A new nanocluster polyoxomolybdate[Mo36O110(NO)4(H2O)14]·52H2O: Synthesis, characterization and application in oxidative degradation of common organic dyes

doi:10.1016/j.cjche.2017.03.031

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (2): 337-342.DOI: 10.1016/j.cjche.2017.03.031

• Catalysis, kinetics and reaction engineering • 上一篇下一篇

A new nanocluster polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O: Synthesis, characterization and application in oxidative degradation of common organic dyes

Mojtaba Amini¹, Mostafa Khaksar¹, Arkady Ellern², L. Keith Woo²

1 Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh 55181-83111, Iran;
2 Chemistry Department, Iowa State University, Ames, IA 50011-3111, USA

收稿日期:2017-01-13 修回日期:2017-03-09 出版日期:2018-02-28 发布日期:2018-03-16
通讯作者: Mojtaba Amini
基金资助:
Supported by the Iranian National Science Foundation (INSF) and University of Maragheh.

A new nanocluster polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O: Synthesis, characterization and application in oxidative degradation of common organic dyes

Mojtaba Amini¹, Mostafa Khaksar¹, Arkady Ellern², L. Keith Woo²

1 Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh 55181-83111, Iran;
2 Chemistry Department, Iowa State University, Ames, IA 50011-3111, USA

Received:2017-01-13 Revised:2017-03-09 Online:2018-02-28 Published:2018-03-16
Contact: Mojtaba Amini
Supported by:
Supported by the Iranian National Science Foundation (INSF) and University of Maragheh.

摘要/Abstract

摘要： Polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O was synthesized by a simple one-pot procedure through reducing an acidified mixture of Na₂MoO₄·2H₂O and NH₂OH·HCl. In order to create a heterogeneous catalyst system, the polyoxomolybdate was pillared with MgAl-LDH-NO₃ by direct ion exchange. These novel materials were carefully analyzed by various chemico-physical methods. The catalytic degradation of methylene blue (MB) and rhodamine B (RB) as common dyes in the presence of MgAl-LDH-1 nanoparticles with aqueous hydrogen peroxide, H₂O₂, as an oxidizing agent was studied in aqueous solution at room temperature. More importantly, the catalyst can be recovered and reused efficiently up to five consecutive cycles with negligible loss of catalytic activity.

关键词: Nanocluster, Polyoxomolybdate, LDH, Methylene blue, Rhodamine B

Abstract: Polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O was synthesized by a simple one-pot procedure through reducing an acidified mixture of Na₂MoO₄·2H₂O and NH₂OH·HCl. In order to create a heterogeneous catalyst system, the polyoxomolybdate was pillared with MgAl-LDH-NO₃ by direct ion exchange. These novel materials were carefully analyzed by various chemico-physical methods. The catalytic degradation of methylene blue (MB) and rhodamine B (RB) as common dyes in the presence of MgAl-LDH-1 nanoparticles with aqueous hydrogen peroxide, H₂O₂, as an oxidizing agent was studied in aqueous solution at room temperature. More importantly, the catalyst can be recovered and reused efficiently up to five consecutive cycles with negligible loss of catalytic activity.

Key words: Nanocluster, Polyoxomolybdate, LDH, Methylene blue, Rhodamine B

Mojtaba Amini, Mostafa Khaksar, Arkady Ellern, L. Keith Woo. A new nanocluster polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O: Synthesis, characterization and application in oxidative degradation of common organic dyes[J]. Chinese Journal of Chemical Engineering, 2018, 26(2): 337-342.

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A new nanocluster polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O: Synthesis, characterization and application in oxidative degradation of common organic dyes

A new nanocluster polyoxomolybdate[Mo₃₆O₁₁₀(NO)₄(H₂O)₁₄]·52H₂O: Synthesis, characterization and application in oxidative degradation of common organic dyes

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