Improvement of CO2 capture performance of calcium-based absorbent modified with palygorskite

›› 2016, Vol. 24 ›› Issue (9): 1283-1289.

• Energy, Resources and Environmental Technology • 上一篇下一篇

Improvement of CO₂ capture performance of calcium-based absorbent modified with palygorskite

Liyuan Shan¹, Hui Li^1,2, Binglu Meng³, Youhai Yu³, Yonggang Min^1,2

1 College of Material and Mineral Resource, Xi'an University of Architecture and Technology, Xi'an 710055, China;
2 Shaanxi Techno-Institute of Recycling Economy, Xi'an 710055, China;
3 Xi'an Institute of Optics and Precision Mechanics of Chinese Academy of Science, Xi'an 710119, China

收稿日期:2015-11-02 修回日期:2016-05-16 出版日期:2016-09-28 发布日期:2016-11-11
通讯作者: Youhai Yu,E-mail address:youhai.yu@gmail.com;Yonggang Min,E-mail address:yong686@126.com
基金资助:
Supported by the National Natural Science Foundation of China (51274159), and Special Funds for The Major Science and Technology Innovation of Shaanxi Province (2012zkc06-2).

Improvement of CO₂ capture performance of calcium-based absorbent modified with palygorskite

Liyuan Shan¹, Hui Li^1,2, Binglu Meng³, Youhai Yu³, Yonggang Min^1,2

1 College of Material and Mineral Resource, Xi'an University of Architecture and Technology, Xi'an 710055, China;
2 Shaanxi Techno-Institute of Recycling Economy, Xi'an 710055, China;
3 Xi'an Institute of Optics and Precision Mechanics of Chinese Academy of Science, Xi'an 710119, China

Received:2015-11-02 Revised:2016-05-16 Online:2016-09-28 Published:2016-11-11
Supported by:
Supported by the National Natural Science Foundation of China (51274159), and Special Funds for The Major Science and Technology Innovation of Shaanxi Province (2012zkc06-2).

摘要/Abstract

摘要： Limestone can be used for CO₂ capture and sequestration (CCS) in flue gas effectively. However, its CCS capability will dramatically decline after several cycles due to the surface "sintering". In this work, the limestone was modified with palygorskite to reduce sintering phenomenon between the absorbent particles during the CCS process and the carbonation rate of the limestone can be enhanced effectively. Palygorskite is a natural mineral with nano-fibrous structure which can reduce the mutual contact of limestone particles during the CCS process. The results were detected by TGA, SEM,MIP, FTIR and particle size analyzer respectively. The best CO₂ capture performance of modified absorbent was 13.11% improvement with only 5 wt% palygorskite added during the CCS process after 15 cycles compared with natural absorbent. It was found that excellent microscopic structures of absorbent modified with palygorskite was created, and the surface sintering was postponed leading to CO₂ capture performance enhanced under the same conditions.

关键词: CO₂ capture, Palygorskite modification, Limestone, Carbonation rate, Anti-sintering

Abstract: Limestone can be used for CO₂ capture and sequestration (CCS) in flue gas effectively. However, its CCS capability will dramatically decline after several cycles due to the surface "sintering". In this work, the limestone was modified with palygorskite to reduce sintering phenomenon between the absorbent particles during the CCS process and the carbonation rate of the limestone can be enhanced effectively. Palygorskite is a natural mineral with nano-fibrous structure which can reduce the mutual contact of limestone particles during the CCS process. The results were detected by TGA, SEM,MIP, FTIR and particle size analyzer respectively. The best CO₂ capture performance of modified absorbent was 13.11% improvement with only 5 wt% palygorskite added during the CCS process after 15 cycles compared with natural absorbent. It was found that excellent microscopic structures of absorbent modified with palygorskite was created, and the surface sintering was postponed leading to CO₂ capture performance enhanced under the same conditions.

