Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane

doi:10.1016/j.cjche.2024.07.025

中国化学工程学报 ›› 2024, Vol. 76 ›› Issue (12): 281-291.DOI: 10.1016/j.cjche.2024.07.025

Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane

Tongming Su¹, Bo Gong¹, Xinling Xie¹, Xuan Luo¹, Zuzeng Qin¹, Hongbing Ji^1,2

1. School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;
2. Zhejiang Green Petrochemical and Light Hydrocarbon Transformation Research Institute, Zhejiang University of Technology, Hangzhou 310014, China

收稿日期:2024-04-14 修回日期:2024-07-21 接受日期:2024-07-22 出版日期:2024-12-28 发布日期:2024-09-28
通讯作者: Zuzeng Qin,E-mail:qinzuzeng@gxu.edu.cn
基金资助:
This work was supported by the Guangxi Natural Science Foundation (2020GXNSFDA297007), the National Natural Science Foundation of China (22078074), and the Special Funding for ‘Guangxi Bagui Scholars’.

Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane

Tongming Su¹, Bo Gong¹, Xinling Xie¹, Xuan Luo¹, Zuzeng Qin¹, Hongbing Ji^1,2

1. School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;
2. Zhejiang Green Petrochemical and Light Hydrocarbon Transformation Research Institute, Zhejiang University of Technology, Hangzhou 310014, China

Received:2024-04-14 Revised:2024-07-21 Accepted:2024-07-22 Online:2024-12-28 Published:2024-09-28
Contact: Zuzeng Qin,E-mail:qinzuzeng@gxu.edu.cn
Supported by:
This work was supported by the Guangxi Natural Science Foundation (2020GXNSFDA297007), the National Natural Science Foundation of China (22078074), and the Special Funding for ‘Guangxi Bagui Scholars’.

摘要/Abstract

摘要： The dry reforming of methane (DRM) reaction can directly convert methane (CH₄) and carbon dioxide (CO₂) into syngas (H₂+CO), which is a promising method for achieving carbon neutralization. In this study, a series of 3Ni-xCo/Mg₁HAP alloy catalysts with different ratio were synthesized by the coprecipitation method, and the optimum Ni-Co ratio for the DRM reaction was studied. A series of characterization methods revealed that after Co was added, the formation of Ni-Co alloys increased the interactions between metals. However, an excess of Co inhibits the entry of Ni into the lattice of Mg₁HAP, resulting in metal accumulation on the surface of the support. In addition, the introduction of Co improves the dispersion of Ni metal, which endows the catalyst with better catalytic activity and stability. Raman spectroscopy of the catalyst after the stability test showed that the addition of Co reduced the proportion of graphitic carbon, which was also the main reason for its improved stability.

关键词: Methane, Carbon dioxide, Hydroxyapatite, Nickel, Cobalt

Abstract: The dry reforming of methane (DRM) reaction can directly convert methane (CH₄) and carbon dioxide (CO₂) into syngas (H₂+CO), which is a promising method for achieving carbon neutralization. In this study, a series of 3Ni-xCo/Mg₁HAP alloy catalysts with different ratio were synthesized by the coprecipitation method, and the optimum Ni-Co ratio for the DRM reaction was studied. A series of characterization methods revealed that after Co was added, the formation of Ni-Co alloys increased the interactions between metals. However, an excess of Co inhibits the entry of Ni into the lattice of Mg₁HAP, resulting in metal accumulation on the surface of the support. In addition, the introduction of Co improves the dispersion of Ni metal, which endows the catalyst with better catalytic activity and stability. Raman spectroscopy of the catalyst after the stability test showed that the addition of Co reduced the proportion of graphitic carbon, which was also the main reason for its improved stability.

Key words: Methane, Carbon dioxide, Hydroxyapatite, Nickel, Cobalt

Tongming Su, Bo Gong, Xinling Xie, Xuan Luo, Zuzeng Qin, Hongbing Ji. Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane[J]. 中国化学工程学报, 2024, 76(12): 281-291.

