3D multiphase flow simulation of Marangoni convection on reactive absorption of CO2 by monoethanolamine in microchannel

doi:10.1016/j.cjche.2021.02.014

中国化学工程学报 ›› 2022, Vol. 43 ›› Issue (3): 370-377.DOI: 10.1016/j.cjche.2021.02.014

3D multiphase flow simulation of Marangoni convection on reactive absorption of CO₂ by monoethanolamine in microchannel

Shuai Chen, Jiahong Lan, Yu Zhang, Jia Guo, Zhikai Cao, Yong Sha

Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

收稿日期:2020-12-24 修回日期:2021-02-24 出版日期:2022-03-28 发布日期:2022-04-28
通讯作者: Yong Sha,E-mail:ysha@xmu.edu.cn
基金资助:
The authors acknowledge financial support provided by National Natural Science Foundation of China (21978243).

3D multiphase flow simulation of Marangoni convection on reactive absorption of CO₂ by monoethanolamine in microchannel

Shuai Chen, Jiahong Lan, Yu Zhang, Jia Guo, Zhikai Cao, Yong Sha

Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Received:2020-12-24 Revised:2021-02-24 Online:2022-03-28 Published:2022-04-28
Contact: Yong Sha,E-mail:ysha@xmu.edu.cn
Supported by:
The authors acknowledge financial support provided by National Natural Science Foundation of China (21978243).

摘要/Abstract

摘要： A multiphase flow 3D numerical simulation method employing the coupled volume of fluid (VOF) and level set model is established to study the reactive absorption of CO₂ by the monoethanolamine (MEA) aqueous solution in a falling film microchannel. Based on the flow-reaction-mass transfer model of the MEA-CO₂ system in the falling film microchannel, the enhancement effect of the Marangoni convection in this reactive absorption process is analyzed. The enhancement factor of the Marangoni convection obtained in this work is in good agreement with experimental results in the literature. With consideration of the absorption ratio as well as the enhancement effect of the Marangoni convection, the influence of different MEA concentrations on absorption of CO₂ is investigated. Furthermore, the appropriate MEA concentration for absorption enhanced by the Marangoni convection is acquired.

关键词: Numerical simulation, Microchannel, Falling film, Marangoni convection, MEA-CO₂

Abstract: A multiphase flow 3D numerical simulation method employing the coupled volume of fluid (VOF) and level set model is established to study the reactive absorption of CO₂ by the monoethanolamine (MEA) aqueous solution in a falling film microchannel. Based on the flow-reaction-mass transfer model of the MEA-CO₂ system in the falling film microchannel, the enhancement effect of the Marangoni convection in this reactive absorption process is analyzed. The enhancement factor of the Marangoni convection obtained in this work is in good agreement with experimental results in the literature. With consideration of the absorption ratio as well as the enhancement effect of the Marangoni convection, the influence of different MEA concentrations on absorption of CO₂ is investigated. Furthermore, the appropriate MEA concentration for absorption enhanced by the Marangoni convection is acquired.

Key words: Numerical simulation, Microchannel, Falling film, Marangoni convection, MEA-CO₂

Shuai Chen, Jiahong Lan, Yu Zhang, Jia Guo, Zhikai Cao, Yong Sha. 3D multiphase flow simulation of Marangoni convection on reactive absorption of CO₂ by monoethanolamine in microchannel[J]. 中国化学工程学报, 2022, 43(3): 370-377.

