Porous g-C3N4 with enhanced adsorption and visible-light photocatalytic performance for removing aqueous dyes and tetracycline hydrochloride

doi:10.1016/j.cjche.2017.10.010

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (4): 753-760.DOI: 10.1016/j.cjche.2017.10.010

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Porous g-C₃N₄ with enhanced adsorption and visible-light photocatalytic performance for removing aqueous dyes and tetracycline hydrochloride

Junlei Zhang¹, Zhen Ma^1,2

1 Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(LAP3), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China;
2 Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, PR China

收稿日期:2017-09-13 修回日期:2017-10-11 出版日期:2018-04-28 发布日期:2018-05-19
通讯作者: Zhen Ma,E-mail address:zhenma@fudan.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (Grant No. 21477022).

Porous g-C₃N₄ with enhanced adsorption and visible-light photocatalytic performance for removing aqueous dyes and tetracycline hydrochloride

Junlei Zhang¹, Zhen Ma^1,2

1 Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(LAP3), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China;
2 Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, PR China

Received:2017-09-13 Revised:2017-10-11 Online:2018-04-28 Published:2018-05-19
Supported by:
Supported by the National Natural Science Foundation of China (Grant No. 21477022).

摘要/Abstract

摘要： Porous g-C₃N₄ samples were obtained by simply calcining bulk g-C₃N₄ in static air in a muffle oven. The photocatalytic performance of these samples was evaluated through the removal of aqueous organic dyes (methylene blue and methyl orange) and tetracycline hydrochloride under visible-light irradiation (λ > 420 nm). Compared to bulk g-C₃N₄, porous g-C₃N₄ exhibited much better capability for removing these contaminants, especially under visible-light irradiation, due to the enlarged specific surface area and more efficient separation of photogenerated charge carries. In particular, porous g-C₃N₄ obtained by calcining bulk g-C₃N₄ in air at 525℃ showed the highest visible-light-driven catalytic activity among these samples. Superoxide radical anions (·O₂^-) were found to be the primary active species responsible for photodegradation.

关键词: C₃N₄, Catalyst, Reaction, Waste treatment, Dyes, Tetracycline hydrochloride

Abstract: Porous g-C₃N₄ samples were obtained by simply calcining bulk g-C₃N₄ in static air in a muffle oven. The photocatalytic performance of these samples was evaluated through the removal of aqueous organic dyes (methylene blue and methyl orange) and tetracycline hydrochloride under visible-light irradiation (λ > 420 nm). Compared to bulk g-C₃N₄, porous g-C₃N₄ exhibited much better capability for removing these contaminants, especially under visible-light irradiation, due to the enlarged specific surface area and more efficient separation of photogenerated charge carries. In particular, porous g-C₃N₄ obtained by calcining bulk g-C₃N₄ in air at 525℃ showed the highest visible-light-driven catalytic activity among these samples. Superoxide radical anions (·O₂^-) were found to be the primary active species responsible for photodegradation.

Key words: C₃N₄, Catalyst, Reaction, Waste treatment, Dyes, Tetracycline hydrochloride

Junlei Zhang, Zhen Ma. Porous g-C₃N₄ with enhanced adsorption and visible-light photocatalytic performance for removing aqueous dyes and tetracycline hydrochloride[J]. Chinese Journal of Chemical Engineering, 2018, 26(4): 753-760.

参考文献

[1] X.C. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J.M. Carlsson, K. Domen, M. Antonietti, A metal-free polymeric photocatalyst for hydrogen production from water under visible light, Nat. Mater. 8(2009) 76-80.

[2] Y. Wang, X.C. Wang, M. Antonietti, Polymeric graphitic carbon nitride as a heterogeneous organocatalyst:From photochemistry to multipurpose catalysis to sustainable chemistry, Angew. Chem. Int. Ed. 51(2012) 68-89.

[3] X.Q. Fan, L.X. Zhang, R.L. Cheng, M. Wang, M.L. Li, Y.J. Zhou, J.L. Shi, Construction of graphitic C₃N₄-based intramolecular donor-acceptor conjugated copolymers for photocatalytic hydrogen evolution, ACS Catal. 5(2015) 5008-5015.

[4] Q. Han, B. Wang, Y. Zhao, C.G. Hu, L.T. Qu, A graphitic-C₃N₄"seaweed" architecture for enhanced hydrogen evolution, Angew. Chem. Int. Ed. 54(2015) 11433-11437.

