The Ce-modified biochar for efficient removal of methylene blue dye: Kinetics, isotherms and reusability studies

doi:10.1016/j.cjche.2024.10.004

中国化学工程学报 ›› 2025, Vol. 77 ›› Issue (1): 57-65.DOI: 10.1016/j.cjche.2024.10.004

The Ce-modified biochar for efficient removal of methylene blue dye: Kinetics, isotherms and reusability studies

Shuaishuai Zhang¹, Xinan Sun¹, Qingwen Luo¹, Lin Chi¹, Peng Sun¹, Lianke Zhang^1,2

1. School of Energy and Environment, Inner Mongolia University of Science and Technology, Baotou 014010, China;
2. School of Automation and Electrical Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China

收稿日期:2024-07-16 修回日期:2024-09-21 接受日期:2024-10-08 出版日期:2025-01-28 发布日期:2024-11-08
通讯作者: Shuaishuai Zhang,E-mail:zhangss123@imust.edu.cn;Lianke Zhang,E-mail:nkdlkzhang@163.com
基金资助:
This work was supported by Basic scientific research business expense project of colleges and universities directly under Inner Mongolia (2024QNJS127 and 2023QNJS131), Science and Technology Plan Program of Inner Mongolia Autonomous Region (2023YFDZ0031), and the Inner Mongolia Natural Science Foundation (2024QN02011).

The Ce-modified biochar for efficient removal of methylene blue dye: Kinetics, isotherms and reusability studies

Shuaishuai Zhang¹, Xinan Sun¹, Qingwen Luo¹, Lin Chi¹, Peng Sun¹, Lianke Zhang^1,2

1. School of Energy and Environment, Inner Mongolia University of Science and Technology, Baotou 014010, China;
2. School of Automation and Electrical Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China

Received:2024-07-16 Revised:2024-09-21 Accepted:2024-10-08 Online:2025-01-28 Published:2024-11-08
Contact: Shuaishuai Zhang,E-mail:zhangss123@imust.edu.cn;Lianke Zhang,E-mail:nkdlkzhang@163.com
Supported by:
This work was supported by Basic scientific research business expense project of colleges and universities directly under Inner Mongolia (2024QNJS127 and 2023QNJS131), Science and Technology Plan Program of Inner Mongolia Autonomous Region (2023YFDZ0031), and the Inner Mongolia Natural Science Foundation (2024QN02011).

摘要/Abstract

摘要： Exploring modification methods for enhancing the adsorption performance of biochar-based adsorbents for effective removal of methylene blue (MB), biochar-loaded CeO₂ nanoparticles (Ce/BC) were synthesized by pomelo peels through co-precipitation combined with the pyrolysis method. Ce/BC showed a higher specific surface area and disorder degree than that of BC. The 0.5Ce/BC (mass ratio of Ce(NO₃)₃·6H₂O/BC = 0.5/1) showed the best performance to adsorption of MB solution at different reaction conditions (MB concentration, Ce/BC composites dosage, and initial pH). Adsorption kinetics and equilibrium isotherms were well-described with a pseudo-first-order equation and Langmuir model, respectively. In addition, the maximum adsorption capacity of 0.5Ce/BC for MB was 105.68 mg·g^-1 at 328 K. The strong adsorption was attributed to multi-interactions including pore filling, π-π interactions, electrostatic interaction, and hydrogen bonding between the composites and MB. This work demonstrated that the modified pomelo peels biochar, as a green promising material with cost-effectiveness, exhibited a great potential for broad application prospectively to dyeing-contaminated wastewater treatment.

