A panoramic view of Li7P3S11 solid electrolytes synthesis, structural aspects and practical challenges for all-solid-state lithium batteries

doi:10.1016/j.cjche.2021.09.021

中国化学工程学报 ›› 2021, Vol. 39 ›› Issue (11): 16-36.DOI: 10.1016/j.cjche.2021.09.021

A panoramic view of Li₇P₃S₁₁ solid electrolytes synthesis, structural aspects and practical challenges for all-solid-state lithium batteries

Muhammad Khurram Tufail¹, Niaz Ahmad¹, Le Yang¹, Lei Zhou¹, Muhammad Adnan Naseer², Renjie Chen^2,3, Wen Yang¹

1 Key Laboratory of Cluster Science of Ministry of Education Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China;
2 School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;
3 Institute of Advanced Technology, Beijing Institute of Technology, Jinan 250300, China

收稿日期:2021-04-15 修回日期:2021-09-02 出版日期:2021-11-28 发布日期:2021-12-27
通讯作者: Renjie Chen, Wen Yang
基金资助:
This work was supported by the National Natural Science Foundation of China (51772030, 21203008, 21975025), the Natural Science Foundation of Beijing (2172051), Beijing Outstanding Young Scientists Program (BJJWZYJH01201910007023), and the State Key Laboratory funding by the project for Modification of Chemical Fibers and Polymer Materials, Donghou University.

A panoramic view of Li₇P₃S₁₁ solid electrolytes synthesis, structural aspects and practical challenges for all-solid-state lithium batteries

Muhammad Khurram Tufail¹, Niaz Ahmad¹, Le Yang¹, Lei Zhou¹, Muhammad Adnan Naseer², Renjie Chen^2,3, Wen Yang¹

1 Key Laboratory of Cluster Science of Ministry of Education Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China;
2 School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;
3 Institute of Advanced Technology, Beijing Institute of Technology, Jinan 250300, China

Received:2021-04-15 Revised:2021-09-02 Online:2021-11-28 Published:2021-12-27
Contact: Renjie Chen, Wen Yang
Supported by:
This work was supported by the National Natural Science Foundation of China (51772030, 21203008, 21975025), the Natural Science Foundation of Beijing (2172051), Beijing Outstanding Young Scientists Program (BJJWZYJH01201910007023), and the State Key Laboratory funding by the project for Modification of Chemical Fibers and Polymer Materials, Donghou University.

摘要/Abstract

摘要： The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm^-1, and deformability, the sulfide-based Li₇P₃S₁₁ solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li₇P₃S₁₁ could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li₇P₃S₁₁-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries.

关键词: Li₇P₃S₁₁ solid electrolyte, 30Li₂S-70P₂S₅ glass ceramics, Chemical stability, Electrolyte/electrode interphase, High energy density all-solid-state lithium batteries

Abstract: The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm^-1, and deformability, the sulfide-based Li₇P₃S₁₁ solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li₇P₃S₁₁ could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li₇P₃S₁₁-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries.

Key words: Li₇P₃S₁₁ solid electrolyte, 30Li₂S-70P₂S₅ glass ceramics, Chemical stability, Electrolyte/electrode interphase, High energy density all-solid-state lithium batteries

Muhammad Khurram Tufail, Niaz Ahmad, Le Yang, Lei Zhou, Muhammad Adnan Naseer, Renjie Chen, Wen Yang. A panoramic view of Li₇P₃S₁₁ solid electrolytes synthesis, structural aspects and practical challenges for all-solid-state lithium batteries[J]. 中国化学工程学报, 2021, 39(11): 16-36.

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A panoramic view of Li₇P₃S₁₁ solid electrolytes synthesis, structural aspects and practical challenges for all-solid-state lithium batteries

A panoramic view of Li₇P₃S₁₁ solid electrolytes synthesis, structural aspects and practical challenges for all-solid-state lithium batteries

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