[5] F. He, G. Chen, Y.S. Zhou, Y.G. Yu, Y. Zheng, S. Hao, The facile synthesis of mesoporous g-C₃N₄ with highly enhanced photocatalytic H₂ evolution performance, Chem. Commun. 51(2015) 16244-16246.

[6] X.Y. Yuan, C. Zhou, Y.R. Jin, Q.Y. Jing, Y.L. Yang, X. Shen, Q. Tang, Y.H. Mu, A.K. Du, Facile synthesis of 3D porous thermally exfoliated g-C₃N₄ nanosheet with enhanced photocatalytic degradation of organic dye, J. Colloid Interf. Sci. 468(2016) 211-219.

[7] Y.Z. Yu, J.G. Wang, Direct microwave synthesis of graphitic C₃N₄ with improved visible-light photocatalytic activity, Ceram. Int. 42(2016) 4063-4071.

[8] M. Zhang, W.J. Jiang, D. Liu, J. Wang, Y.F. Liu, Y.Y. Zhu, Y.F. Zhu, Photodegradation of phenol via C₃N₄-agar hybrid hydrogel 3D photocatalysts with free separation, Appl. Catal. B-Environ. 183(2016) 263-268.

[9] X.L. Yang, F.F. Qian, G.J. Zou, M.L. Li, J.R. Lu, Y.M. Li, M.T. Bao, Facile fabrication of acidified g-C₃N₄/g-C₃N₄ hybrids with enhanced photocatalysis performance under visible light irradiation, Appl. Catal. B-Environ. 193(2016) 22-35.

[10] Y.J. Cui, Y.B. Tang, X.C. Wang, Template-free synthesis of graphitic carbon nitride hollow spheres for photocatalytic degradation of organic pollutants, Mater. Lett. 161(2015) 197-200.

[11] P.F. Xia, B.C. Zhu, J.G. Yu, S.W. Cao, M. Jaroniec, Ultra-thin nanosheet assemblies of graphitic carbon nitride for enhanced photocatalytic CO₂ reduction, J. Mater. Chem. A 5(2017) 3230-3238.

[12] G.H. Dong, W.K. Ho, Y.H. Li, L.Z. Zhang, Facile synthesis of porous graphene-like carbon nitride (C₆N₉H₃) with excellent photocatalytic activity for NO removal, Appl. Catal. B-Environ. 174(2015) 477-485.

[13] F. Dong, Y.H. Li, Z.Y. Wang, W.K. Ho, Enhanced visible light photocatalytic activity and oxidation ability of porous graphene-like g-C₃N₄ nanosheets via thermal exfoliation, Appl. Surf. Sci. 358(2015) 393-403.

[14] W.K. Ho, Z.Z. Zhang, M.K. Xu, X.W. Zhang, X.X. Wang, Y. Huang, Enhanced visiblelight-driven photocatalytic removal of NO:Effect on layer distortion on g-C₃N₄ by H₂ heating, Appl. Catal. B-Environ. 179(2015) 106-112.

[15] X.F. Chen, J.S. Zhang, X.Z. Fu, M. Antonietti, X.C. Wang, Fe-g-C₃N₄-catalyzed oxidation of benzene to phenol using hydrogen peroxide and visible light, J. Am. Chem. Soc. 131(2009) 11658-11659.

[16] L. Ge, C.C. Han, X.L. Xiao, L.L. Guo, Y.J. Li, Enhanced visible light photocatalytic hydrogen evolution of sulfur-doped polymeric g-C₃N₄ photocatalysts, Mater. Res. Bull. 48(2013) 3919-3925.

[17] K. Wang, Q. Li, B.S. Liu, B. Cheng, W.K. Ho, J.G. Yu, Sulfur-doped g-C₃N₄ with enhanced photocatalytic CO₂ reduction performance, Appl. Catal. B-Environ. 176(2015) 44-52.

[18] J.W. Fu, B.C. Zhu, C.J. Jiang, B. Cheng, Hierarchical porous O-doped g-C₃N₄ with enhanced photocatalytic CO₂ reduction activity, Small 13(2017), 1603938. (9 pages).

[19] X.J She, J.J. Wu, J. Zhong, H. Xu, Y.C. Yang, R. Vajtai, J. Lou, Y. Liu, D.L. Du, H.M. Li, P.M. Ajayan, Oxygenated monolayer carbon nitride for excellent photocatalytic hydrogen evolution and external quantum efficiency, Nano Energy 27(2016) 138-146.