参考文献

[1] A.G. Olabi, M. Ali Abdelkareem, Renewable energy and climate change, Renew. Sustain. Energy Rev. 158 (2022) 112111.
[2] A. Munyentwali, H. Li, Q.H. Yang, Review of advances in bifunctional solid acid/base catalysts for sustainable biodiesel production, Appl. Catal. A Gen. 633 (2022) 118525.
[3] C.W. Mao, Y.X. Chang, X.T. Zhao, X.Y. Dong, Y.F. Geng, N. Zhang, L. Dai, X.W. Wu, L. Wang, Z.X. He, Functional carbon materials for high-performance Zn metal anodes, J. Energy Chem. 75 (2022) 135-153.
[4] E. Chamanehpour, M.H. Sayadi, M. Hajiani, A hierarchical graphitic carbon nitride supported by metal-organic framework and copper nanocomposite as a novel bifunctional catalyst with long-term stability for enhanced carbon dioxide photoreduction under solar light irradiation, Adv. Compos. Hybrid Mater. 5 (3) (2022) 2461-2477.
[5] S.L. Hamukwaya, Z.Y. Zhao, H.Y. Hao, H.M. Abo-Dief, K.M. Abualnaja, A.K. Alanazi, M.M. Mashingaidze, S.M. El-Bahy, M.N. Huang, Z.H. Guo, Enhanced photocatalytic performance for hydrogen production and carbon dioxide reduction by a mesoporous single-crystal-like TiO₂ composite catalyst, Adv. Compos. Hybrid Mater. 5 (3) (2022) 2620-2630.
[6] J.Y. Wang, R. Fu, S.K. Wen, P. Ning, M.H. Helal, M.A. Salem, B.B. Xu, Z.M. El-Bahy, M.N. Huang, Z.H. Guo, L. Huang, Q. Wang, Progress and current challenges for CO₂ capture materials from ambient air, Adv. Compos. Hybrid Mater. 5 (4) (2022) 2721-2759.
[7] J.M. Shi, A.G. Wang, Y.L. An, S. Chen, C.Y. Bi, L.N. Qu, C. Shi, F.Y. Kang, C.F. Sun, Z.H. Huang, H.J. Qi, J.G. Hu, Core@shell-structured catalysts based on Mg-O-Cu bond for highly selective photoreduction of carbon dioxide to methane, Adv. Compos. Hybrid Mater. 7 (1) (2023) 2.
[8] Q.L.M. Ha, H. Atia, C. Kreyenschulte, H. Lund, S. Bartling, G. Lisak, S. Wohlrab, U. Armbruster, Effects of modifier (Gd, Sc, La) addition on the stability of low Ni content catalyst for dry reforming of model biogas, Fuel 312 (2022) 122823.
[9] Z.P. Zou, T. Zhang, L. Lv, W.X. Tang, G.Q. Zhang, R. Kumar Gupta, Y. Wang, S.W. Tang, Preparation adjacent Ni-Co bimetallic nano catalyst for dry reforming of methane, Fuel 343 (2023) 128013.
[10] X.T. Cui, S.K. Kaer, A comparative study on three reactor types for methanol synthesis from syngas and CO₂, Chem. Eng. J. 393 (2020) 124632.
[11] J. Yang, W.P. Ma, D. Chen, A. Holmen, B.H. Davis, Fischer-Tropsch synthesis: A review of the effect of CO conversion on methane selectivity, Appl. Catal. A Gen. 470 (2014) 250-260.
[12] Y.L. Huang, X.D. Li, Q. Zhang, V.A. Vinokurov, W. Huang, Enhanced carbon tolerance of hydrotalcite-derived Ni-Ir/Mg(Al)O catalysts in dry reforming of methane under elevated pressures, Fuel Process. Technol. 237 (2022) 107446.
[13] T. Kobayashi, T. Furuya, H. Fujitsuka, T. Tago, Synthesis of Birdcage-type zeolite encapsulating ultrafine Pt nanoparticles and its application in dry reforming of methane, Chem. Eng. J. 377 (2019) 120203.
[14] Z.Y. Liu, F. Zhang, N. Rui, X. Li, L.L. Lin, L.E. Betancourt, D. Su, W.Q. Xu, J.J. Cen, K. Attenkofer, H. Idriss, J.A. Rodriguez, S.D. Senanayake, Highly active ceria-supported Ru catalyst for the dry reforming of methane: In situ identification of Ru^δ+-Ce³⁺ interactions for enhanced conversion, ACS Catal. 9 (4) (2019) 3349-3359.
[15] R.K. Singha, A. Shukla, A. Sandupatla, G. Deo, R. Bal, Synthesis and catalytic activity of a Pd doped Ni-MgO catalyst for dry reforming of methane, J. Mater. Chem. A 5 (30) (2017) 15688-15699.
[16] J. Wu, L.Y. Qiao, Z.F. Zhou, G.J. Cui, S.S. Zong, D.J. Xu, R.P. Ye, R.P. Chen, R. Si, Y.G. Yao, Revealing the synergistic effects of Rh and substituted La₂B₂O₇ (B = Zr or Ti) for preserving the reactivity of catalyst in dry reforming of methane, ACS Catal. 9 (2) (2019) 932-945.
