Hydrate formation from liquid CO2 in a glass beads bed

doi:10.1016/j.cjche.2022.01.008

中国化学工程学报 ›› 2022, Vol. 43 ›› Issue (3): 185-191.DOI: 10.1016/j.cjche.2022.01.008

Hydrate formation from liquid CO₂ in a glass beads bed

Nan Li¹, Jing-Yu Kan¹, Chang-Yu Sun², Guang-Jin Chen²

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing at Karamay, Karamay 834000, China;
2. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China

收稿日期:2021-07-23 修回日期:2021-12-07 出版日期:2022-03-28 发布日期:2022-04-28
通讯作者: Nan Li,E-mail:linan@cupk.edu.cn
基金资助:
This work was financially supported by the National Natural Science Foundation of China (No. 22008258), Tianshan Youth Program in Xinjiang Uygur Autonomous Region (2019Q089) and the Scientific Research Program of Universities in Xinjiang Uygur Autonomous Region (XJEDU2019Y069).

Hydrate formation from liquid CO₂ in a glass beads bed

Nan Li¹, Jing-Yu Kan¹, Chang-Yu Sun², Guang-Jin Chen²

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing at Karamay, Karamay 834000, China;
2. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China

Received:2021-07-23 Revised:2021-12-07 Online:2022-03-28 Published:2022-04-28
Contact: Nan Li,E-mail:linan@cupk.edu.cn
Supported by:
This work was financially supported by the National Natural Science Foundation of China (No. 22008258), Tianshan Youth Program in Xinjiang Uygur Autonomous Region (2019Q089) and the Scientific Research Program of Universities in Xinjiang Uygur Autonomous Region (XJEDU2019Y069).

摘要/Abstract

摘要： CO₂ sequestration in marine sediments as solid hydrates is a potential way to capture and store anthropogenic CO₂. In this study, hydrate formation from liquid CO₂ in marine sediments was simulated in a glass beads bed, and the factors affecting the kinetics of hydrate formation were investigated. The results indicated that the rapid initial hydrate formation with a high driving force always increases the mass transfer resistance, which slows down hydrate growth. The final ratio of water conversion is higher under conditions of low temperature and higher pressure. A smaller particle size is conductive to initial CO₂ hydrate growth, but the water conversion ratio in a bed with larger particles is slightly higher. Compared with other factors, the change in water saturation has an obvious effect on the final water conversion. To inhibit the initial hydrate formation during the injection process, in this paper, a kinetic inhibitor is proposed for pre-injection into marine sediments. This work shows that at a low pressure, a low-concentration inhibitor has an obvious inhibition effect on hydrate growth. However, at a high pressure, it is necessary to increase the concentration of inhibitor to produce an obvious inhibition effect.

关键词: Liquid CO₂, Hydrate formation, Sequestration, Kinetic, Water conversion

Abstract: CO₂ sequestration in marine sediments as solid hydrates is a potential way to capture and store anthropogenic CO₂. In this study, hydrate formation from liquid CO₂ in marine sediments was simulated in a glass beads bed, and the factors affecting the kinetics of hydrate formation were investigated. The results indicated that the rapid initial hydrate formation with a high driving force always increases the mass transfer resistance, which slows down hydrate growth. The final ratio of water conversion is higher under conditions of low temperature and higher pressure. A smaller particle size is conductive to initial CO₂ hydrate growth, but the water conversion ratio in a bed with larger particles is slightly higher. Compared with other factors, the change in water saturation has an obvious effect on the final water conversion. To inhibit the initial hydrate formation during the injection process, in this paper, a kinetic inhibitor is proposed for pre-injection into marine sediments. This work shows that at a low pressure, a low-concentration inhibitor has an obvious inhibition effect on hydrate growth. However, at a high pressure, it is necessary to increase the concentration of inhibitor to produce an obvious inhibition effect.

Key words: Liquid CO₂, Hydrate formation, Sequestration, Kinetic, Water conversion

Nan Li, Jing-Yu Kan, Chang-Yu Sun, Guang-Jin Chen. Hydrate formation from liquid CO₂ in a glass beads bed[J]. 中国化学工程学报, 2022, 43(3): 185-191.

