Chemical looping conversion of methane via Fe2O3-LaFeO3 calcined from LaFe-MOF precursor

doi:10.1016/j.cjche.2023.04.002

中国化学工程学报 ›› 2023, Vol. 62 ›› Issue (10): 225-237.DOI: 10.1016/j.cjche.2023.04.002

• Full Length Article • 上一篇下一篇

Chemical looping conversion of methane via Fe₂O₃-LaFeO₃ calcined from LaFe-MOF precursor

Jitong Deng¹, Yongjun Zhang^1,2, Xiaopeng Wang³, Wei Zhang¹, Hongjing Han¹, Haiying Wang¹, Huimin Yuan², Yanan Zhang¹, Yanguang Chen¹

1. College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2. PetroChina Daqing Petrochemical Research Center, Daqing 163714, China;
3. CNPC Safety and Environmental Technology Research Institute Co. LTD., Beijing 102206, China

收稿日期:2022-12-29 修回日期:2023-04-11 出版日期:2023-10-28 发布日期:2023-12-23
通讯作者: Hongjing Han,E-mail:hongjing_han@163.com;Yanguang Chen,E-mail:ygchen79310@126.com
基金资助:
This work was financially supported by the National Natural Science Foundation of China (21908021), the China Petroleum Science and Technology Innovation Fund project (2021DQ02-0701), the High-Level Talent Project of Heilongjiang Province of China (2020GSP17), the New Energy and New Direction Project of Northeast Petroleum University (XNYXLY202102), and the Guiding Innovation Fund of Northeast Petroleum University (2021YDL-03).

Chemical looping conversion of methane via Fe₂O₃-LaFeO₃ calcined from LaFe-MOF precursor

Jitong Deng¹, Yongjun Zhang^1,2, Xiaopeng Wang³, Wei Zhang¹, Hongjing Han¹, Haiying Wang¹, Huimin Yuan², Yanan Zhang¹, Yanguang Chen¹

1. College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2. PetroChina Daqing Petrochemical Research Center, Daqing 163714, China;
3. CNPC Safety and Environmental Technology Research Institute Co. LTD., Beijing 102206, China

Received:2022-12-29 Revised:2023-04-11 Online:2023-10-28 Published:2023-12-23
Contact: Hongjing Han,E-mail:hongjing_han@163.com;Yanguang Chen,E-mail:ygchen79310@126.com
Supported by:
This work was financially supported by the National Natural Science Foundation of China (21908021), the China Petroleum Science and Technology Innovation Fund project (2021DQ02-0701), the High-Level Talent Project of Heilongjiang Province of China (2020GSP17), the New Energy and New Direction Project of Northeast Petroleum University (XNYXLY202102), and the Guiding Innovation Fund of Northeast Petroleum University (2021YDL-03).

摘要/Abstract

摘要： The effective utilization of natural gas resources is a promising option for the implementation of the “dual carbon” strategy. However, the capture of carbon dioxide with relatively lower concentration after the combustion of natural gas is the crucial step. Fortunately, the lattice oxygen is used for chemical cycle conversion of methane to overcome the shortcomings mentioned above. A method was proposed to synthesize perovskite for methane cycle conversion using metal organic framework as a precursor. Morphology and pore structure of Fe₂O₃-LaFeO₃ composite oxides were regulated by precursor synthesis conditions and calcination process. Moreover, the chemical looping conversion performance of methane was evaluated. The results showed that the pure phase precursor of La[Fe(CN)₆]·5H₂O was synthesized with the specific surface area of 23.91 m²·g^-1 under the crystallization of 10 h and the pH value of 10.5. Fe₂O₃-LaFeO₃ was obtained by controlled calcination of La[Fe(CN)₆]·5H₂O and Fe₂O₃ with variable mass ratio. The selectivity of CO₂ can reach more than 99% under the optimal parameters of methane chemical looping conversion: m(Fe₂O₃):m(LaFeO₃) = 2:1, the reaction temperature is 900 ℃, the lattice oxygen conversion is less than 40%. Fe₂O₃-LaFeO₃ still has good phase and structure stability after five redox reaction and regeneration cycles.

