Vapor-Liquid Equilibrium of Ethyl Acetate+CnH2n+1OH(n=1, 2, 3) Binary Systems at 0.3 Mpa

Chinese Journal of Chemical Engineering ›› 2012, Vol. 20 ›› Issue (4): 723-730.

Vapor-Liquid Equilibrium of Ethyl Acetate+C_nH_2n+1OH(n=1, 2, 3) Binary Systems at 0.3 Mpa

SUSIAL P., RODRIGUEZ-HENRIQUEZ J. J., SOSA-ROSARIO A., RIOS-SANTANA R.

School of Industrial and Civil Engineering, University of Las Palmas de Gran Canaria, Canary Islands, Spain

收稿日期:2011-03-31 修回日期:2012-02-28 出版日期:2012-08-28 发布日期:2012-09-15
通讯作者: SUSIAL P., E-mail:psusial@dip.ulpgc.es

Vapor-Liquid Equilibrium of Ethyl Acetate+C_nH_2n+1OH(n=1, 2, 3) Binary Systems at 0.3 Mpa

SUSIAL P., RODRIGUEZ-HENRIQUEZ J. J., SOSA-ROSARIO A., RIOS-SANTANA R.

School of Industrial and Civil Engineering, University of Las Palmas de Gran Canaria, Canary Islands, Spain

Received:2011-03-31 Revised:2012-02-28 Online:2012-08-28 Published:2012-09-15

摘要/Abstract

摘要： Vapor-liquid equilibrium data for the binary systems of ethyl acetate + methanol,ethyl acetate + ethanol and ethyl acetate + 1-propanol at 0.3 MPa were determined.The experimental data were verified with the point-to-point test of van Ness(1973).All these systems present an azeotropic point at 0.3 MPa that increases in ester composition for longer alcohol chains.The UNIFAC in different versions and ASOG prediction models were applied.

关键词: vapor-liquid equilibrium, vapor-liquid equilibrium isobaric data, ethyl ester, alcohol

Abstract: Vapor-liquid equilibrium data for the binary systems of ethyl acetate + methanol,ethyl acetate + ethanol and ethyl acetate + 1-propanol at 0.3 MPa were determined.The experimental data were verified with the point-to-point test of van Ness(1973).All these systems present an azeotropic point at 0.3 MPa that increases in ester composition for longer alcohol chains.The UNIFAC in different versions and ASOG prediction models were applied.

Key words: vapor-liquid equilibrium, vapor-liquid equilibrium isobaric data, ethyl ester, alcohol

SUSIAL P., RODRIGUEZ-HENRIQUEZ J. J., SOSA-ROSARIO A., RIOS-SANTANA R. . Vapor-Liquid Equilibrium of Ethyl Acetate+C_nH_2n+1OH(n=1, 2, 3) Binary Systems at 0.3 Mpa[J]. Chinese Journal of Chemical Engineering, 2012, 20(4): 723-730.

SUSIAL P., RODRIGUEZ-HENRIQUEZ J. J., SOSA-ROSARIO A., RIOS-SANTANA R.. Vapor-Liquid Equilibrium of Ethyl Acetate+C_nH_2n+1OH(n=1, 2, 3) Binary Systems at 0.3 Mpa[J]. Chin.J.Chem.Eng., 2012, 20(4): 723-730.