Key words: CO₂ capture, Palygorskite modification, Limestone, Carbonation rate, Anti-sintering

中图分类号:

10.1016/j.cjche.2016.05.021

Liyuan Shan, Hui Li, Binglu Meng, Youhai Yu, Yonggang Min. Improvement of CO₂ capture performance of calcium-based absorbent modified with palygorskite[J]. , 2016, 24(9): 1283-1289.

参考文献

[1] S. Wang, Y. Luo, Z. Zhao, et al., Debates on the cause of global warming, Adv. Clim. Chang. Res. 7(2) (2011) 79-84(in Chinese).
[2] J.T. Houghton, Y. Ding, D.J. Griggs, et al., Climate Change 2001:The Scientific Basis. Contribution of Working Group I to the Third Assessment Report of the IntergovernmentaPanel on Climate Change, Cambridge University Press, Cambridge, UK, and New York, USA, 2001.
[3] S.F. Singer, Nature, not human activity, rules the climate:Summary for policymakers of the report of the nongovernmental, International Panel on Climate Change, The Heartland Institute, Chicago, 2008.
[4] K.C. Meng, R.H.Williams, M.A. Celia, Opportunities for low-cost CO₂ storage demonstration projects in China, Energ Policy 35(4) (2007) 2368-2378.
[5] Z. Ma, l. Wang, Technical progress of emission-reduction and utilization of carbon dioxide in cement industry, Mater. Rev. 25(10) (2011) 150-154.
[6] D. Britt, H. Furukawa, B.Wang, et al., Highly efficient separation of carbon dioxide by a metal-organic frame-work replete with open metal sites, Proc. Natl. Acad. Sci. 106(49) (2009) 20637-20640.
[7] Y.S. Bae, K.L. Mulfort, H. Frost, et al., Separation of CO₂ from CH₄ using mixed-lig and metal-organic frame-works, Langmuir 24(16) (2008) 8592-8598.
[8] A.R. Millward, O.M. Yaghi, Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature, J. Am. Chem. Soc. 127(51) (2005) 17998-17999.
[9] P.D.C. Dietzel, R.E. Johnsen, H. Fjellvag, et al., Adsorption properties and structure of CO₂ adsorbed on open coordination sites of metal-organic framework Ni²(dhtp) from gas adsorption, Ir spectroscopy and X-ray diffraction, Chem. Commun. 41(2008) 5125-5127.
[10] P.D.C. Dietzel, V. Besikiotis, R. Blom, Application of metal-organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide, J. Mater. Chem. 19(39) (2009) 7362-7370.
[11] A.O.Z.R. Yazaydm, A.I. Benin, S.A. Faheem, et al., Enhanced CO₂ adsorption in metal-organic frameworks via occupation of open-metal sites by coordinated water molecules, Chem. Mater. 21(18) (2009) 1425-1430.
[12] H. Li, W. Yang, Y. Duan, Experiment of CO₂ capture based on Ca-based sorbents cyclic calcination/carbonation reaction, Bull. Chin. Ceram. Soc. 32(2) (2013) 356-362(in chinese).
[13] A. Antzaraa, E. Heracleous, A.A. Lemonidou, Improving the stability of synthetic CaObased CO₂ sorbents by structural promoters, Appl. Energy 156(2015) 331-343.
[14] H. Yang, Z. Xu, M. Fan, et al., Progress in carbon dioxide separation and capture:A review, J. Environ. Sci. 20(2008) 14-17.
[15] D. Karami, N.Mahinpey, Highly active CaO-based sorbents for CO₂ capture using the precipitation method:Preparation and characterization of the sorbent powder, Ind. Eng. Chem. Res. 51(12) (2012) 4567-4572.
[16] C. Stewart, M.A. Hessami, A study of methods of carbon dioxide capture and sequestration-the sustainability of a photosynthetic bioreactor approach, Energy Convers. Manag. 46(3) (2005) 403-420.