关键词: Composite, Chemical looping conversion, Carbon dioxide, Metal organic frameworks, Lattice oxygen, Methane

Abstract: The effective utilization of natural gas resources is a promising option for the implementation of the “dual carbon” strategy. However, the capture of carbon dioxide with relatively lower concentration after the combustion of natural gas is the crucial step. Fortunately, the lattice oxygen is used for chemical cycle conversion of methane to overcome the shortcomings mentioned above. A method was proposed to synthesize perovskite for methane cycle conversion using metal organic framework as a precursor. Morphology and pore structure of Fe₂O₃-LaFeO₃ composite oxides were regulated by precursor synthesis conditions and calcination process. Moreover, the chemical looping conversion performance of methane was evaluated. The results showed that the pure phase precursor of La[Fe(CN)₆]·5H₂O was synthesized with the specific surface area of 23.91 m²·g^-1 under the crystallization of 10 h and the pH value of 10.5. Fe₂O₃-LaFeO₃ was obtained by controlled calcination of La[Fe(CN)₆]·5H₂O and Fe₂O₃ with variable mass ratio. The selectivity of CO₂ can reach more than 99% under the optimal parameters of methane chemical looping conversion: m(Fe₂O₃):m(LaFeO₃) = 2:1, the reaction temperature is 900 ℃, the lattice oxygen conversion is less than 40%. Fe₂O₃-LaFeO₃ still has good phase and structure stability after five redox reaction and regeneration cycles.

Key words: Composite, Chemical looping conversion, Carbon dioxide, Metal organic frameworks, Lattice oxygen, Methane

Jitong Deng, Yongjun Zhang, Xiaopeng Wang, Wei Zhang, Hongjing Han, Haiying Wang, Huimin Yuan, Yanan Zhang, Yanguang Chen. Chemical looping conversion of methane via Fe₂O₃-LaFeO₃ calcined from LaFe-MOF precursor[J]. 中国化学工程学报, 2023, 62(10): 225-237.