参考文献

1 Susial,P.,Sosa-Rosario,A.,Rios-Santana,R.,"Vapor-liquid equilibria for ethyl acetate+methanol at(0.1,0.5,and 0.7)MPa.Measurements with a new ebulliometer",J.Chem.Eng.Data,55,5701-5706(2010).
2 Susial,P.,Sosa-Rosario,A.,Rodriguez-Henriquez,J.J.,Rios-Santana, R.,"Vapor pressure and VLE data measurements on ethyl acetate/ethanol binary system at 0.1,0.5,and 0.7 MPa",J.Chem.Eng. Jpn,44,155-163(2011).
3 Gmehling,J.,Onken,U.,Arlt,W.,Grenzheuser,P.,Weidlich,U., Kolbe,B.,Rarey,J.,Vapor-Liquid Equilibrium Data Collection,Vol.1,Part 2,Dechema,Frankfurt,Germany(1986).
4 Orchillés,A.V.,Miguel,P.J.,Vercher,E.,Martinéz-Abreu,A.,"Isobaric vapor-liquid equilibria for ethyl acetate+ethanol+1-ethyl-3methylimidazolium Trifluoro-methane-sulfonate at 100 kPa",J. Chem.Eng.Data,52,2325-2330(2007).
5 Calvar,N.,Domínguez,A.,Tojo,J.,"Vapor-liquid equilibria for the quaternary reactive system ethyl acetate+ethanol+water+acetic acid and some of the constituent binary systems at 101.3 kPa",Fluid Phase Equilib.,235,215-222(2005).
6 Chein-Hsiun,T.,Yuh-Shen,W.,Feng-Chao,O.,"Effect of1,2-Propanediol on the vapor-liquid equilibria of the ethyl acetate+ethanol system at 101.3 kPa",Fluid Phase Equilib.,130,243-252 (1997).
7 Ortega,J.,Peña,J.A.,de-Afonso,C.,"Isobaric vapor-liquid equilibria of ethyl acetate+ethanol mixtures at(760±0.5)mmHg",J.Chem. Eng.Data,31,339-342(1986).
8 Topphoff,M.,Kiepe,J.,Gmehling,J.,"Effects of lithium nitrate on the vapor-liquid equilibria of methyl acetate+methanol and ethyl acetate+ethanol",J.Chem.Eng.Data,46,1333-1337(2001).
9 Ortega,J.,Peña,J.A.,"Isobaric VLE for the ethyl acetate+n-propanol and n-butanol",Rev.Lat.Am.Ing.Quim.,16,317-321(1986).
10 Gmehling,J.,Menke,J.,Krafczyk,J.,Fischer,K.,Azeotropic Data, Part 1,2nd,edition,Wiley-VCH Verlag,Weinheim,Germany(2004).
11 van Ness,H.C.,Byer,S.M.,Gibbs,R.E."Vapor-liquid equilibrium(I) An appraisal of data reduction methods",AIChE J.,19,238-244(1973).
12 Fredenslund,A.,Gmehling,J.,Rasmussen,P.,Vapor-Liquid Equilibria Using UNIFAC.A Group Contribution Model,Elsevier,Amsterdam(1977).
13 Larsen,B.L.,Rasmussen,P.,Fredenslund,A.,"A modified UNIFAC group-contribution model for prediction of phase equilibria and heats of mixing,"Ind.Eng.Chem.Res.,26,2274-2286(1987).
14 Hansen,H.K.,Rasmussen,P.,Fredenslund,A.,Schiller,M.,Gmehling,J.,"Vapor-liquid equilibria by UNIFAC group-contribution.5. Revision and extension",Ind.Eng.Chem.Res.,30,2355-2358(1991).
15 Gmehling,J.,Li,J.,Schiller,M.,"A modified UNIFAC model.2. present parameter matrix and results for different thermodynamic properties",Ind.Eng.Chem.Res.,32,178-193(1993).
16 Kojima,K.,Tochigi,K.,Prediction of Vapor-Liquid Equilibria by the ASOG Method,Kodansha Ltd.,Tokyo(1979).
17 Riddick,J.A.,Bunger,W.B.,Sakano,T.K.Organic Solvents, Wiley-Interscience,New York(1986).
18 Nagata,I.,Ohta,T.,Nakagawa,S.,"Excess Gibss free energies and heats of mixing for binary alcoholic liquid mixtures",J.Chem.Eng. Jpn.,9,276-281(1976).
19 Resa,J.M.,Gonzalez,C.,Goenaga,J.M.,"Density,refractive index, speed of sound at 298.15 K,and vapor-liquid equilibria at 101.3 kPa for binary mixtures of propanol+2-methyl-1-butanol and propanol+3-methyl-1-butanol",J.Chem.Eng.Data,51,73-78(2006).
20 Susial,P.,Sosa-Rosario,A.,Rios-Santana,R.,"VLE with a new ebulliometer.ester-alcohol systems at 5.0 bar",Chin.J.Chem.Eng.,18,1000-1007(2010).
21 Hayden,J.G.,O'Connell,J.P.,"A generalised method for predicting second virial coefficients",Ind.Eng.Chem.Process Des.Dev.,14,209-216(1975).
22 Yen,L.C.,Woods,S.S.,"A generalized equation for computer calculation of liquid densities",AIChE J.,12,95-99(1966).

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Vapor-Liquid Equilibrium of Ethyl Acetate+C_nH_2n+1OH(n=1, 2, 3) Binary Systems at 0.3 Mpa

Vapor-Liquid Equilibrium of Ethyl Acetate+C_nH_2n+1OH(n=1, 2, 3) Binary Systems at 0.3 Mpa

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