Nan Li, Jing-Yu Kan, Chang-Yu Sun, Guang-Jin Chen. Hydrate formation from liquid CO₂ in a glass beads bed[J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 185-191.

参考文献

[1] K.Z. House, D.P. Schrag, C.F. Harvey, K.S. Lackner, Permanent carbon dioxide storage in deep-sea sediments, PNAS 103 (33) (2006) 12291-12295
[2] S.M. Benson, D.R. Cole, CO₂ sequestration in deep sedimentary formations, Elements 4 (5) (2008) 325-331
[3] N. Goel, In situ methane hydrate dissociation with carbon dioxide sequestration:current knowledge and issues, J. Petroleum Sci. Eng. 51 (3-4) (2006) 169-184
[4] L.T. Chen, C.Y. Sun, G.J. Chen, Y.Q. Nie, Z.S. Sun, Y.T. Liu, Measurements of hydrate equilibrium conditions for CH₄, CO₂, and CH₄ + C₂H₆ + C₃H₈ in various systems by step-heating method, Chin. J. Chem. Eng. 17 (4) (2009) 635-641
[5] C.G. Xu, X.S. Li, K.F. Yan, X.K. Ruan, Z.Y. Chen, Z.M. Xia, Research progress in hydrate-based technologies and processes in China:a review, Chin. J. Chem. Eng. 27 (9) (2019) 1998-2013
[6] S.P. Kang, J.W. Lee, Kinetic behaviors of CO₂ hydrates in porous media and effect of kinetic promoter on the formation kinetics, Chem. Eng. Sci. 65 (5) (2010) 1840-1845
[7] M.J. Yang, Y.C. Song, W.G. Liu, J.F. Zhao, X.K. Ruan, L.L. Jiang, Q.P. Li, Effects of additive mixtures (THF/SDS) on carbon dioxide hydrate formation and dissociation in porous media, Chem. Eng. Sci. 90 (2013) 69-76
[8] S.H.B. Yang, P. Babu, S.F.S. Chua, P. Linga, Carbon dioxide hydrate kinetics in porous media with and without salts, Appl. Energy 162 (2016) 1131-1140
[9] C. Dicharry, C. Duchateau, H. Asbaï, D. Broseta, J.P. Torré, Carbon dioxide gas hydrate crystallization in porous silica gel particles partially saturated with a surfactant solution, Chem. Eng. Sci. 98 (2013) 88-97
[10] P. Mekala, M. Busch, D. Mech, R.S. Patel, J.S. Sangwai, Effect of silica sand size on the formation kinetics of CO₂ hydrate in porous media in the presence of pure water and seawater relevant for CO₂ sequestration, J. Petroleum Sci. Eng. 122 (2014) 1-9
[11] G. Bhattacharjee, A. Kumar, T. Sakpal, R. Kumar, Carbon dioxide sequestration:influence of porous media on hydrate formation kinetics, ACS Sustainable Chem. Eng. 3 (6) (2015) 1205-1214
[12] T. Takahashi, T. Sato, M. Inui, S. Hirabayashi, P.E. Brumby, Modeling of CO₂-hydrate formation at the gas-water interface in sand sediment, Chem. Eng. Technol. 35 (10) (2012) 1751-1758
[13] T. Yu, T. Sato, T. Nakashima, M. Inui, H. Oyama, An integrated model for CO₂ hydrate formation in sand sediments for sub-seabed CO₂ storage, Int. J. Greenh. Gas Control 52 (2016) 250-269
[14] M.J. Yang, Y.C. Song, X.K. Ruan, Y. Liu, J.F. Zhao, Q.P. Li, Characteristics of CO₂ hydrate formation and dissociation in glass beads and silica gel, Energies 5 (4)(2012) 925-937
[15] M.J. Yang, Y.C. Song, L.L. Jiang, N.J. Zhu, Y. Liu, Y.C. Zhao, B.L. Dou, Q.P. Li, CO₂ hydrate formation and dissociation in cooled porous media:a potential technology for CO₂ capture and storage, Environ. Sci. Technol. 47 (17) (2013) 9739-9746
