Thermal conductivity of natural rubber nanocomposites with hybrid fillers

doi:10.1016/j.cjche.2018.09.019

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (4): 928-934.DOI: 10.1016/j.cjche.2018.09.019

• Energy, Resources and Environmental Technology • 上一篇下一篇

Thermal conductivity of natural rubber nanocomposites with hybrid fillers

Junping Song¹, Xiteng Li¹, Kaiyan Tian¹, Lianxiang Ma¹, Wei Li², Shichune Yao³

1 Key Laboratory of Rubber-plastics, Ministry of Education, Shandong Provincial Key Laboratory of Rubber-plastics, Chinese and German School of Science and Technology, College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China;
2 Department of Energy Engineering, Zhejiang University, Hangzhou 310027, China;
3 Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213-3890, USA

收稿日期:2018-04-23 修回日期:2018-08-07 出版日期:2019-04-28 发布日期:2019-06-14
通讯作者: Junping Song
基金资助:
Supported by the National Natural Science Foundation of China (51606107, 51576102), and the Collaborative Innovation Project of Green Tire and Rubber (0200501436).

Thermal conductivity of natural rubber nanocomposites with hybrid fillers

Junping Song¹, Xiteng Li¹, Kaiyan Tian¹, Lianxiang Ma¹, Wei Li², Shichune Yao³

1 Key Laboratory of Rubber-plastics, Ministry of Education, Shandong Provincial Key Laboratory of Rubber-plastics, Chinese and German School of Science and Technology, College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China;
2 Department of Energy Engineering, Zhejiang University, Hangzhou 310027, China;
3 Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213-3890, USA

Received:2018-04-23 Revised:2018-08-07 Online:2019-04-28 Published:2019-06-14
Contact: Junping Song
Supported by:
Supported by the National Natural Science Foundation of China (51606107, 51576102), and the Collaborative Innovation Project of Green Tire and Rubber (0200501436).

摘要/Abstract

摘要： Natural rubber nanocomposites filled with hybrid fillers of multi-walled carbon nanotubes (CNTs) and carbon black (CB) were prepared. CNTs were ultrasonically modified in mixture of hydrogen peroxide (H₂O₂) and distilled water (H₂O). The functional groups on the surface of CNTs, changes in nanotube structure and morphology were characterized by Fourier transform infrared spectroscopy (FT-IR), Raman Spectroscopy, and transmission electron microscopy (TEM). It shows that hydroxyl (OH·) is successfully introduced. The surface defects of modified CNTs were obviously higher than those of original CNTs, and the degree of agglomeration was greatly reduced. Thermal conductivity of the composites was tested by protection heat flow meter method. Compared with unmodified CNTs/CB filling system, the thermal conductivity of hybrid composites is improved by an average of 5.8% with 1.5 phr (phr is parts per hundred rubber) of hydroxyl CNTs and 40 phr of CB filled. A three-dimensional heat conduction network composed of hydroxyl CNTs and CB, as observed by TEM, contributes to the good properties. Thermal conductivity of the hybrid composites increases as temperature rises. The mechanical properties of hybrid composites are also good with hydroxyl CNTs filled nanocomposites; the tensile strength, 100% and 300% tensile stress are improved by 10.1%, 22.4% and 26.2% respectively.

关键词: Modified carbon nanotube, Carbon black, Hybrid filler, Natural rubber, Thermal conductivity

Abstract: Natural rubber nanocomposites filled with hybrid fillers of multi-walled carbon nanotubes (CNTs) and carbon black (CB) were prepared. CNTs were ultrasonically modified in mixture of hydrogen peroxide (H₂O₂) and distilled water (H₂O). The functional groups on the surface of CNTs, changes in nanotube structure and morphology were characterized by Fourier transform infrared spectroscopy (FT-IR), Raman Spectroscopy, and transmission electron microscopy (TEM). It shows that hydroxyl (OH·) is successfully introduced. The surface defects of modified CNTs were obviously higher than those of original CNTs, and the degree of agglomeration was greatly reduced. Thermal conductivity of the composites was tested by protection heat flow meter method. Compared with unmodified CNTs/CB filling system, the thermal conductivity of hybrid composites is improved by an average of 5.8% with 1.5 phr (phr is parts per hundred rubber) of hydroxyl CNTs and 40 phr of CB filled. A three-dimensional heat conduction network composed of hydroxyl CNTs and CB, as observed by TEM, contributes to the good properties. Thermal conductivity of the hybrid composites increases as temperature rises. The mechanical properties of hybrid composites are also good with hydroxyl CNTs filled nanocomposites; the tensile strength, 100% and 300% tensile stress are improved by 10.1%, 22.4% and 26.2% respectively.

