Design, synthesis, and nanoengineered modification of spherical graphene surface by layered double hydroxide (LDH) for removal of As(III) from aqueous solutions

doi:10.1016/j.cjche.2022.01.023

中国化学工程学报 ›› 2023, Vol. 53 ›› Issue (1): 374-380.DOI: 10.1016/j.cjche.2022.01.023

• Full Length Article • 上一篇下一篇

Design, synthesis, and nanoengineered modification of spherical graphene surface by layered double hydroxide (LDH) for removal of As(III) from aqueous solutions

Najma Kamali¹, Jahan B. Ghasemi¹, Ghodsi Mohammadi Ziarani², Sahar Moradian¹, Alireza Badiei¹

1. School of Chemistry, College of Science, University of Tehran, Tehran, Iran;
2. Department of Organic Chemistry, Faculty of Chemistry, Alzahra University, Vanak Square, Tehran, Iran

收稿日期:2021-10-16 修回日期:2021-12-08 出版日期:2023-01-28 发布日期:2023-04-08
通讯作者: Alireza Badiei,E-mail:abadiei@ut.ac.ir
基金资助:
The authors wish to thank the University of Tehran for financial support.

Design, synthesis, and nanoengineered modification of spherical graphene surface by layered double hydroxide (LDH) for removal of As(III) from aqueous solutions

Najma Kamali¹, Jahan B. Ghasemi¹, Ghodsi Mohammadi Ziarani², Sahar Moradian¹, Alireza Badiei¹

1. School of Chemistry, College of Science, University of Tehran, Tehran, Iran;
2. Department of Organic Chemistry, Faculty of Chemistry, Alzahra University, Vanak Square, Tehran, Iran

Received:2021-10-16 Revised:2021-12-08 Online:2023-01-28 Published:2023-04-08
Contact: Alireza Badiei,E-mail:abadiei@ut.ac.ir
Supported by:
The authors wish to thank the University of Tehran for financial support.

摘要/Abstract

摘要： In this study, new nano spherical graphene modified with LDH (Layered Double Hydroxide) was prepared and used to remove As(III) ion from aqueous solutions. At first, graphene oxide was synthesized from graphite using a well-known Hammer method. The obtained graphene oxide solution was sprayed in octanol solution under different temperatures and sprayed speed as influenced variables. The structure and physical characterization of synthesized spherical graphene oxide were determined by various techniques, including FT-IR, N₂ adsorption–desorption, SEM, TEM, and EDX. In the next step, the hydrothermal method was applied to deposition LDH on the spherical graphene oxide. The synthesized spherical graphene modified by LDH was used to remove As(III) as a toxic heavy metal ion. The effect of influenced variables including pH, contact time, amount of sorbent, and type eluent studied and the optimum values were as 8, 30, 50, and HCl (0.5 mol·L^-1), respectively. After optimization, the studied sorbent was shown a high adsorption capacity (149.3 mg·g^-1). The adsorption mechanism and kinetic models exhibited good agreement with the Langmuir isotherm and pseudo-second-order trends, respectively. Besides, the synthesized product was tested for seven times without significant loss in its sorption efficiency.

关键词: Graphene-based spherical adsorbent, Layered double hydroxide (LDH), Adsorption, Spray-assisted deep-frying

Abstract: In this study, new nano spherical graphene modified with LDH (Layered Double Hydroxide) was prepared and used to remove As(III) ion from aqueous solutions. At first, graphene oxide was synthesized from graphite using a well-known Hammer method. The obtained graphene oxide solution was sprayed in octanol solution under different temperatures and sprayed speed as influenced variables. The structure and physical characterization of synthesized spherical graphene oxide were determined by various techniques, including FT-IR, N₂ adsorption–desorption, SEM, TEM, and EDX. In the next step, the hydrothermal method was applied to deposition LDH on the spherical graphene oxide. The synthesized spherical graphene modified by LDH was used to remove As(III) as a toxic heavy metal ion. The effect of influenced variables including pH, contact time, amount of sorbent, and type eluent studied and the optimum values were as 8, 30, 50, and HCl (0.5 mol·L^-1), respectively. After optimization, the studied sorbent was shown a high adsorption capacity (149.3 mg·g^-1). The adsorption mechanism and kinetic models exhibited good agreement with the Langmuir isotherm and pseudo-second-order trends, respectively. Besides, the synthesized product was tested for seven times without significant loss in its sorption efficiency.

Key words: Graphene-based spherical adsorbent, Layered double hydroxide (LDH), Adsorption, Spray-assisted deep-frying

Najma Kamali, Jahan B. Ghasemi, Ghodsi Mohammadi Ziarani, Sahar Moradian, Alireza Badiei. Design, synthesis, and nanoengineered modification of spherical graphene surface by layered double hydroxide (LDH) for removal of As(III) from aqueous solutions[J]. 中国化学工程学报, 2023, 53(1): 374-380.

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Design, synthesis, and nanoengineered modification of spherical graphene surface by layered double hydroxide (LDH) for removal of As(III) from aqueous solutions

Design, synthesis, and nanoengineered modification of spherical graphene surface by layered double hydroxide (LDH) for removal of As(III) from aqueous solutions

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