Preparation of new and novel wave like poly(2-anisidine) zirconium tungstate nanocomposite: Thermal, electrical and ion-selective studies

doi:10.1016/j.cjche.2018.03.028

Chinese Journal of Chemical Engineering ›› 2019, Vol. 27 ›› Issue (2): 459-466.DOI: 10.1016/j.cjche.2018.03.028

• Energy, Resources and Environmental Technology • 上一篇下一篇

Preparation of new and novel wave like poly(2-anisidine) zirconium tungstate nanocomposite: Thermal, electrical and ion-selective studies

Anish Khan^1,2, Aftab Aslam Parwaz Khan^1,2, Mahmoud A. Hussein^1,3, Bernaurdshaw Neppolian⁴, Abdullah M. Asiri^1,2

1 Chemistry Department, King Abdulaziz University, Jeddah 21589, Saudi Arabia;
2 Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia;
3 Polymer Chemistry Laboratory, Chemistry Department, Faculty of Science, Assiut University, 71516 Assiut, Egypt;
4 SRM Research Institute, SRM University, Kattankulathur, Chennai 603203, Tamil Nadu, India

收稿日期:2018-01-14 修回日期:2018-03-07 出版日期:2019-02-28 发布日期:2019-03-18
通讯作者: Anish Khan

Preparation of new and novel wave like poly(2-anisidine) zirconium tungstate nanocomposite: Thermal, electrical and ion-selective studies

Anish Khan^1,2, Aftab Aslam Parwaz Khan^1,2, Mahmoud A. Hussein^1,3, Bernaurdshaw Neppolian⁴, Abdullah M. Asiri^1,2

1 Chemistry Department, King Abdulaziz University, Jeddah 21589, Saudi Arabia;
2 Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia;
3 Polymer Chemistry Laboratory, Chemistry Department, Faculty of Science, Assiut University, 71516 Assiut, Egypt;
4 SRM Research Institute, SRM University, Kattankulathur, Chennai 603203, Tamil Nadu, India

Received:2018-01-14 Revised:2018-03-07 Online:2019-02-28 Published:2019-03-18
Contact: Anish Khan

摘要/Abstract

摘要： It is necessary to synthesize new material for the advancements of the technology. In this study, new and novel poly (2-anisidine)@zirconium tungstate (P2A/ZrW₂O₈) was synthesized by simple so-gel method. Physicochemical characterization of P2A/ZrW₂O₈ was done by thermogravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), ion exchange and simultaneous four probe dc conductivity studies. The conductivity study revealed its highly semiconducting nature, in the range of 10^-1-10^-2 S·cm^-1. Ion-exchange capabilities of the composite make it applicable for cation-exchange studies. The result of distribution studies (K_d) revealed its selectivity towards Cd²⁺ compared to other metal ions. This property of the composite was utilized for designing Cd²⁺ selective membrane electrode. Several important physical parameters of the ion-selective electrode were determined, such as Nernstian slope (32.32 mV·decade^-1), working pH range was 2.0-4.0 and response time was found~17 s. The analytical utility of this wave like composite membrane electrode was as, indicator electrode in various potentiometric titrations.

关键词: Conducting polymers, Electrochemistry, Ion-exchangers, Electrode, Cd²⁺, Poly(2-anisidine)

Abstract: It is necessary to synthesize new material for the advancements of the technology. In this study, new and novel poly (2-anisidine)@zirconium tungstate (P2A/ZrW₂O₈) was synthesized by simple so-gel method. Physicochemical characterization of P2A/ZrW₂O₈ was done by thermogravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), ion exchange and simultaneous four probe dc conductivity studies. The conductivity study revealed its highly semiconducting nature, in the range of 10^-1-10^-2 S·cm^-1. Ion-exchange capabilities of the composite make it applicable for cation-exchange studies. The result of distribution studies (K_d) revealed its selectivity towards Cd²⁺ compared to other metal ions. This property of the composite was utilized for designing Cd²⁺ selective membrane electrode. Several important physical parameters of the ion-selective electrode were determined, such as Nernstian slope (32.32 mV·decade^-1), working pH range was 2.0-4.0 and response time was found~17 s. The analytical utility of this wave like composite membrane electrode was as, indicator electrode in various potentiometric titrations.

Key words: Conducting polymers, Electrochemistry, Ion-exchangers, Electrode, Cd²⁺, Poly(2-anisidine)

Anish Khan, Aftab Aslam Parwaz Khan, Mahmoud A. Hussein, Bernaurdshaw Neppolian, Abdullah M. Asiri. Preparation of new and novel wave like poly(2-anisidine) zirconium tungstate nanocomposite: Thermal, electrical and ion-selective studies[J]. Chinese Journal of Chemical Engineering, 2019, 27(2): 459-466.

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Preparation of new and novel wave like poly(2-anisidine) zirconium tungstate nanocomposite: Thermal, electrical and ion-selective studies

Preparation of new and novel wave like poly(2-anisidine) zirconium tungstate nanocomposite: Thermal, electrical and ion-selective studies

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