Key words: Modified carbon nanotube, Carbon black, Hybrid filler, Natural rubber, Thermal conductivity

Junping Song, Xiteng Li, Kaiyan Tian, Lianxiang Ma, Wei Li, Shichune Yao. Thermal conductivity of natural rubber nanocomposites with hybrid fillers[J]. 中国化学工程学报, 2019, 27(4): 928-934.

Junping Song, Xiteng Li, Kaiyan Tian, Lianxiang Ma, Wei Li, Shichune Yao. Thermal conductivity of natural rubber nanocomposites with hybrid fillers[J]. Chinese Journal of Chemical Engineering, 2019, 27(4): 928-934.

参考文献

[1] C.K. Leong, D.D.L. Chung, Carbon black dispersions as thermal pastes that surpass solder in providing high thermal contact conductance, Carbon 41(2003) 2459-2469.
[2] J.P. Song, L.X. Ma, Y. He, W. Li, S.C. Yao, Discuss about thermal conductivity of carbon black filled rubber, Spec. Top. Rev. Porous Media Int. J. 6(2015) 159-172.
[3] S. Iijima, Helical microtubules of graphitic carbon, Nature 354(1991) 56-58.
[4] Z.D. Han, A. Fina, Thermal conductivity of carbon nanotubes and their polymer nanocomposites:A review, Prog. Polym. Sci. 7(2011) 914-944.
[5] R. Sadri, G. Ahmadi, H. Togun, M. Dahari, S.N. Kazi, E. Sadeghinezhad, N. Zubir, An experimental study on thermal conductivity and viscosity of nanofluids containing carbon nanotubes, Nanoscale Res. Lett. 9(2014) 1-6.
[6] X.L. Pang, H.L. Peng, H.S. Yang, K.W. Gao, X.L. Wu, A.A. Volinsky, Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes, Chem. Eng. Res. Des. 91(2013) 361-368.
[7] B. Arash, Q. Wang, V.K. Varadan, Mechanical properties of carbon nanotube/polymer composites, Polym. Mater. Sci. Eng. 4(2008) 1-8.
[8] J.N. Coleman, U. Khan, W.J. Blau, Y.K. Gun Ko, Small but strong:A review of the mechanical properties of carbon nanotube-polymer composites, Carbon 44(2006) 1624-1652.
[9] F. Liu, N. Hu, H. Ning, S. Atobe, C. Yan, Y. Liu, L. Wu, X. Liu, S. Fu, C. Xu, Investigation on the interfacial mechanical properties of hybrid graphene-carbon nanotube/polymer nanocomposites, Carbon 115(2017) 694-700.
[10] H.S. Patanwala, D. Hong, S.R. Vora, B. Bognet, A.W.K. Ma, The microstructure and mechanical properties of 3D printed carbon nanotube-polylactic acid composites, Polym. Compos. (2018) E1060-E1071.
[11] J.M. Park, G.Y. Gu, Z.J. Wang, D.J. Kwon, K.L. Devries, Interfacial durability and electrical properties of CNT or ITO/PVDF nanocomposites for self-sensor and micro actuator applications, Appl. Surf. Sci. 287(2013) 75-83.
[12] C. Yuan, Y. Long, L. Hou, J. Li, Y. Sun, X. Zhang, L. Shen, X. Lu, S. Xiong, W.L. Xiong, Flexible hybrid paper made of monolayer co 3 O 4 microsphere arrays on rGO/CNTs and their application in electrochemical capacitors, Adv. Funct. Mater. 22(2012) 2560-2566.
[13] E. Piesowicz, I. Irska, K. Bryll, K. Gawdzinska, M. Bratychak, Poly(Butylene Terephthalate)/Carbon Nanotubes Nanocomposites. Part Ⅱ. Structure and Properties, Sociedad Española De Historia De Las Ciencias Y De Las Técnicas Sehcyt, 201689-111.
[14] Y.K. Su, I.M. Kwon, Y.G. Kim, S. Lee, Y.S. Seo, A large increase in the thermal conductivity of carbon nanotube/polymer composites produced by percolation phenomena, Carbon 55(2013) 285-290.
[15] H.S. Kim, J. Jang, J. Yu, S.Y. Kim, Thermal conductivity of polymer composites based on the length of multi-walled carbon nanotubes, Compos. Part B 79(2015) 505-512.
[16] J. Yu, H.K. Choi, H.S. Kim, S.Y. Kim, Synergistic effect of hybrid graphene nanoplatelet and multi-walled carbon nanotube fillers on the thermal conductivity of polymer composites and theoretical modeling of the synergistic effect, Compos. A:Appl. Sci. Manuf. 88(2016) 79-85.