参考文献

[1] K. Li, W. Leigh, P. Feron, H. Yu, M. Tade, Systematic study of aqueous monoethanolamine (MEA)-based CO₂ capture process:Techno-economic assessment of the MEA process and its improvements, Appl. Energy 165 (2016) 648-659
[2] Z. Huang, Z. Deng, J. Ma, Y. Qin, Y. Zhang, Y. Luo, Z. Wu, Comparison of mass transfer coefficients and desorption rates of CO₂ absorption into aqueous MEA + ionic liquids solution, Chem. Eng. Res. Des. 117 (2017) 66-72
[3] T. Wang, W. Yu, M. Fang, H. He, Q. Xiang, Q. Ma, M. Xia, Z. Luo, K. Cen, Wetted-wall column study on CO₂ absorption kinetics enhancement by additive of nanoparticles, Greenhouse Gas. Sci. Technol. 5 (5) (2015) 682-694
[4] C. Madeddu, M. Errico, R. Baratti, Rigorous modeling of a CO₂-MEA stripping system, Chem. Eng. Trans. 57 (2017) 451-456
[5] H. Gao, B. Xu, L. Han, X. Luo, Z. Liang, Mass transfer performance and correlations for CO₂ absorption into aqueous blended of DEEA/MEA in a random packed column, AIChE J. 63 (7) (2017) 3048-3057
[6] F.I. Talens-Alesson, The modelling of falling film chemical reactors, Chem. Eng. Sci. 54 (12) (1999) 1871-1881
[7] B. Dabir, M.R. Riazi, H.R. Davoudirad, Modelling of falling film reactors, Chem. Eng. Sci. 51 (11) (1996) 2553-2558
[8] D. Lokhat, A.K. Domah, K. Padayachee, A. Baboolal, D. Ramjugernath, Gas-liquid mass transfer in a falling film microreactor:Effect of reactor orientation on liquid-side mass transfer coefficient, Chem. Eng. Sci. 155 (2016) 38-44
[9] J. Zhang, K. Wang, A.R. Teixeira, K.F. Jensen, G. Luo, Design and scaling up of microchemical systems:A review, Annu. Rev. Chem. Biomol. Eng. 8 (2017) 285-305
[10] M. Zanfir, A. Gavriilidis, C. Wille, V. Hessel, Carbon dioxide absorption in a falling film microstructured reactor:Experiments and modeling, Ind. Eng. Chem. Res. 44 (6) (2005) 1742-1751
[11] N. Goel, D.Y. Goswami, Experimental verification of a new heat and mass transfer enhancement concept in a microchannel falling film absorber, J. Heat Transfer129 (2) (2007) 154-161
[12] N. Akkarawatkhoosith, A. Kaewchada, A. Jaree, High-throughput CO₂ capture for biogas purification using monoethanolamine in a microtube contactor, J. Taiwan Inst. Chem. Eng. 98 (2019) 113-123
[13] P. Sobieszuk, R. Pohorecki, P. Cygański, M. Kraut, F. Olschewski, Marangoni effect in a falling film microreactor, Chem. Eng. J. 164 (1) (2010) 10-15
[14] K. Warmuziński, J. Buzek, J. Podkański, Marangoni instability during absorption accompanied by chemical reaction, Chem. Eng. J. Biochem. Eng. J. 58 (2) (1995) 151-160
[15] J. Buzek, J. Podkański, K. Warmuziński, The enhancement of the rate of absorption of CO₂ in amine solutions due to the Marangoni effect, Energy Convers. Manag. 38 (Suppl. 1) (1997) S69-S74
[16] B.R. Fu, M.S. Tsou, C. Pan, Flow-pattern-based correlations for pressure drop during flow boiling of ethanol-water mixtures in a microchannel, Int. J. Heat Mass Transfer 61 (1) (2013) 332-339
[17] Z. Pan, F. Wang, H. Wang, Instability of Marangoni toroidal convection in a microchannel and its relevance with the flowing direction, Microfluid. Nanofluid. 11 (3) (2011) 327-338