[20] Z.F. Huang, J.J. Song, L. Pan, Z.M. Wang, X.Q. Zhang, J.J. Zou, W.B. Mi, X.W. Zhang, L. Wang, Carbon nitride with simultaneous porous network and O-doping for efficient solar-energy-driven hydrogen evolution, Nano Energy 12(2015) 646-656.

[21] S.C. Yan, Z.S. Li, Z.G. Zou, Photodegradation of rhodamine B and methyl orange over boron-doped g-C₃N₄ under visible light irradiation, Langmuir 26(2010) 3894-3901.

[22] J. Liu, Y. Liu, N.Y. Liu, Y.Z. Han, X. Zhang, H. Huang, Y. Lifshitz, S.T. Lee, J. Zhong, Z.H. Kang, Metal-free efficient photocatalyst for stable visible water splitting via a twoelectron pathway, Science 347(2015) 970-974.

[23] Y.P. Zhu, T.Z. Ren, Z.Y. Yuana, Mesoporous phosphorus-doped g-C₃N₄ nanostructured flowers with superior photocatalytic hydrogen evolution performance, ACS Appl. Mater. Inter. 7(2015) 16850-16856.

[24] J.R. Ran, T.Y. Ma, G.P. Gao, X.W. Du, S.Z. Qiao, Porous P-doped graphitic carbon nitride nanosheets for synergistically enhanced visible-light photocatalytic H₂ production, Energy Environ. Sci. 8(2015) 3708-3717.

[25] Z.A. Lan, G.G. Zhang, X.C. Wang, A facile synthesis of Br-modified g-C₃N₄ semiconductors for photoredox water splitting, Appl. Catal. B-Environ. 192(2016) 116-125.

[26] Y. Shiraishi, Y. Kofuji, S. Kanazawa, H. Sakamoto, S. Ichikawa, S. Tanaka, T. Hirai, Platinum nanoparticles strongly associated with graphitic carbon nitride as efficient cocatalysts for photocatalytic hydrogen evolution under visible light, Chem. Commun. 50(2014) 15255-15258.

[27] S. Samanta, S. Martha, K. Parida, Facile synthesis of Au/g-C₃N₄ nanocomposites:An inorganic/organic hybrid plasmonic photocatalyst with enhanced hydrogen gas evolution under visible-light irradiation, ChemCatChem 6(2014) 1453-1462.

[28] Y.S. Fu, T. Huang, L.L. Zhang, J.W. Zhu, X. Wang, Ag/g-C₃N₄ catalyst with superior catalytic performance for the degradation of dyes:A borohydride-generated superoxide radical approach, Nanoscale 7(2015) 13723-13733.

[29] F. Dong, Z.W. Zhao, Y.J. Sun, Y.X. Zhang, S. Yan, Z.B. Wu, An advanced semimetal-organic Bi spheres-g-C₃N₄ nanohybrid with SPR-enhanced visible-light photocatalytic performance for NO purification, Environ. Sci. Technol. 49(2015) 12432-12440.

[30] Z.W. Zhao, Y.J. Sun, F. Dong, Graphitic carbon nitride based nanocomposites:A review, Nanoscale 7(2015) 15-37.

[31] G. Mamba, A.K. Mishra, Graphitic carbon nitride (g-C₃N₄) nanocomposites:A new and exciting generation of visible light driven photocatalysts for environmental pollution remediation, Appl. Catal. B-Environ. 198(2016) 347-377.

[32] J.L. Zhang, Z. Ma, Novel β-Ag₂MoO₄/g-C₃N₄ heterojunction catalysts with highly enhanced visible-light-driven photocatalytic activity, RSC Adv. 7(2017) 2163-2171.

[33] J.L. Zhang, Z. Ma, Ag₆Mo₁₀O₃₃/g-C₃N₄ 1D-2D hybridized heterojunction as an efficient visible-light-driven photocatalyst, Mol. Catal. 432(2017) 285-291.

[34] M. Groenewolt, M. Antonietti, Synthesis of g-C₃N₄ nanoparticles in mesoporous silica host matrices, Adv. Mater. 17(2005) 1789-1792.

[35] X. Jin, V.V. Balasubramanian, S.T. Selvan, D.P. Sawant, M.A. Chari, G.Q. Lu, A. Vinu, Highly ordered mesoporous carbon nitride nanoparticles with high nitrogen content:A metal-free basic catalyst, Angew. Chem. Int. Ed. 48(2009) 7884-7887.