[17] T. Jose, G. Moni, S. S., A.J. Raju, J.J. George, S.C. George, Multifunctional multi-walled carbon nanotube reinforced natural rubber nanocomposites, Ind. Crop. Prod. 105(2017) 63-73.
[18] G.P. Jin, Q. Cheng, J. Lu, J. Bao, S. Li, Y. Tian, Z. Liang, C. Zhang, B. Wang, Thermal conductivity of MWCNT/epoxy composites:The effects of length, alignment and functionalization, Carbon 50(2012) 2083-2090.
[19] I.N. Mazov, I.A. Ilinykh, V.L. Kuznetsov, A.A. Stepashkin, K.S. Ergin, D.S. Muratov, V.V. Tcherdyntsev, D.V. Kuznetsov, J.P. Issi, Thermal conductivity of polypropylene-based composites with multiwall carbon nanotubes with different diameter and morphology, J. Alloys Compd. 586(2014) S440-S442.
[20] P.C. Ma, N.A. Siddiqui, G. Marom, J.K. Kim, Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites:A review, Compos. A 41(2010) 1345-1367.
[21] F.H. Gojny, M.H.G. Wichmann, B. Fiedler, I.A. Kinloch, W. Bauhofer, A.H. Windle, K. Schulte, Evaluation and identification of electrical and thermal conduction mechanisms in carbon nanotube/epoxy composites, Polymer 47(2006) 2036-2045.
[22] Y. Chen, B. Zhang, Z. Gao, C. Chen, S. Zhao, Y. Qin, Functionalization of multiwalled carbon nanotubes with uniform polyurea coatings by molecular layer deposition, Carbon 82(2015) 470-478.
[23] P. Bilalis, D. Katsigiannopoulos, A. Avgeropoulos, G. Sakellariou, Non-covalent functionalization of carbon nanotubes with polymers, RSC Adv. 4(2014) 2911-2934.
[24] N. Shenogina, S. Shenogin, L. Xue, P. Keblinski, On the lack of thermal percolation in carbon nanotube composites, Appl. Phys. Lett. 87(2005) Z3-Z28.
[25] M.T. Byrne, Y.K. Gun'Ko, Recent advances in research on carbon nanotube-polymer composites, Adv. Mater. 22(2010) 1672-1688.
[26] C. Li, E.T. Thostenson, T.W. Chou, Sensors and actuators based on carbon nanotubes and their composites:A review, Compos. Sci. Technol. 68(2008) 1227-1249.
[27] R.F. Gibson, E.O. Ayorinde, Y.F. Wen, Vibrations of carbon nanotubes and their composites:A review, Compos. Sci. Technol. 67(2007) 1-28.
[28] J.N. Coleman, U. Khan, Y.K. Gun'Ko, Mechanical reinforcement of polymers using carbon nanotubes, Adv. Mater. 18(2006) 689-706.
[29] J. Zhang, H.L. Zou, Q. Qing, Y.L. Yang, Q.W. Li, Z.F. Liu, X.Y. Guo, Z. Du, Effect of chemical oxidation on the structure of single-walled carbon nanotubes, J. Phys. Chem. B 107(2015) 3712-3718.
[30] K.Y. Lee, W.M. Yeoh, S.P. Chai, S. Ichikawa, A.R. Mohamed, The role of water vapor in carbon nanotube formation via water-assisted chemical vapor deposition of methane, J. Ind. Eng. Chem. 18(2012) 1504-1511.
[31] S.A. Chernyak, A.S. Ivanov, K.I. Maslakov, A.V. Egorov, Z. Shen, S.S. Savilov, V.V. Lunin, Oxidation, defunctionalization and catalyst life cycle of carbon nanotubes:A Raman spectroscopy view, Phys. Chem. Chem. Phys. 19(2017) 2276-2285.
[32] A. Cummings, M. Osman, D. Srivastava, M. Menon, Thermal conductivity of Y-junction carbon nanotubes, Phys. Rev. B Condens. Matter 70(2004) 2516-2528.
[33] F.Y. Meng, S. Ogata, D.S. Xu, Y. Shibutani, S.Q. Shi, Thermal conductivity of an ultrathin carbon nanotube with an X-shaped junction, Phys. Rev. B 75(2007) 205403.
[34] R. Bhandari, N. Dhiman, C. Bajaj, P. Jindal, K. Dharamvir, V.K. Jindal, Modification of thermal conductivity of PMMA and PC by making their nanocomposites with carbon nanotubes, Physics 38(2015) 1395-1398.

Thermal conductivity of natural rubber nanocomposites with hybrid fillers

Thermal conductivity of natural rubber nanocomposites with hybrid fillers

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