[18] H. Kikura, M. Motosuke, S. Wada, Flow visualization using UVP, J. Vis. Soc. Japan 142 (2016) 6-6
[19] K.F. Lam, E. Sorensen, A. Gavriilidis, Review on gas-liquid separations in microchannel devices, Chem. Eng. Res. Des. 91 (10) (2013) 1941-1953
[20] Y. Imai, T. Yamamoto, A. Sekimoto, Y. Okano, R. Sato, Y. Shigeta, Numerical investigation of the nano-scale solutal Marangoni convections, J. Taiwan Inst. Chem. Eng. 98 (2019) 20-26
[21] K. Sun, P. Zhang, Z. Che, T. Wang, Marangoni-flow-induced partial coalescence of a droplet on a liquid/air interface, Phys. Rev. Fluids 3 (2) (2018) 023602
[22] Y. Zhong, Y. Zhuo, Z. Wang, Y. Sha, Marangoni convection induced by simultaneous mass and heat transfer during evaporation of n-heptane/ether binary liquid mixture, Int. J. Heat Mass Transfer 108 (2017) 812-821
[23] C.W. Hirt, B.D. Nichols, Volume of fluid (VOF) method for the dynamics of free boundaries, J. Comput. Phys. 39 (1) (1981) 201-225
[24] S. Osher, J.A. Sethian, Fronts propagating with curvature-dependent speed:Algorithms based on Hamilton-Jacobi formulations, J. Comput. Phys. 79 (1) (1988) 12-49
[25] D. L. Youngs, Time-dependent multi-material flow with large fluid distortion, Academic Press, New York, 1982
[26] Chakraborty, G. Biswas, P.S. Ghoshdastidar, A coupled level-set and volume-of-fluid method for the buoyant rise of gas bubbles in liquids, Int. J. Heat Mass Transfer 58 (1-2) (2013) 240-259
[27] J.U. Brackbill, D.B. Kothe, C. Zemach, A continuum method for modeling surface tension, J. Comput. Phys. 100 (2) (1992) 335-354
[28] E. Sada, H. Kumazawa, M.A. Butt, Gas absorption with complex chemical reaction:Approximate analytical solutions, Can. J. Chem. Eng. 55 (5) (1977) 623-625
[29] S. Freguia, G.T. Rochelle, Modeling of CO₂ capture by aqueous monoethanolamine, AIChE J. 49 (7) (2003) 1676-1686
[30] S. Freguia, Modeling of CO₂ removal from flue gases with monoethanolamine, M.S. Thesis, Univ of Texas at Austin, America, 2002.
[31] A.A. Shapiro, E.H. Stenby, Thermodynamics of the multicomponent vapor-liquid equilibrium under capillary pressure difference, Fluid Phase Equilib. 178 (1-2) (2001) 17-32
[32] D. Fu, Y.F. Xu, L.F. Wang, L.H. Chen, Experiments and model for the surface tension of carbonated monoethanolamine aqueous solutions, Sci. China Chem. 55 (7) (2012) 1467-1473
[33] J.I. Lee, F.D. Otto, A.E. Mather, Equilibrium between carbon dioxide and aqueous monoethanolamine solutions, J. Appl. Chem. Biotechnol. 26 (10) (1976) 541-549
[34] L.F. Chiu, M.H. Li, Heat capacity of alkanolamine aqueous solutions, J. Chem. Eng. Data 44 (6) (1999) 1396-1401
[35] J.B. Haelssig, A.Y. Tremblay, J. Thibault, S.G. Etemad, Direct numerical simulation of interphase heat and mass transfer in multicomponent vapour-liquid flows, Int. J. Heat Mass Transfer 53 (19-20) (2010) 3947-3960
[36] S.D. Kenarsari, D. Yang, G. Jiang, S. Zhang, J. Wang, A.G. Russell, Q. Wei, M. Fan, Review of recent advances in carbon dioxide separation and capture, RSC Adv. 3 (45) (2013) 22739-22773
[37] F.H. Al-Masabi, M. Castier, Simulation of carbon dioxide recovery from flue gases in aqueous 2-amino-2-methyl-1-propanol solutions, Int. J. Greenhouse Gas Control. 5 (6) (2011) 1478-1488