[36] P. Niu, L.L. Zhang, G. Liu, H.M. Cheng, Graphene-like carbon nitride nanosheets for improved photocatalytic activities, Adv. Funct. Mater. 22(2012) 4763-4770.

[37] S.B. Yang, Y.J. Gong, J.S. Zhang, L. Zhan, L.L. Ma, Z.Y. Fang, R. Vajtai, X.C. Wang, P.M. Ajayan, Exfoliated graphitic carbon nitride nanosheets as efficient catalysts for hydrogen evolution under visible light, Adv. Mater. 25(2013) 2452-2456.

[38] X.J. Bai, L. Wang, R.L. Zong, Y.F. Zhu, Photocatalytic activity enhanced via g-C₃N₄ nanoplates to nanorods, J. Phys. Chem. C 117(2013) 9952-9961.

[39] Y. Zhao, F. Zhao, X.P. Wang, C.Y. Xu, Z.P. Zhang, G.Q. Shi, L.T. Qu, Graphitic carbon nitride nanoribbons:Graphene-assisted formation and synergic function for highly efficient hydrogen evolution, Angew. Chem. Int. Ed. 53(2014) 13934-13939.

[40] Y.S. Jun, E.Z. Lee, X.C. Wang, W.H. Hong, G.D. Stucky, A. Thomas, From melaminecyanuric acid supramolecular aggregates to carbon nitride hollow spheres, Adv. Funct. Mater. 23(2013) 3661-3667.

[41] D.D. Zheng, C.J. Huang, X.C. Wang, Post-annealing reinforced hollow carbon nitride nanospheres for hydrogen photosynthesis, Nanoscale 7(2015) 465-470.

[42] Q. Han, B. Wang, J. Gao, Z.H. Cheng, Y. Zhao, Z.P. Zhang, L.T. Qu, Atomically thin mesoporous nanomesh of graphitic C₃N₄ for high-efficiency photocatalytic hydrogen evolution, ACS Nano 10(2016) 2745-2751.

[43] S.N. Guo, Y. Zhu, Y.Y. Yan, Y.L. Min, J.C. Fan, Q.J. Xu, Holey structured graphitic carbon nitride thin sheets with edge oxygen doping via photo-Fenton reaction with enhanced photocatalytic activity, Appl. Catal. B-Environ. 185(2016) 315-321.

[44] Q.H. Liang, Z. Li, X.L. Yu, Z.H. Huang, F.Y. Kang, Q.H. Yang, Macroscopic 3D porous graphitic carbon nitride monolith for enhanced photocatalytic hydrogen evolution, Adv. Mater. 27(2015) 4634-4639.

[45] L.Q. Yang, J.F. Huang, L. Shi, L.Y. Cao, Q. Yu, Y.N. Jie, J. Fei, H.B. Ouyang, J.H. Ye, A surface modification resultant thermally oxidized porous g-C₃N₄ with enhanced photocatalytic hydrogen production, Appl. Catal. B-Environ. 204(2017) 335-345.

[46] S.W. Cao, J.X. Low, J.G. Yu, M. Jaroniec, Polymeric photocatalysts based on graphitic carbon nitride, Adv. Mater. 27(2015) 2150-2176.

[47] J.L. Zhang, H. Liu, Z. Ma, Flower-like Ag₂O/Bi₂MoO₆ p-n heterojunction with enhanced photocatalytic activity under visible light irradiation, J. Mol. Catal. A Chem. 424(2016) 37-44.

[48] J.L. Zhang, Z. Ma, Flower-like Ag₂MoO₄/Bi₂MoO₆ heterojunctions with enhanced photocatalytic activity under visible light irradiation, J. Taiwan Inst. Chem. Eng. 71(2017) 156-164.

[49] J.L. Zhang, Z. Ma, Flower-like Ag₃VO₄/BiOBr n-p heterojunction photocatalysts with enhanced visible-light-driven catalytic activity, Mol. Catal. 436(2017) 190-198.

[50] J.L. Zhang, Z. Ma, Enhanced visible-light photocatalytic performance of Ag₃VO₄/Bi₂WO₆ heterojunctions in removing aqueous dyes and tetracycline hydrochloride, J. Taiwan Inst. Chem. Eng. 78(2017) 212-218.

