Metal-organic framework-derived Co-C catalyst for the selective hydrogenation of cinnamaldehyde to cinnamic alcohol

doi:10.1016/j.cjche.2023.04.013

中国化学工程学报 ›› 2023, Vol. 62 ›› Issue (10): 46-56.DOI: 10.1016/j.cjche.2023.04.013

• Full Length Article • 上一篇下一篇

Metal-organic framework-derived Co-C catalyst for the selective hydrogenation of cinnamaldehyde to cinnamic alcohol

Fuping Tian¹, Xinchi Zhang¹, Yingying Sheng¹, Xiao Chen², Xiang Wang², Changhai Liang²

1. State Key Laboratory of Fine Chemicals & Department of Chemistry, Dalian University of Technology, Dalian 116024, China;
2. School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

收稿日期:2022-12-28 修回日期:2023-04-12 出版日期:2023-10-28 发布日期:2023-12-23
通讯作者: Fuping Tian,E-mail:fptian@dlut.edu.cn
基金资助:
The authors are grateful for financial support from the National Natural Science Foundation of China (22272016).

Metal-organic framework-derived Co-C catalyst for the selective hydrogenation of cinnamaldehyde to cinnamic alcohol

Fuping Tian¹, Xinchi Zhang¹, Yingying Sheng¹, Xiao Chen², Xiang Wang², Changhai Liang²

1. State Key Laboratory of Fine Chemicals & Department of Chemistry, Dalian University of Technology, Dalian 116024, China;
2. School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Received:2022-12-28 Revised:2023-04-12 Online:2023-10-28 Published:2023-12-23
Contact: Fuping Tian,E-mail:fptian@dlut.edu.cn
Supported by:
The authors are grateful for financial support from the National Natural Science Foundation of China (22272016).

摘要/Abstract

摘要： The liquid phase selective hydrogenation of cinnamaldehyde has been investigated over the catalysts Co-C-T (T = 400–700 ℃), which were derived from the carbonization of the MOF precursor Co-BTC at different temperatures in inert atmosphere. Co-C-500 exhibited a higher conversion (85.3%) than those carbonized at other temperatures, with 51.5% selectivity to cinnamyl alcohol, under a mild condition (90 ℃, 4 h, 2 MPa H₂, solvent: 9 ml ethanol and 1 ml water). The high catalytic activity of Co-C-500 can be ascribed to the large specific surface area of the catalyst, the uniformly dispersed metallic cobalt nanoparticles, and the more defect sites on the carbon support. Moreover, Co-C-500 showed excellent reusability in 5 successive cycles, mainly related to the uniformly dispersed cobalt nanoparticles embedded in carbon support.

关键词: Catalyst, Hydrogenation, Selectivity, Cinnamaldehyde, Cinnamyl alcohol, Co-C

Abstract: The liquid phase selective hydrogenation of cinnamaldehyde has been investigated over the catalysts Co-C-T (T = 400–700 ℃), which were derived from the carbonization of the MOF precursor Co-BTC at different temperatures in inert atmosphere. Co-C-500 exhibited a higher conversion (85.3%) than those carbonized at other temperatures, with 51.5% selectivity to cinnamyl alcohol, under a mild condition (90 ℃, 4 h, 2 MPa H₂, solvent: 9 ml ethanol and 1 ml water). The high catalytic activity of Co-C-500 can be ascribed to the large specific surface area of the catalyst, the uniformly dispersed metallic cobalt nanoparticles, and the more defect sites on the carbon support. Moreover, Co-C-500 showed excellent reusability in 5 successive cycles, mainly related to the uniformly dispersed cobalt nanoparticles embedded in carbon support.

Key words: Catalyst, Hydrogenation, Selectivity, Cinnamaldehyde, Cinnamyl alcohol, Co-C

Fuping Tian, Xinchi Zhang, Yingying Sheng, Xiao Chen, Xiang Wang, Changhai Liang. Metal-organic framework-derived Co-C catalyst for the selective hydrogenation of cinnamaldehyde to cinnamic alcohol[J]. 中国化学工程学报, 2023, 62(10): 46-56.

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Metal-organic framework-derived Co-C catalyst for the selective hydrogenation of cinnamaldehyde to cinnamic alcohol

Metal-organic framework-derived Co-C catalyst for the selective hydrogenation of cinnamaldehyde to cinnamic alcohol

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