参考文献

[1] J.D. Figueroa, T. Fout, S. Plasynski, H. McIlvried, Advances in CO₂ capture technology-The U.S. Department of energy's carbon sequestration program, Int. J. Greenh. Gas Control. 2 (1) (2008) 9-20.
[2] Z. Wang, D. Luo, L. Liu, Natural gas utilization in China: Development trends and prospects, Energy Rep 4 (2018) 351-356.
[3] W.W. Tso, C.D. Demirhan, C.A. Floudas, C.A. Floudas, E.N. Pistikopoulos, Multi-scale energy systems engineering for optimal natural gas utilization, Catal. Today. 356 (2020) 18-26.
[4] X.Y. Lin, J.Y. Li, M.Y. Qi, Z.R. Tang, Y.J. Xu, Methane conversion over artificial photocatalysts, Catal. Commun. 159 (2021) 106346.
[5] C. Bessou, F. Ferchaud, B. Gabrielle, B. Mary, Biofuels, greenhouse gases and climate change. A review, Agron Sustain Dev 31 (2011) 1-79.
[6] P. Cho, T. Mattisson, A. Lyngfelt, Defluidization conditions for a fluidized bed of iron oxide-, nickel oxide-, and manganese oxide-containing oxygen carriers for chemical looping combustion, Ind. Eng. Chem. Res. 45 (2006) 968-977.
[7] D. Wawrzyńczak, M. Panowski, I. Majchrzak-Kucębaet, Possibilities of CO₂ purification coming from oxy-combustion for enhanced oil recovery and storage purposes by adsorption method on activated carbon, Energy 180 (2019) 787-796.
[8] F. He, H. Li, Z. Zhao, Advancements in Development of Chemical-Looping Combustion: A Review, Int J Chem Eng 2009 (2009) 1-16.
[9] C.W. Ong, C.L. Chen, Intensification, optimization and economic evaluations of the CO₂-capturing oxy-combustion CO₂ power system integrated with the utilization of liquefied natural gas cold energy, Energy 234 (2021) 121255.
[10] X. Zhu, Q. Imtiaz, F. Donat, C.R. Müller, F.X. Li. Chemical looping beyond combustion–a perspective. Energy Environ. Sci.13 (2020) 772-804.
[11] H.J. Richter, K.F. Knoche, Reversibility of combustion processes, ACS Symp. Ser. 235 (1983) 71-86.
[12] M. Ishida, D. Zheng, T. Akehata, Evaluation of a chemical-looping-combustion power-generation system by graphic exergy analysis, Energy 12 (2) (1987) 147-157.
[13] X. Zhu, Y.P. Du, H. Wang, Y.G. Wei, K.Z. Li, L.Y.Sun, Chemical interaction of Ce-Fe mixed oxides for methane selective oxidation, J. Rare Earths 32 (9) (2014) 824–830.
[14] D. Tian, K.Z. Li, Y.G. Wei, X. Zhu, C.H. Zeng, X.M. Cheng, Y.E. Zheng, H. Wang, DFT insights into oxygen vacancy formation and CH₄ activation over CeO₂ surfaces modified by transition metals (Fe, Co and Ni), Phys. Chem. Chem. Phys. 20 (17) (2018) 11912–11929.
[15] Y.P Du, X. Zhu, H. Wang, Y.G. Wei, K.Z. Li. Selective oxidation of methane to syngas using Pr_0.7Zr_0.3O₂–Δ: Stability of oxygen carrier. T NONFERR METAL SOC. 25(4) (2015) 1248-1253.
[16] Byeong, S. Kwak, Reduction and oxidation performance evaluation of Manganese-based iron, cobalt, nickel, and copper bimetallic oxide oxygen carriers for chemical-looping combustion, Appl. Therm. Eng. 128 (2018) 1273–1281.[LinkOut].
[17] M. Mohammedramadan, Tijani, Determination of redox pathways of supported bimetallic oxygen carriers in a methane fuelled chemical looping combustion system, Fuel 233 (2018) 133–145.