[16] M.J. Yang, Y.C. Song, L.L. Jiang, Y. Liu, Y.H. Li, CO₂ hydrate formation characteristics in a water/brine-saturated silica gel, Ind. Eng. Chem. Res. 53 (26) (2014) 10753-10761
[17] D. Sun, P. Englezos, CO₂ storage capacity in laboratory simulated depleted hydrocarbon reservoirs-Impact of salinity and additives, J. Nat. Gas Sci. Eng. 35 (2016) 1416-1425
[18] X.Y. Zang, L.H. Wan, D.Q. Liang, Investigation of the hydrate formation process in fine sediments by a binary CO₂/N₂ gas mixture, Chin. J. Chem. Eng. 27 (9) (2019) 2157-2163
[19] R. Shukla, P. Ranjith, A. Haque, X. Choi, A review of studies on CO₂ sequestration and caprock integrity, Fuel 89 (10) (2010) 2651-2664
[20] Y. Abe, Y. Takagi, A. Kaneko, K. Yamane, Hydrodynamics of liquid CO₂ with hydrate formation in packed bed, Int. J. Heat Mass Transf. 65 (2013) 95-101
[21] N.S. Molokitina, A.N. Nesterov, L.S. Podenko, A.M. Reshetnikov, Carbon dioxide hydrate formation with SDS:further insights into mechanism of gas hydrate growth in the presence of surfactant, Fuel 235 (2019) 1400-1411
[22] L.T. Chen, C.Y. Sun, G.J. Chen, J.Y. Zuo, H.J. Ng, Assessment of hydrate kinetic inhibitors with visual observations, Fluid Phase Equilibria 298 (1) (2010) 143-149
[23] M.T.J. Barwood, P.J. Metaxas, V.W.S. Lim, M.L. Johns, Z.M. Aman, E.F. May, High-resolution performance tests of nucleation and growth suppression by two kinetic hydrate inhibitors, Chem. Eng. Sci. 244 (2021) 116776
[24] K.E. Starling, M.S. Han, Thermo data refined for LPG-14. mixtures, Hydrocarb. Process. 51(5) (1972):129-132
[25] Z.H. Duan, N. Møller, J.H. Weare, An equation of state for the CH₄-CO₂-H₂O system:I. Pure systems from 0 to 1000℃ and 0 to 8000 bar, Geochimica Cosmochimica Acta 56 (7) (1992) 2605-2617
[26] Q. Yuan, C.Y. Sun, X. Yang, P.C. Ma, Z.W. Ma, Q.P. Li, G.J. Chen, Gas production from methane-hydrate-bearing sands by ethylene glycol injection using a three-dimensional reactor, Energy Fuels 25 (7) (2011) 3108-3115
[27] D. Sloan, C.A. Koh, Clathrate Hydrates of Natural Gases-Third Edition, CRC Press, 2007
[28] G.J. Chen, T.M. Guo, A new approach to gas hydrate modelling, Chem. Eng. J. 71 (2) (1998) 145-151
[29] L.T. Chen, N. Li, C.Y. Sun, G.J. Chen, C.A. Koh, B.J. Sun, Hydrate formation in sediments from free gas using a one-dimensional visual simulator, Fuel 197 (2017) 298-309
[30] S.L. Li, C.Y. Sun, B. Liu, X.J. Feng, F.G. Li, L.T. Chen, G.J. Chen, Initial thickness measurements and insights into crystal growth of methane hydrate film, AIChE J. 59 (6) (2013) 2145-2154
[31] S. Oya, M. Aifaa, R. Ohmura, Formation, growth and sintering of CO₂ hydrate crystals in liquid water with continuous CO₂ supply:implication for subsurface CO₂ sequestration, Int. J. Greenh. Gas Control 63 (2017) 386-391

Hydrate formation from liquid CO₂ in a glass beads bed

Hydrate formation from liquid CO₂ in a glass beads bed

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