关键词: CeO₂, Biochar, Methylene blue, Adsorption, Stability

Abstract: Exploring modification methods for enhancing the adsorption performance of biochar-based adsorbents for effective removal of methylene blue (MB), biochar-loaded CeO₂ nanoparticles (Ce/BC) were synthesized by pomelo peels through co-precipitation combined with the pyrolysis method. Ce/BC showed a higher specific surface area and disorder degree than that of BC. The 0.5Ce/BC (mass ratio of Ce(NO₃)₃·6H₂O/BC = 0.5/1) showed the best performance to adsorption of MB solution at different reaction conditions (MB concentration, Ce/BC composites dosage, and initial pH). Adsorption kinetics and equilibrium isotherms were well-described with a pseudo-first-order equation and Langmuir model, respectively. In addition, the maximum adsorption capacity of 0.5Ce/BC for MB was 105.68 mg·g^-1 at 328 K. The strong adsorption was attributed to multi-interactions including pore filling, π-π interactions, electrostatic interaction, and hydrogen bonding between the composites and MB. This work demonstrated that the modified pomelo peels biochar, as a green promising material with cost-effectiveness, exhibited a great potential for broad application prospectively to dyeing-contaminated wastewater treatment.

Key words: CeO₂, Biochar, Methylene blue, Adsorption, Stability

Shuaishuai Zhang, Xinan Sun, Qingwen Luo, Lin Chi, Peng Sun, Lianke Zhang. The Ce-modified biochar for efficient removal of methylene blue dye: Kinetics, isotherms and reusability studies[J]. 中国化学工程学报, 2025, 77(1): 57-65.