[18] T. Mattisson, M. Johansson, A.Lyngfelt, Multicycle reduction and oxidation of different types of iron oxide ParticlesApplication to chemical-looping combustion, Energy Fuels 18 (3) (2004) 628–637.
[19] E.R. Monazam, R.W. Breault, R.Siriwardane, Kinetics of magnetite (Fe₃O₄) oxidation to hematite (Fe₂O₃) in air for chemical looping combustion, Ind. Eng. Chem. Res. 53 (34) (2014) 13320–13328.
[20] E. Monazam, R. Breault, R. Siriwardane, G. Richards, S. Carpenter, Kinetics of the reduction of hematite (Fe₂O₃) by methane (CH₄) during chemical looping combustion: a global mechanism, Chem. Eng. J. 232 (2013) 478–487.
[21] Tobias, Mattisson, The use of iron oxide as an oxygen carrier in chemical-looping combustion of methane with inherent separation of CO₂, Fuel 80 (13) (2001) 1953–1962.
[22] S. Nasr, K.P. Plucknett, Kinetics of iron ore reduction by methane for chemical looping combustion, Energy Fuels 28 (2) (2014) 1387–1395.
[23] Z.P. Chen, S. Wang, W.G. Liu, X.H. Gao, D.N. Gao, M.Z. Wang, S.D. Wang, Morphology-dependent performance of CO₃O₄ via facile and controllable synthesis for methane combustion, Appl. Catal. A-Gen. 525 (2016) 94-102.
[24] J.M. Gu, S.H. Li, E.B. Wang, Q.Y. Li, G.Y. Sun, R. Xu, H. Zhang, Single-crystalline α-Fe₂O₃ with hierarchical structures: Controllable synthesis, formation mechanism and photocatalytic properties, J. Solid. State. Chem. 182 (2009) 1265-1272.
[25] B.T. Hang, T.T. Anh, Controlled synthesis of various Fe₂O₃ morphologies as energy storage materials, Sci. Rep. 11 (1) (2021) 5185.
[26] B.M. Corbella, L. de Diego, F. García Labiano, J. Adánez, J.M. Palacios, Characterization and performance in a multicycle test in a fixed-bed reactor of silica-supported copper oxide as oxygen carrier for chemical-looping combustion of methane, Energy Fuels 20 (1) (2006) 148–154.
[27] L. Nalbandian, A. Eudou, V. Zaspalis, La_1-xSr_xM_yFe_1-yO₃-δ perovskites as oxygen-carrier materials for chemical-looping reforming, Int. J. Hydrogen. Energ. 36 (11) (2011) 6657-6670.
[28] F. He, J. Chen, S. Liu, Z. Huang, G.Q. Wei, G.X. Wang, Y. Cao, K. Zhao, La_1-xSr_xFeO₃ perovskite-type oxides for chemical-looping steam methane reforming: Identification of the surface elements and redox cyclic performance, Int. J. Hydrogen. Energ. 44 (21, 23) (2019) 10265-10276.
[29] N.L. Galinsky, H. Yan, A. Shafiefarhood, F.X. Li, Iron oxide with facilitated O₂– transport for facile fuel oxidation and CO₂ capture in a chemical looping scheme, ACS. Sustain. Chem. Eng. 1 (3) (2013) 364-373.
[30] A. Shafiefarhood, N. Galinsky, A.P.Y. Huang, Y.G. Chen, A. Li, Fe₂O₃@La_xSr_1-xFeO₃ Core–Shell Redox Catalyst for Methane Partial Oxidation, ChemCatChem 6 (2014) 790-799.
[31] V.V. Kharton, M.V. Patrakeev, J.C. Waerenborgh, V.A. Sobyanin, S.A. Veniaminov, A.A. Yaremchenko, P. Gaczyński, V.D. Belyaev, G.L. Semin, J.R. Frade, Methane oxidation over perovskite-related ferrites: effects of oxygen nonstoichiometry, Solid. State. Sci. 7 (11) (2005) 1344-1352.
[32] H.Z. Wang, W.C. Xu, S. Richins, K. Liaw, L. Yan, M. Zhou, H.M. Luo, Polymer-assisted approach to LaCo_1-xNi_xO₃ network nanostructures as bifunctional oxygen electrocatalysts, Electrochim. Acta. 296 (2019) 954-953.