[51] J.H. Li, B. Shen, Z.H. Hong, B.Z. Lin, B.F. Gao, Y.L. Chen, A facile approach to synthesize novel oxygen-doped g-C₃N₄ with superior visible-light photoreactivity, Chem. Commun. 48(2012) 12017-12019.

[52] L. Shi, K. Chang, H.B. Zhang, X. Hai, L.Q. Yang, T. Wang, J.H. Ye, Drastic enhancement of photocatalytic activities over phosphoric acid protonated porous g-C₃N₄ nanosheets under visible light, Small 12(2016) 4431-4439.

[53] P. Qiu, H. Chen, C. Xu, N. Zhou, F. Jiang, X. Wang, Y. Fu, Fabrication of an exfoliated graphitic carbon nitride as a highly active visible light photocatalyst, J. Mater. Chem. A 3(2015) 24237-24244.

[54] W.J. Ong, L.L. Tan, Y.H. Ng, S.T. Yong, S.P. Chai, Graphitic carbon nitride (g-C₃N₄)-based photocatalysts for artificial photosynthesis and environmental remediation:Are we a step closer to achieving sustainability? Chem. Rev. 116(2016) 7159-7329.

[55] J.L. Zhang, L.S. Zhang, N. Yu, K.B. Xu, S.J. Li, H.L. Wang, J.S. Liu, Flower-like Bi₂S₃/Bi₂MoO₆ heterojunction superstructures with enhanced visible-light-driven photocatalytic activity, RSC Adv. 5(2015) 75081-75088.

[56] J.L. Zhang, L.S. Zhang, X.F. Shen, P.F. Xu, J.S. Liu, Synthesis of BiOBr/WO₃ p-n heterojunctions with enhanced visible light photocatalytic activity, CrystEngComm 18(2016) 3856-3865.

[57] M. Yan, Y.L. Wu, F.F. Zhu, Y.Q. Hua, W.D. Shi, The fabrication of a novel Ag₃VO₄/WO₃ heterojunction with enhanced visible light efficiency in the photocatalytic degradation of TC, Phys. Chem. Chem. Phys. 18(2016) 3308-3315.

[58] L.F. Yue, S.F. Wang, G.Q. Shan, W. Wu, L.W. Qiang, L.Y. Zhu, Novel MWNTs-Bi₂WO₆ composites with enhanced simulated solar photoactivity toward adsorbed and free tetracycline in water, Appl. Catal. B-Environ. 176(2015) 11-19.

[59] M.L. Li, L.X. Zhang, X.Q. Fan, Y.J. Zhou, M.Y. Wu, J.L. Shi, Highly selective CO₂ photoreduction to CO over g-C₃N₄/Bi₂WO₆ composites under visible light, J. Mater. Chem. A 3(2015) 5189-5196.

[60] S.S. Yi, J.M. Yan, B.R. Wulan, S.J. Li, K.H. Liu, Q. Jiang, Noble-metal-free cobalt phosphide modified carbon nitride:An efficient photocatalyst for hydrogen generation, Appl. Catal. B-Environ. 200(2017) 477-483.

[61] T.T. Zhu, L.Y. Huang, Y.H. Song, Z.G. Chen, H.Y. Ji, Y.P. Li, Y.G. Xu, Q. Zhang, H. Xu, H.M. Li, Modification of Ag₃VO₄ with graphene-like MoS₂ for enhanced visible-light photocatalytic property and stability, New J. Chem. 40(2016) 2168-2177.

[62] Y.F. Li, R.X. Jin, X. Fang, Y. Yang, M. Yang, X.C. Liu, Y. Xing, S.Y. Song, In situ loading of Ag₂WO₄ on ultrathin g-C₃N₄ nanosheets with highly enhanced photocatalytic performance, J. Hazard. Mater. 313(2016) 219-228.