[17] C. Salvador, D. Lu, E.J. Anthony, et al., Enhancement of CaO for CO₂ capture in an fbc environment, Chem. Eng. J. 96(1/3) (2003) 187-195.
[18] H. Gupta, L.S. Fan, Carbonation-calcination cycle using high reactivity calcium oxide for carbon dioxide separation from flue gas, Ind. Eng. Chem. Res. 41(16) (2002) 4035-4042.
[19] D. Dasgupta, K.Mondal, T.Wiltowski, Robust, high reactivity and enhanced capacity carbon dioxide removal agents for hydrogen production applications, Int. J. Hydrog. Energy 33(1) (2008) 303-311.
[20] Y. Li, C. Zhao, C. Qu, et al., CO₂ capture using CaO modified with ethanol/water solution during cyclic calcination/carbonation, Chem. Eng. Technol. 31(2) (2008) 237-244.
[21] Y. Li, C. Zhao, H. Chen, et al., Modified CaO-based sorbent looping cycle for CO₂ mitigation, Fuel 88(4) (2009) 697-704.
[22] V. Manovic, D. Lu, E.J. Anthony, Steam hydration of sorbents from a dual fluidized bed CO₂ looping cycle reactor, Fuel 87(15/16) (2008) 3344-3352.
[23] Z. Li, N. Cai, Y. Huang, et al., Synthesis, experimental studies, and analysis of a new calcium-based carbon dioxide absorbent, Energy Fuel 19(4) (2005) 1447-1452.
[24] C.S. Martavaltzi, A.A. Lemonidou, Parametric study of the CaO-Ca₁₂Al₁₄O₃₃ synthesis with respect to high CO₂ sorption capacity and stability onmulticycle operation, Ind. Eng. Chem. Res. 47(23) (2008) 9537-9543.
[25] Z. Li, N. Cai, Y. Huang, Effect of preparation temperature on cyclic CO₂ capture and multiple carbonation-calcination cycles for a new Ca-based CO₂ sorbent, Ind. Eng. Chem. Res. 45(6) (2006) 1911-1917.
[26] F. Zeman, Effect of steam hydration on performance of lime sorbent for CO₂ capture, Int. J. Greenh. Gas Control 2(2008) 203-209.
[27] R. Sun, Y. Li, H. Liu, et al., CO₂ capture performance of calcium-based sorbent doped with manganese salts during calcium looping cycle, Appl. Energy 89(2012) 368-373.
[28] Y. Li, C. Zhao, H. Chen, Variation behavior of CaO microstructure during cyclic calcination/carbonation, J. Southeast Univ. (Nat. Sci. Ed.) 39(2) (2009) 262-268(in Chinese).
[29] Z. Li, F. Fang, N. Cai, Experimental research on CaO carbonation/calcination cycles in fluidized bed, J. Combust. Sci. Technol. 14(6) (2008) 529-532(in Chinese).
[30] V. Manovic, E.J. Anthony, Thermal activation of CaO-based sorbent and selfreactivation during CO₂ capture looping cycles, Environ. Sci. Technol. 42(2008) 4170-4180.
[31] Y. Guo, C. Zhao, X. Chen, C. Li, CO₂ capture and sorbent regeneration performances of some wood ash materials, Appl. Energy 137(2015) 26-36.
[32] H. Chen, C. Zhao,W. Yu, Calcium-based sorbent doping with attapulgite for CO₂ capture, Appl. Energy 112(2013) 67-74(in Chinese).
[33] G. Wei, C. Zhang, C. Guoliang, et al., Study on archaeological lime powders from Taosi and Yinxu sites by FTIR, Spectrosc. Spectr. Anal. 35(3) (2015) 613-616(in Chinese).
[34] W.C. Yan, D. Liu, D.Y. Tan, et al., FTIR spectroscopy study of the structure changes of palygorskite under heating, Spectrochim. Acta A Mol. Biomol. 97(2012) 1052-1057.

Improvement of CO₂ capture performance of calcium-based absorbent modified with palygorskite

Improvement of CO₂ capture performance of calcium-based absorbent modified with palygorskite

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