[33] C. Jin, X.C. Cao, F.L. Lu, Z.R. Yang, R.Z. Yang, Electrochemical study of Ba_0.5Sr_0.5Co_0.8Fe_0.2O₃ perovskite as bifunctional catalyst in alkaline media, Int. J. Hydrogen. Energ. 38 (25) (2013) 10389-10393.
[34] K.Y. Zhu, H.Y. Liu, X.N. Li, Q.M. Li, J.H. Wang, X.F. Zhu, W.S. Yang, Oxygen evolution reaction over Fe site of BaZr_xFe_1-xO₃-σ perovskite oxides, Electrochim. Acta. 241 (2017) 433-439.
[35] Y.J. Sim, I.C. Yang, D. Kwon, J.M. Ha, J.C. Jung, Preparation of LaAlO₃ perovskite catalysts by simple solid-state method for oxidative coupling of methane, Catal. Today. 352 (2020) 134-139.
[36] H.Y. Wang, H.J. Han, Y.N. Zhang, J.X. Li, Y.G. Chen, H. Song, E.H. Sun, H.Z. Zhao, M. Zhang, D.D. Yuan, Influence of calcination temperature for LaTi_0.2Fe_0.8O₃ on catalytic pyrolysis of bagasse lignin, J. Rare. Earth. 8 (37) (2019) 837-844.
[37] D. Sánchez-Rodríguez, H. Wada, S. Yamaguchi, J. Farjas, H. Yahiro, Self-propagating high-temperature synthesis of LaMO₃ perovskite-type oxide using heteronuclearcyano metal complex precursors, J. Alloys Compd. 649 (2015) 1291-1299.
[38] M. Yamada, S.Y. Yonekura, Nanometric metal-organic framework of Ln[Fe(CN)6]: morphological analysis and thermal conversion dynamics by direct TEM observation, J. Phys. Chem. C. 113 (52) (2009) 21531-21537.
[39] S. Farhadi, F. Siadatnasab, Perovskite-type LaFeO₃ nanoparticles prepared by thermal decomposition of the La[Fe(CN)6]·5H₂O complex: A new reusable catalyst for rapid and efficient reduction of aromatic nitro compounds to arylamines with propan-2-ol under microwave irradiation, J. Mol. Catal. A-Chem. 339 (1–2) (2011) 108-116.
[40] S. Yamaguchi, H. Wada, D. SÁNCHEZ-RODRÍGUEZ, J. FARJAS, H. YAHIRO, Synthesis of perovskite-type oxide, LaFeO₃, from coordination polymer precursor, La[Fe(CN)6]·5H₂O, JCSJ 124 (12) (2016) 3284-3289.
[41] H.T. Huang, W.L. Zhang, X.D. Zhang, X. Guo, NO₂ sensing properties of SmFeO₃ porous hollow microspheres, Sens. Actuators. B-Chem. 265 (2018) 443-451.
[42] X.D. Zhang, W.L. Zhang, Z.X. Cai, Y.K. Li, Y. Yusuke, G. Xin, MOF-Derived LaFeO₃ Porous Hollow Micro-Spindles for NO₂ Sensing, Ceram. Int. 45 (2019) 5240-5248.
[43] S.G. Duyker, G.J. Halder, P.D. Southon, D.J. Price, A.J. Edwards, V.K. Peterson, C.J. Kepert, Topotactic structural conversion and hydration-dependent thermal expansion in robust LnMIII(CN)6·nH₂O and flexible ALnFeII(CN)6·nH₂O frameworks (A = Li, Na, K; Ln = La-Lu, Y; M = Co, Fe; 0 ≤ n ≤ 5), Chem. Sci. 9 (5) (2014) 3409-3417.
[44] H. Jiao, J.L. Wang. Single crystal ellipsoidal and spherical particles of α-Fe₂O₃: Hydrothermal synthesis, formation mechanism, and magnetic properties. J Alloy Compd. 577 (2013) 402-408.
[45] R. Wang, C. Xu, J. Sun, L. Gao. Three-Dimensional Fe₂O₃ Nanocubes/Nitrogen-doped Graphene Aerogels: Nucleation Mechanism and Lithium Storage Properties. Sci Rep 4(2014) 7171.
[46] Z.G. An, J.J. Zhang, S.L. Pan, G.Z. Song. Novel peanut-like α-Fe₂O₃ superstructures: Oriented aggregation and Ostwald ripening in a one-pot solvothermal process. Powder Technol. 217(2012) 274-280.
[47] Y.X. Wang, X.Z. Cui, Z. Shu, Y.S. Li, H.R. Chen, J.L. Shi, A simple co-nanocasting method to synthesize high surface area mesoporous LaCoO₃ oxides for CO and NO oxidations, Micropor. Mesopor. Mat. 176 (2013) 8-15.