Porous g-C₃N₄ with enhanced adsorption and visible-light photocatalytic performance for removing aqueous dyes and tetracycline hydrochloride

Porous g-C₃N₄ with enhanced adsorption and visible-light photocatalytic performance for removing aqueous dyes and tetracycline hydrochloride

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Jinlong Liu, Chenye Wang, Xingrui Wang, Chen Zhao, Huiquan Li, Ganyu Zhu, Jianbo Zhang. Reconstruction and recovery of anatase TiO₂ from spent selective catalytic reduction catalyst by NaOH hydrothermal method[J]. 中国化学工程学报, 2023, 60(8): 53-60.
[2]	Ming Liu, Ying Li, Rui Wang, Guoqiang Shao, Pengpeng Lv, Jun Li, Qingshan Zhu. Uniform deposition of ultra-thin TiO₂ film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration[J]. 中国化学工程学报, 2023, 60(8): 99-107.
[3]	Eileen Katherine Coronado-Aldana, Cindy Lizeth Ferreira-Salazar, Nubia Yineth Piñeros-Castro, Rubén Vázquez-Medina, Felipe A. Perdomo. Thermodynamic analysis, synthesis, characterization, and evaluation of 1-ethyl-3-methylimidazolium chloride: Study of its effect on pretreated rice husk[J]. 中国化学工程学报, 2023, 60(8): 143-154.
[4]	Yifan Jiang, Bingqi Xie, Jisong Zhang. Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction[J]. 中国化学工程学报, 2023, 60(8): 165-172.
[5]	Peipei Ai, Huiqing Jin, Jie Li, Xiaodong Wang, Wei Huang. Ultra-stable Cu-based catalyst for dimethyl oxalate hydrogenation to ethylene glycol[J]. 中国化学工程学报, 2023, 60(8): 186-193.
[6]	Yuehua Liu, Lili Chen, Shoujun Liu, Song Yang, Ju Shangguan. Role of iron-based catalysts in reducing NO_x emissions from coal combustion[J]. 中国化学工程学报, 2023, 59(7): 1-8.
[7]	Haixiang Liu, Jun Zhang, Chunlei Dong, Gang Zhu, Guanben Du, Shuduan Deng. Synthesis, performance and structure characterization of glyoxal-monomethylolurea-melamine (G-MMU-M) co-condensed resin[J]. 中国化学工程学报, 2023, 59(7): 92-104.
[8]	Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang. Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling[J]. 中国化学工程学报, 2023, 59(7): 105-117.
[9]	Fei Li, Xuemei Wang, Pengze Zhang, Qinqin Wang, Mingyuan Zhu, Bin Dai. Nitrogen and phosphorus co-doped activated carbon induces high density Cu⁺ active center for acetylene hydrochlorination[J]. 中国化学工程学报, 2023, 59(7): 193-199.
[10]	Zhonghao Li, Yuanyuan Yang, Huanong Cheng, Yun Teng, Chao Li, Kangkang Li, Zhou Feng, Hongwei Jin, Xinshun Tan, Shiqing Zheng. Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid[J]. 中国化学工程学报, 2023, 59(7): 210-221.
[11]	Runze Chen, Yuran Chen, Xuemin Liang, Yapeng Kong, Yangyang Fan, Quan Liu, Zhenyu Yang, Feiying Tang, Johnny Muya Chabu, Maru Dessie Walle, Liqiang Wang. Oxidative exfoliation of spent cathode carbon: A two-in-one strategy for its decontamination and high-valued application[J]. 中国化学工程学报, 2023, 59(7): 262-269.
[12]	Qunfeng Zhang, Bingcheng Li, Yuan Zhou, Deshuo Zhang, Chunshan Lu, Feng Feng, Jinghui Lv, Qingtao Wang, Xiaonian Li. Regulation of the selective hydrogenation performance of sulfur-doped carbon-supported palladium on chloronitrobenzene[J]. 中国化学工程学报, 2023, 58(6): 69-75.
[13]	Pengcheng Zou, Kai Wang. Methanolysis of amides under high-temperature and high-pressure conditions with a continuous tubular reactor[J]. 中国化学工程学报, 2023, 58(6): 170-178.
[14]	Xinyu Liu, Hongliang Sheng, Song He, Chunhua Du, Yuansheng Ma, Chichi Ruan, Chunxiang He, Huaming Dai, Yajun Huang, Yuelei Pan. Insight into pyrolysis of hydrophobic silica aerogels: Kinetics, reaction mechanism and effect on the aerogels[J]. 中国化学工程学报, 2023, 58(6): 266-281.
[15]	Haike Li, Xindong Li, Guozai Ouyang, Lang Li, Zhaohuang Zhong, Meng Cai, Wenhao Li, Wanfu Huang. Tannic acid/Fe³⁺ interlayer for preparation of high-permeability polyetherimide organic solvent nanofiltration membranes for organic solvent separation[J]. 中国化学工程学报, 2023, 57(5): 17-29.