Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Brønsted ionic liquids

doi:10.1016/j.cjche.2021.09.009

中国化学工程学报 ›› 2022, Vol. 52 ›› Issue (12): 154-160.DOI: 10.1016/j.cjche.2021.09.009

• Full Length Article • 上一篇下一篇

Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Brønsted ionic liquids

Yipeng Zheng, Zhennan Cao, Zheng Zhou, Gaodong Yang, Zhibing Zhang

School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

收稿日期:2021-07-18 修回日期:2021-09-03 出版日期:2022-12-28 发布日期:2023-01-31
通讯作者: Gaodong Yang,E-mail:gaodong_yang@nju.edu.cn;Zhibing Zhang,E-mail:zbzhang@nju.edu.cn
基金资助:
The authors are grateful for the financial support of National Natural Science Foundation of China ( 21776122) and the Fundamental Research Funds for the Central Universities.

Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Brønsted ionic liquids

Yipeng Zheng, Zhennan Cao, Zheng Zhou, Gaodong Yang, Zhibing Zhang

School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Received:2021-07-18 Revised:2021-09-03 Online:2022-12-28 Published:2023-01-31
Contact: Gaodong Yang,E-mail:gaodong_yang@nju.edu.cn;Zhibing Zhang,E-mail:zbzhang@nju.edu.cn
Supported by:
The authors are grateful for the financial support of National Natural Science Foundation of China ( 21776122) and the Fundamental Research Funds for the Central Universities.

摘要/Abstract

摘要： A series of SO₃-functional Brønsted acidic ionic liquids (SBAILs) were prepared to catalyze the N-formylation of aniline with DMF. The reaction conditions such as ionic liquid type, reaction temperature, catalyst loading and molar ratio of reactants were investigated. To the best of our knowledge, kinetic model for the N-formylation of aniline with DMF using SBAIL was firstly built and simulated. The studies on the reaction order of the reaction were evaluated by initial concentration method, and the kinetic parameters such as reaction rate constant and activation energy were proposed and used to explain the catalytic activities of the SBAILs catalysts. Accordingly, the recycling experiments showed that the SBAIL [Bsmim][HSO₄] can be easily recovered and reused with stable activity. Further, the temperature-controlled study emphasized that the ionic liquid was easy to be separated and environmentally friendly.

关键词: N-formylation of aniline, Ionic liquid, Temperature-controlled system, Kinetic

Abstract: A series of SO₃-functional Brønsted acidic ionic liquids (SBAILs) were prepared to catalyze the N-formylation of aniline with DMF. The reaction conditions such as ionic liquid type, reaction temperature, catalyst loading and molar ratio of reactants were investigated. To the best of our knowledge, kinetic model for the N-formylation of aniline with DMF using SBAIL was firstly built and simulated. The studies on the reaction order of the reaction were evaluated by initial concentration method, and the kinetic parameters such as reaction rate constant and activation energy were proposed and used to explain the catalytic activities of the SBAILs catalysts. Accordingly, the recycling experiments showed that the SBAIL [Bsmim][HSO₄] can be easily recovered and reused with stable activity. Further, the temperature-controlled study emphasized that the ionic liquid was easy to be separated and environmentally friendly.

Key words: N-formylation of aniline, Ionic liquid, Temperature-controlled system, Kinetic

Yipeng Zheng, Zhennan Cao, Zheng Zhou, Gaodong Yang, Zhibing Zhang. Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Brønsted ionic liquids[J]. 中国化学工程学报, 2022, 52(12): 154-160.

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Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Brønsted ionic liquids

Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Brønsted ionic liquids

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