[48] R.E. Linga, Z. Lu, S. Youssef, O.C. Samy, L. Sergei, G. Daniel, D.G. Pascal, B. Jean-Marie, Methane-induced activation mechanism of fused ferric oxide-alumina catalysts during methane decomposition, ChemSusChem 9 (15) (2016) 1911-1915.
[49] A. Pérez, M. Orfila, M. Linares, M. Linares, R. Sanz, J. Marugán, R. Molina, J.A. Botas, Hydrogen production by thermochemical water splitting with La_0.8Al_0.2MeO_3-δ (Me= Fe, Co, Ni and Cu) perovskites prepared under controlled pH, Catal. Today. 390 (2022) 22-33.
[50] Y.G. Chen, N. Galinsky, Z.R. Wang, F.X. Li, Investigation of perovskite supported composite oxides for chemical looping conversion of syngas, Fuel 134 (2014) 521-530.
[51] H. Nishimoto, K. Nakagawa, N. Ikenaga, M. Nishitani-Gamo, T. Ando, T. Suzuki, Partial oxidation of methane to synthesis gas over oxidized diamond catalysts, Appl. Catal. A-Gen. 264 (1) (2004) 65-72.
[52] W.Y. Hernández, M.N. Tsampas, C. Zhao, A. Boreave, F. Bosselet, P. Vernoux, La/Sr-based perovskites as soot oxidation catalysts for Gasoline Particulate Filters, Catal. Today. 258 (2015) 525-534.
[53] D.Z. Shi, R.S. Hu, Q.H. Zhou, L.R. Yang, Catalytic activities of supported perovskite promoter catalysts La₂NiMnO₆-CuCl₂/γ-Al₂O₃ and La_1.7K_0.3NiMnO₆-CuCl₂/γ-Al₂O₃ for ethane oxychlorination, Chem. Eng. J. 288 (2016) 588-595.
[54] T. Yamashita, P. Hayes, Analysis of XPS spectra of Fe ²⁺ and Fe ³⁺ ions in oxide materials, Appl. Surf. Sci. 254 (8) (2008) 2441-2449.
[55] K. Sutthiumporn, S. Kawi, Promotional effect of alkaline earth over Ni–La₂O₃ catalyst for CO₂ reforming of CH₄: Role of surface oxygen species on H₂ production and carbon suppression, Int. J. Hydrogen Energ 36 (22) (2011) 14435-14446.
[56] J.L.G. Fierro, Structure and composition of perovskite surface in relation to adsorption and catalytic properties, Catal. Today. 8 (1990) 153-174.
[57] C.M. Shi, H.W. Qin, M. Zhao, X.F. Wang, L. Li, J.F. Hu, Investigation on electrical transport, CO sensing characteristics and mechanism for nanocrystalline La_1-xCa_xFeO₃ sensors, Sensor. Actuat. B-Chem. 190 (2014) 25-31.
[58] Z. Cheng, L. Qin, M.Q. Guo, M.Y. Xu, J.A. Fan, L. Fan, Oxygen vacancy promoted methane partial oxidation over iron oxide oxygen carriers in the chemical looping process, Phys. Chem. Chem. Phys. 18 (2016) 32418-32428.
[59] J. Yang, S.Y. Hu, L.M. Shi, S. Hoang, W.W Yang, Y.R. Fang, Z.F. Liang, C.Q. Pan, Y.H. Zhu, L. Li, J. Wu, J.P Hu, Y.B. Guo, Oxygen vacancies and Lewis acid sites synergistically promoted catalytic methane combustion over perovskite oxides, Environ. Sci. Technol. 55 (2021) 9243-9254.
[60] G. Tian, X.Y Liu, C.X Zhang, X.Y Fan, H. Xiong, X. Chen, Z.W. Li, B.H Yan, L. Zhang, N. Wang, H.J. Peng, F. Wei. Accelerating syngas-to-aromatic conversion via spontaneously monodispersed Fe in ZnCr₂O₄ spinel. Nat Commun. 13 (2022) 5567.

Chemical looping conversion of methane via Fe₂O₃-LaFeO₃ calcined from LaFe-MOF precursor

Chemical looping conversion of methane via Fe₂O₃-LaFeO₃ calcined from LaFe-MOF precursor

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