参考文献

[1] N. Moradi, M. Jamshidi, R. Ghamarpoor, M.R. Moghbeli, Surface functionalization/silane modification of CeO₂ nanoparticles and their influences on photocatalytic activity of acrylic films for methylene blue removal, Prog. Org. Coat. 183(2023) 107787.
[2] J.L. Tan, Ag nanoparticles functionalized melamine sponges for enhanced catalytic reduction of methylene blue, Chem. Eng. Sci. 291(2024) 119963.
[3] C. Waghmare, S. Ghodmare, K. Ansari, M.H. Dehghani, M. Amir Khan, M.A. Hasan, S. Islam, N.A. Khan, S. Zahmatkesh, Experimental investigation of H₃PO₄ activated papaya peels for methylene blue dye removal from aqueous solution: Evaluation on optimization, kinetics, isotherm, thermodynamics, and reusability studies, J. Environ. Manage. 345(2023) 118815.
[4] K.L. Wu, M.L. Shi, X.M. Pan, J.Q. Zhang, X.M. Zhang, T. Shen, Y.Q. Tian, Decolourization and biodegradation of methylene blue dye by a ligninolytic enzyme-producing bacillus thuringiensis: Degradation products and pathway, Enzyme Microb. Technol. 156(2022) 109999.
[5] S.Y. Chen, L. Li, M. Feng, T. Huang, N. Zhang, Y. Wang, UV-activated superwetting ability of electrospun polysulfone/titanium dioxide membranes toward highly efficient methylene blue removal and oil/water separation, J. Membr. Sci. 695(2024) 122450.
[6] S.T. K, R. Pavithran, A. Vidhya, Design of 3D-supramolecular metal organic framework of zinc as photocatalyst for the degradation of methylene blue through advanced oxidation process, J. Mol. Struct. 1245(2021) 131039.
[7] L. Natrayan, V.R. Niveditha, V.S. Nadh, C. Srinivas, J.A. Dhanraj, A. Saravanan, Application of response surface and artificial neural network optimization approaches for exploring methylene blue adsorption using luffa fiber treated with sodium chlorite, J. Water Process. Eng. 58(2024) 104778.
[8] H.T. Jiang, Y.J. Dai, Vitamin C modified crayfish shells biochar efficiently remove tetracycline from water: A good medicine for water restoration, Chemosphere 311(Pt 1) (2023) 136884.
[9] S.V. Gupta, V.V. Kulkarni, M. Ahmaruzzaman, Fabrication of a bio-adsorbent material by grafting CeO₂ quantum dots (QDts) over areca nut shell biochar using saccharum officinarum extract as a solvent/capping agent for adsorption of methylene blue dye: Synthesis, material analyses, adsorption kinetics and isotherms studies, Colloids Surf. A Physicochem. Eng. Aspects 680(2024) 132611.
[10] V.P. Dinh, N.Q. Tran, N.Q.T. Le, Q.H. Tran, T.D. Nguyen, V.T. Le, Facile synthesis of FeFe₂O₄ magnetic nanomaterial for removing methylene blue from aqueous solution, Prog. Nat. Sci. Mater. Int. 29(6) (2019) 648-654.
[11] H.V.T. Luong, T.P. Le, T.L.T. Le, H.G. Dang, T.B.Q. Tran, A graphene oxide based composite granule for methylene blue separation from aqueous solution: Adsorption, kinetics and thermodynamic studies, Heliyon 10(7) (2024) e28648.
[12] A. Reghioua, D. Atia, A. Hamidi, A.H. Jawad, A.S. Abdulhameed, H.M. Mbuvi, Production of eco-friendly adsorbent of Kaolin clay and cellulose extracted from peanut shells for removal of methylene blue and Congo red removal dyes, Int. J. Biol. Macromol. 263(Pt 1) (2024) 130304.
[13] M.M. Altayan, N. Tzoupanos, M. Barjenbruch, Polymer based on beta-cyclodextrin for the removal of bisphenol A, methylene blue and lead(II): Preparation, characterization, and investigation of adsorption capacity, J. Mol. Liq. 390(2023) 122822.
[14] R. Amen, H. Bashir, I. Bibi, S. M. Shaheen, N. K. Niazi, M. Shahid, M. M. Hussain, V. Antoniadis, M. B. Shakoor, S. G. Al-Solaimani, H.L. Wang, J. Bundschuh, J. Rinklebe. A critical review on arsenic removal from water using biochar-based sorbents: the significance of modification and redox reactions, Chem. Eng. J. 396(2020) 125195.
[15] Z.Y. Shao, Shuangbao, S. Wu, Y.W. Gao, X. Liu, Y.J. Dai, Two-step pyrolytic preparation of biochar for the adsorption study of tetracycline in water, Environ. Res. 242(2024) 117566.
