mengxuan Liu¹, Chunli Xu¹, Yu Yin¹, Lei Shi², Hong Wu², Aihua Yuan¹, Xiao-Ming Ren³, Shaobin Wang⁴, Hongqi Sun²

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. School of Engineering, Edith Cowan University, Joondalup, WA 6027, Australia;
3. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China;
4. School of Chemical Engineering and Advanced Materials, The University of Adelaide, Adelaide, SA 5005, Australia

Received:2021-05-13 Revised:2021-07-30 Online:2022-08-28 Published:2022-09-30
Contact: Yu Yin,E-mail:season_july@just.edu.cn;Aihua Yuan,E-mail:aihua.yuan@just.edu.cn;Hongqi Sun,E-mail:h.sun@ecu.edu.au
Supported by:
We would like to show our great appreciation for funding support from National Natural Science Foundation of China (51602133) and State Key Laboratory of Materials-Oriented Chemical Engineering (KL19-05). The authors also express thanks for taking TEM images from the Centre for Microscopy, Characterization and Analysis (CMCA) of the University of Western Australia.

摘要/Abstract

摘要： Refractory antibiotics in domestic wastewater are hard to be completely eliminated by conventional methods, and then lead to severe environmental contamination and adverse effects on public health. In present work, advanced oxidation processes (AOPs) are adopted to remove the antibiotic of sulfachloropyridazine (SCP). Nanosized Mn₂O₃ was fabricated on the SBA-15 material to catalytically activate potassium peroxydisulfate (PDS) to generate reactive oxygen radicals of ?OH and SO₄^- for SCP degradation. The effects of location and size of Mn₂O₃ were explored through choosing either the as-made or template-free SBA-15 as the precursor of substrate. Great influences from the site and size of Mn₂O₃ on the oxidation activity were discovered. It was found that Mn₂O₃ with a large size at the exterior of SBA-15 (Mn-tfSBA) was slightly easier to degrade SCP at a low manganese loading of 1.0–2.0?mmol?g^?1; however, complete SCP removal could only be achieved on the catalyst of Mn₂O₃ with a refined size at the interior of SBA-15 (Mn-asSBA). Moreover, the SO₄^- species were revealed to be the decisive radicals in the SCP degradation processes. Exploring the as-made mesoporous silica as a support provides a new idea for the further development of environmentally friendly catalysts.

关键词: Advanced oxidation processes (AOPs), Sulfate radical, Antibiotic degradation, Manganese, Mesoporous silica

Abstract: Refractory antibiotics in domestic wastewater are hard to be completely eliminated by conventional methods, and then lead to severe environmental contamination and adverse effects on public health. In present work, advanced oxidation processes (AOPs) are adopted to remove the antibiotic of sulfachloropyridazine (SCP). Nanosized Mn₂O₃ was fabricated on the SBA-15 material to catalytically activate potassium peroxydisulfate (PDS) to generate reactive oxygen radicals of ?OH and SO₄^- for SCP degradation. The effects of location and size of Mn₂O₃ were explored through choosing either the as-made or template-free SBA-15 as the precursor of substrate. Great influences from the site and size of Mn₂O₃ on the oxidation activity were discovered. It was found that Mn₂O₃ with a large size at the exterior of SBA-15 (Mn-tfSBA) was slightly easier to degrade SCP at a low manganese loading of 1.0–2.0?mmol?g^?1; however, complete SCP removal could only be achieved on the catalyst of Mn₂O₃ with a refined size at the interior of SBA-15 (Mn-asSBA). Moreover, the SO₄^- species were revealed to be the decisive radicals in the SCP degradation processes. Exploring the as-made mesoporous silica as a support provides a new idea for the further development of environmentally friendly catalysts.

Key words: Advanced oxidation processes (AOPs), Sulfate radical, Antibiotic degradation, Manganese, Mesoporous silica

Min Lu, Mengxuan Liu, Chunli Xu, Yu Yin, Lei Shi, Hong Wu, Aihua Yuan, Xiao-Ming Ren, Shaobin Wang, Hongqi Sun. Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation[J]. 中国化学工程学报, 2022, 48(8): 36-43.

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Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

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