Calcium looping heat storage performance and mechanical property of CaO-based pellets under fluidization

doi:10.1016/j.cjche.2020.10.002

中国化学工程学报 ›› 2021, Vol. 36 ›› Issue (8): 170-180.DOI: 10.1016/j.cjche.2020.10.002

• Energy Science and Technology • 上一篇下一篇

Calcium looping heat storage performance and mechanical property of CaO-based pellets under fluidization

Zhangke Ma¹, Yingjie Li¹, Boyu Li¹, Zeyan Wang², Tao Wang³, Wentao Lei³

1 School of Energy and Power Engineering, Shandong University, Jinan 250061, China;
2 State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China;
3 Shandong Naxin Electric Power Technology Co., Ltd., Jinan 250101, China

收稿日期:2020-08-29 修回日期:2020-10-04 出版日期:2021-08-28 发布日期:2021-09-30
通讯作者: Yingjie Li
基金资助:
This research was supported by the National Natural Science Foundation of China (51876105), the Fundamental Research Funds of Shandong University (2018JC039) and Major Scientific and Technological Innovation Projects of Key Research & Development Program of Shandong Province (2019JZZY020118).

Calcium looping heat storage performance and mechanical property of CaO-based pellets under fluidization

Zhangke Ma¹, Yingjie Li¹, Boyu Li¹, Zeyan Wang², Tao Wang³, Wentao Lei³

1 School of Energy and Power Engineering, Shandong University, Jinan 250061, China;
2 State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China;
3 Shandong Naxin Electric Power Technology Co., Ltd., Jinan 250101, China

Received:2020-08-29 Revised:2020-10-04 Online:2021-08-28 Published:2021-09-30
Contact: Yingjie Li
Supported by:
This research was supported by the National Natural Science Foundation of China (51876105), the Fundamental Research Funds of Shandong University (2018JC039) and Major Scientific and Technological Innovation Projects of Key Research & Development Program of Shandong Province (2019JZZY020118).

摘要/Abstract

摘要： The CaO-based pellets were fabricated using extrusion-spheronization method for calcium looping thermochemical heat storage under the fluidization. The effects of adhesive, biomass-based pore-forming agent, binder and particle size on the heat storage performance and mechanical property of the CaO-based pellets were investigated in a bubbling fluidized bed reactor. The addition of 2% (mass) polyvinylpyrrolidone as an adhesive not only helps granulate, but also improves the heat storage capacity of the pellets. All biomass-templated CaO-based pellets display higher heat storage capacity than biomass-free pellets, indicating that the biomass-based pore-forming agent is beneficial for heat storage under the fluidization. Especially, bagasse-templated pellets show the highest heat storage conversion of 0.61 after 10 cycles. Moreover, Al₂O₃ as a binder for the pellets helps obtain high mechanical strength. The CaO-based pellets doped with 10% (mass) bagasse and 5% (mass) Al₂O₃ reach the highest heat storage density of 1621 kJ·kg^-1 after 30 cycles and the highest crushing strength of 4.98 N. The microstructure of the bagasse-templated pellets appears more porous than that of biomass-free pellets. The bagasse-templated CaO-based pellets doped with Al₂O₃ seem promising for thermochemical heat storage under the fluidization, owing to the enhanced heat storage capacity, excellent mechanical strength, and simplicity of the synthesis procedure.

关键词: Calcium looping heat storage, Fluidization, CaO-based pellets, Mechanical property

Abstract: The CaO-based pellets were fabricated using extrusion-spheronization method for calcium looping thermochemical heat storage under the fluidization. The effects of adhesive, biomass-based pore-forming agent, binder and particle size on the heat storage performance and mechanical property of the CaO-based pellets were investigated in a bubbling fluidized bed reactor. The addition of 2% (mass) polyvinylpyrrolidone as an adhesive not only helps granulate, but also improves the heat storage capacity of the pellets. All biomass-templated CaO-based pellets display higher heat storage capacity than biomass-free pellets, indicating that the biomass-based pore-forming agent is beneficial for heat storage under the fluidization. Especially, bagasse-templated pellets show the highest heat storage conversion of 0.61 after 10 cycles. Moreover, Al₂O₃ as a binder for the pellets helps obtain high mechanical strength. The CaO-based pellets doped with 10% (mass) bagasse and 5% (mass) Al₂O₃ reach the highest heat storage density of 1621 kJ·kg^-1 after 30 cycles and the highest crushing strength of 4.98 N. The microstructure of the bagasse-templated pellets appears more porous than that of biomass-free pellets. The bagasse-templated CaO-based pellets doped with Al₂O₃ seem promising for thermochemical heat storage under the fluidization, owing to the enhanced heat storage capacity, excellent mechanical strength, and simplicity of the synthesis procedure.

Key words: Calcium looping heat storage, Fluidization, CaO-based pellets, Mechanical property

Zhangke Ma, Yingjie Li, Boyu Li, Zeyan Wang, Tao Wang, Wentao Lei. Calcium looping heat storage performance and mechanical property of CaO-based pellets under fluidization[J]. 中国化学工程学报, 2021, 36(8): 170-180.

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Calcium looping heat storage performance and mechanical property of CaO-based pellets under fluidization

Calcium looping heat storage performance and mechanical property of CaO-based pellets under fluidization

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