[16] E. Rashad, H.N. Saleh, A.S. Eltaweil, M.E. Saleh, M. Sillanpaa, A.R. Mostafa, Pinewood sawdust biochar as an effective biosorbent for PAHs removal from wastewater, Biomass Convers. Biorefin. 13(15) (2023) 13443-13459.
[17] X. Liu, Z.Y. Shao, Y.X. Wang, Y.F. Liu, S.Y. Wang, F. Gao, Y.J. Dai, New use for Lentinus edodes bran biochar for tetracycline removal, Environ. Res. 216(Pt 4) (2023) 114651.
[18] Z. Cao, R. Zhu, Y. Li, A. Kakade, S.Y. Zhang, Y.L. Yuan, Y.B. Wu, J.D. Mi, Mitigation of ammonia and hydrogen sulfide emissions during aerobic composting of laying hen waste through NaOH-modified biochar, J. Environ. Manage. 365(2024) 121634.
[19] Q.M. Truong, T.B. Nguyen, C.W. Chen, W.H. Chen, X.T. Bui, C.D. Dong, KHCO₃- activated high surface area biochar derived from brown algae: A case study for efficient adsorption of Cr(VI) in aqueous solution, Environ. Res. 247(2024) 118227.
[20] H.T. Jiang, X. Li, Y.J. Dai, Phosphoric acid activation of cow dung biochar for adsorbing enrofloxacin in water: Icing on the cake, Environ. Pollut. 341(2024) 122887.
[21] R.A. Essa, M.A. El-Aal, A. Sedky, E.F. Abo Zeid, S. Amin, ZnO NPs-modified biochar derived from banana peels for adsorptive removal of methylene blue from water, J. Mol. Struct. 1321(2025) 139821.
[22] E. Nyankson, J. Adjasoo, J.K. Efavi, A. Yaya, G. Manu, A. Kingsford, R.Y. Abrokwah, Synthesis and kinetic adsorption characteristics of Zeolite/CeO₂ nanocomposite, Sci. Afr. 7(2020) e00257.
[23] N.K. Soliman, A.F. Moustafa, H.R.A. El-Mageed, O.F. Abdel-Gawad, E.T. Elkady, S.A. Ahmed, H.S. Mohamed, Experimentally and theoretically approaches for disperse red 60 dye adsorption on novel quaternary nanocomposites, Sci. Rep. 11(1) (2021) 10000.
[24] S.M. Gao, W.W. Zhang, Z.H. An, S.L. Kong, D.H. Chen, Adsorption of anionic dye onto magnetic Fe₃O₄/CeO₂ nanocomposite: Equilibrium, kinetics, and thermodynamics, Adsorpt. Sci. Technol. 37(3-4) (2019) 185-204.
[25] S.V. Gupta, V.V. Kulkarni, M. Ahmaruzzaman, A robust bio-source mediated CeO₂-SnS₂ quantum dots @Oryza sativa var. biochar, photo-adsorbent for removal of baszol violet 57L dye from aqueous discharge: Development, materialistic analyses, and its application, J. Water Process. Eng. 60(2024) 105159.
[26] J.M. Soney, T. Dhannia, Enhanced photocatalytic activity of CeO₂ and magnetic biochar-CeO₂ nanocomposite prepared from Murraya koenigii stem for degradation of methyl orange under UV light, J. Photochem. Photobiol. A Chem. 447(2024) 115259.
[27] K. Luo, N.F. Lin, X. Li, Y. Pang, L.P. Wang, M. Lei, Q. Yang, Efficient hexavalent chromium removal by nano-cerium oxide functionalized biochar: Insight into the role of reduction, J. Environ. Chem. Eng. 11(3) (2023) 110004.
[28] S.V. Gupta, V.V. Kulkarni, M. Ahmaruzzaman, Bandgap engineering approach for designing CuO/Mn₃O₄/CeO₂ heterojunction as a novel photocatalyst for AOP-assisted degradation of Malachite green dye, Sci. Rep. 13(1) (2023) 3009.
[29] Q. Xu, Y.J. Jin, F. Zheng, J.Y. Lu, Exploitation of pomelo peel developing porous biochar by N, P co-doping and KOH activation for efficient CO₂ adsorption, Sep. Purif. Technol. 324(2023) 124595.
[30] N. Bhuvanendran, S. Ravichandran, S. Kandasamy, W.Q. Zhang, Q. Xu, L. Khotseng, T. Maiyalagan, H.N. Su, Spindle-shaped CeO₂/biochar carbon with oxygen-vacancy as an effective and highly durable electrocatalyst for oxygen reduction reaction, Int. J. Hydrog. Energy 46(2) (2021) 2128-2142.
[31] X. Zhao, M. Liu, H. Feng, X.Y. Luo, Y. Yang, J.L. Hu, Y.W. Hu, Effects and mechanisms on Cr(VI) and methylene blue adsorption by acid (NH₄)₂S₂O₈ modified sludge biochar, Sep. Purif. Technol. 345(2024) 127100.
[32] S.S. Sahoo, V.K. Vijay, R. Chandra, H. Kumar, Production and characterization of biochar produced from slow pyrolysis of pigeon pea stalk and bamboo, Clean. Eng. Technol. 3(2021) 100101.
[33] E. Abdel Azim, M. Samy, M. Hanafy, H. Mahanna, Novel mint-stalks derived biochar for the adsorption of methylene blue dye: Effect of operating parameters, adsorption mechanism, kinetics, isotherms, and thermodynamics, J. Environ. Manag. 357(2024) 120738.