3D multiphase flow simulation of Marangoni convection on reactive absorption of CO₂ by monoethanolamine in microchannel

3D multiphase flow simulation of Marangoni convection on reactive absorption of CO₂ by monoethanolamine in microchannel

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Jiahao Xing, Huaizhi Han, Ruitian Yu, Wen Luo. Numerical simulation of flow and heat transfer of n-decane in sub-millimeter spiral tube at supercritical pressure[J]. 中国化学工程学报, 2023, 60(8): 173-185.
[2]	Jian Han, Xinhua Liu, Shanwei Hu, Nan Zhang, Jingjing Wang, Bin Liang. Optimization of decoupling combustion characteristics of coal briquettes and biomass pellets in household stoves[J]. 中国化学工程学报, 2023, 59(7): 182-192.
[3]	Shengfeng Luo, Song Zhang, Yiping Zeng, Hui Zhang, Lili Zheng, Zhaopeng Xu. Study on oxygen transport and titanium oxidation in coating cracks under parallel gas flow based on LBM modelling[J]. 中国化学工程学报, 2023, 56(4): 15-24.
[4]	Jikai Dong, Bing Wang, Xinjie Wang, Chenxi Cao, Shikuan Chen, Wenli Du. Optimization of sensor deployment sequences for hazardous gas leakage monitoring and source term estimation[J]. 中国化学工程学报, 2023, 56(4): 169-179.
[5]	Shuangfei Zhao, Yingying Nie, Wenyan Zhang, Runze Hu, Lianzhu Sheng, Wei He, Ning Zhu, Yuguang Li, Dong Ji, Kai Guo. Microfluidic field strategy for enhancement and scale up of liquid–liquid homogeneous chemical processes by optimization of 3D spiral baffle structure[J]. 中国化学工程学报, 2023, 56(4): 255-265.
[6]	Ming Chen, Huiyan Jiao, Jun Li, Zhibin Wang, Feng He, Yang Jin. Liquid–liquid two-phase flow in a wire-embedded concentric microchannel: Flow pattern and mass transfer performance[J]. 中国化学工程学报, 2023, 56(4): 281-289.
[7]	Qi Han, Xin-Yuan Zhang, Hai-Bo Wu, Xian-Tai Zhou, Hong-Bing Ji. Different efficiency toward the biomimetic aerobic oxidation of benzyl alcohol in microchannel and bubble column reactors: Hydrodynamic characteristics and gas–liquid mass transfer[J]. 中国化学工程学报, 2023, 55(3): 84-92.
[8]	Chunxin Fan, Zini Guo, Jianhong Luo. Study on an improved rotating microchannel separator in the intensification for demulsification and separation process[J]. 中国化学工程学报, 2023, 55(3): 181-191.
[9]	Qinyan Wang, Yang Jin, Jun Li, Yongbo Zhou, Ming Chen. Study on liquid–liquid two-phase mass transfer characteristics in the microchannel with deformed insert[J]. 中国化学工程学报, 2023, 54(2): 114-126.
[10]	Xibao Zhang, Zhenghong Luo. Bubble size modeling approach for the simulation of bubble columns[J]. 中国化学工程学报, 2023, 53(1): 194-200.
[11]	Yongbo Zhou, Yang Jin, Jun Li, Qinyan Wang, Ming Chen. Numerical study on the hydrodynamics behavior of a central insert microchannel[J]. 中国化学工程学报, 2023, 53(1): 361-373.
[12]	Pan Zhang, Guanghui Chen, Weiwen Wang, Guodong Zhang, Huaming Wang. Analysis of the nutation and precession of the vortex core and the influence of operating parameters in a cyclone separator[J]. 中国化学工程学报, 2022, 46(6): 1-10.
[13]	Ye Zhang, Yong Gao, Peng Wang, Duo Na, Zhenming Yang, Jinsong Zhang. Solvent extraction with a three-dimensional reticulated hollow-strut SiC foam microchannel reactor[J]. 中国化学工程学报, 2022, 46(6): 53-62.
[14]	Yaran Yin, Xianming Zhang, Chunying Zhu, Taotao Fu, Youguang Ma. Formation characteristics of Taylor bubbles in a T-junction microchannel with chemical absorption[J]. 中国化学工程学报, 2022, 46(6): 214-222.
[15]	Zhen Chen, Chunying Zhu, Taotao Fu, Xiqun Gao, Youguang Ma. Formation dynamics and size prediction of bubbles for slurry system in T-shape microchannel[J]. 中国化学工程学报, 2022, 45(5): 153-161.