[34] D. Kumar, J. Pandey, A. Kumar, Enhanced photocatalytic removal of Cd(II) from aqueous solution using Bi/S Co-doped carbon quantum dots, Mater. Sci. Energy Technol. 7(2024) 9-18.
[35] P. Zhang, D. O’Connor, Y. Wang, L. Jiang, T. Xia, L. Wang, D.C.W. Tsang, Y.S. Ok, D. Hou, A green biochar/iron oxide composite for methylene blue removal, J. Hazard. Mater. 384(2020) 121286.
[36] Y.C. Sun, T.T. Wang, C.H. Han, X.T. Lv, L. Bai, X.Y. Sun, P.F. Zhang, Facile synthesis of Fe-modified lignin-based biochar for ultra-fast adsorption of methylene blue: Selective adsorption and mechanism studies, Bioresour. Technol. 344(Pt A) (2022) 126186.
[37] H.Y. Li, J. Kong, H.T. Zhang, J.L. Gao, Y. Fang, J.Q. Shi, T. Ge, T. Fang, Y.H. Shi, R. Zhang, N.Y. Zhang, X.J. Dong, Y.H. Zhang, H. Li, Mechanisms and adsorption capacities of ball milled biomass fly ash/biochar composites for the adsorption of methylene blue dye from aqueous solution, J. Water Process. Eng. 53(2023) 103713.
[38] N. Tabassam, S. Mutahir, M.A. Khan, I.U. Khan, U. Habiba, M.S. Refat, Facile synthesis of cinnamic acid sensitized rice husk biochar for removal of organic dyes from wastewaters: Batch experimental and theoretical studies, Mater. Chem. Phys. 288(2022) 126327.
[39] A.A. Emam, S.A. Abo Faraha, F.H. Kamal, A.M. Gamal, M. Basseem, Modification and characterization of nano cellulose crystalline from eichhornia crassipes using citric acid: An adsorption study, Carbohydr. Polym. 240(2020) 116202.
[40] K.L. Yu, X.J. Lee, H.C. Ong, W.H. Chen, J.S. Chang, C.S. Lin, P.L. Show, T.C. Ling, Adsorptive removal of cationic methylene blue and anionic Congo red dyes using wet-torrefied microalgal biochar: Equilibrium, kinetic and mechanism modeling, Environ. Pollut. 272(2021) 115986.
[41] H.K. Yagmur, I. Kaya, Synthesis and characterization of magnetic ZnCl₂-activated carbon produced from coconut shell for the adsorption of methylene blue, J. Mol. Struct. 1232(2021) 130071.
[42] N.O. Rubangakene, M. Elkady, A. Elwardany, M. Fujii, H. Sekiguchi, H. Shokry, Effective decontamination of methylene blue from aqueous solutions using novel nano-magnetic biochar from green pea peels, Environ. Res. 220(2023) 115272.
[43] M.A. Rahman, D. Lamb, M.M. Rahman, M.M. Bahar, P. Sanderson, S. Abbasi, A.S.M.F. Bari, R. Naidu, Removal of arsenate from contaminated waters by novel zirconium and zirconium-iron modified biochar, J. Hazard. Mater. 409(2021) 124488.
[44] B. Chen, F.X. Long, S.J. Chen, Y.R. Cao, X.J. Pan, Magnetic chitosan biopolymer as a versatile adsorbent for simultaneous and synergistic removal of different sorts of dyestuffs from simulated wastewater, Chem. Eng. J. 385(2020) 123926.
[45] Y. Liu, L. Wang, C. Liu, J. Ma, X.X. Ouyang, L.P. Weng, Y.L. Chen, Y.T. Li, Enhanced cadmium removal by biochar and iron oxides composite: Material interactions and pore structure, J. Environ. Manage. 330(2023) 117136.
[46] Q.J. Dai, Q. Liu, X.Y. Zhang, L.Y. Cao, B. Hu, J. Shao, F.J. Ding, X.S. Guo, B. Gao, Synergetic effect of co-pyrolysis of sewage sludge and lignin on biochar production and adsorption of methylene blue, Fuel 324(2022) 124587.
[47] K.R. Li, J. Wu, X. Li, B.D. Li, D.H. Zhou, Preparation of porous composite hydrogel with ultra-high dye adsorption capacity based on biochar: Adsorption behaviors and mechanisms, Chem. Eng. Sci. 295(2024) 120115.
[48] H.B. Chen, Y.R. Gao, A. El-Naggar, N.K. Niazi, C.H. Sun, S.M. Shaheen, D.Y. Hou, X. Yang, Z.Y. Tang, Z.Z. Liu, H. Hou, W.F. Chen, J. Rinklebe, M. Pohorely, H.L. Wang, Enhanced sorption of trivalent antimony by chitosan-loaded biochar in aqueous solutions: Characterization, performance and mechanisms, J. Hazard. Mater. 425(2022) 127971.

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The Ce-modified biochar for efficient removal of methylene blue dye: Kinetics, isotherms and reusability studies

The Ce-modified biochar for efficient removal of methylene blue dye: Kinetics, isotherms and reusability studies

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