[17] Y. Fu, W. Kong, B. Pan, C. Yuan, S. Li, H. Zhu, J. Zhang, In situ redispersion of rhodium nanocatalyst for CO₂ reforming of CH₄, Journal of Environmental Chemical Engineering, 9(4) (2021) 105790.
[18] W.J. Jang, J.O. Shim, H.M. Kim, S.Y. Yoo, H.S. Roh, A review on dry reforming of methane in aspect of catalytic properties, Catal. Today 324 (2019) 15-26.
[19] Y. Xu, X.H. Du, J. Li, P. Wang, J. Zhu, F.J. Ge, J. Zhou, M. Song, W.Y. Zhu, A comparison of Al₂O₃ and SiO₂ supported Ni-based catalysts in their performance for the dry reforming of methane, J. Fuel Chem. Technol. 47 (2) (2019) 199-208.
[20] M.A. Khan, M.S. Challiwala, A.V. Prakash, N.O. Elbashir, Conceptual modeling of a reactor bed of a nickel-copper bi-metallic catalyst for dry reforming of methane, Chem. Eng. Sci. 267 (2023) 118315.
[21] P.B. Kurmashov, A.G. Bannov, M.V. Popov, A.E. Brester, A.V. Ukhina, A.V. Ishchenko, E.A. Maksimovskii, L.I. Tolstobrova, A.O. Chulkov, G.G. Kuvshinov, COx-free catalytic decomposition of methane over solution combustion synthesis derived catalyst: Synthesis of hydrogen and carbon nanofibers, Int. J. Energy Res. 46 (9) (2022) 11957-11971.
[22] L. Yao, J. Shi, H.L. Xu, W. Shen, C.W. Hu, Low-temperature CO₂ reforming of methane on Zr-promoted Ni/SiO₂ catalyst, Fuel Process. Technol. 144 (2016) 1-7.
[23] Y. Kathiraser, U. Oemar, E.T. Saw, Z.W. Li, S. Kawi, Kinetic and mechanistic aspects for CO₂ reforming of methane over Ni based catalysts, Chem. Eng. J. 278 (2015) 62-78.
[24] M. Grabchenko, G. Pantaleo, F. Puleo, T.S. Kharlamova, V.I. Zaikovskii, O. Vodyankina, L.F. Liotta, Design of Ni-based catalysts supported over binary La-Ce oxides: Influence of La/Ce ratio on the catalytic performances in DRM, Catal. Today 382 (2021) 71-81.
[25] P.K. Chaudhary, G. Deo, Process and catalyst improvements for the dry reforming of methane, Chem. Eng. Sci. 276 (2023) 118767.
[26] R.L.B.A. Medeiros, G.P. Figueredo, H.P. Macedo, A.A.S. Oliveira, R.C. Rabelo-Neto, D.M.A. Melo, R.M. Braga, M.A.F. Melo, One-pot microwave-assisted combustion synthesis of Ni-Al₂O₃ nanocatalysts for hydrogen production via dry reforming of methane, Fuel 287 (2021) 119511.
[27] J.G. Meng, W. Pan, T.T. Gu, C.S. Bu, J.B. Zhang, X.Y. Wang, C.Q. Liu, H. Xie, G.L. Piao, One-pot synthesis of a highly active and stable Ni-embedded hydroxyapatite catalyst for syngas production via dry reforming of methane, Energy Fuels 35 (23) (2021) 19568-19580.
[28] L. Baharudin, A.C.K. Yip, V. Golovko, M.J. Watson, Potential of metal monoliths with grown carbon nanomaterials as catalyst support in intensified steam reformer: A perspective, Rev. Chem. Eng. 36 (4) (2020) 459-491.
[29] C.Y. Jiang, M.R. Akkullu, B. Li, J.C. Davila, M.J. Janik, K.M. Dooley, Rapid screening of ternary rare-earth-Transition metal catalysts for dry reforming of methane and characterization of final structures, J. Catal. 377 (2019) 332-342.
[30] J. Wang, Y.R. Mao, L.Z. Zhang, Y.L. Li, W.M. Liu, Q.X. Ma, D.S. Wu, H.G. Peng, Remarkable basic-metal oxides promoted confinement catalysts for CO₂ reforming, Fuel 315 (2022) 123167.
[31] X.L. He, D.Q. Zeng, Y.M. Liu, Q. Chen, J.R. Yang, R.C. Gao, T. Fujita, Y.Z. Wei, Porous CoxP nanosheets decorated Mn_0.35Cd_0.65S nanoparticles for highly enhanced noble-metal-free photocatalytic H₂ generation, J. Colloid Interface Sci. 625 (2022) 859-870.
[32] F.G. Wang, K.H. Han, L.L. Xu, H. Yu, W.D. Shi, Ni/SiO₂ catalyst prepared by strong electrostatic adsorption for a low-temperature methane dry reforming reaction, Ind. Eng. Chem. Res. 60 (8) (2021) 3324-3333.
[33] S. De, J.G. Zhang, R. Luque, N. Yan, Ni-based bimetallic heterogeneous catalysts for energy and environmental applications, Energy Environ. Sci. 9 (11) (2016) 3314-3347.
[34] Z. Bian, S. Das, M.H. Wai, P. Hongmanorom, S. Kawi, A review on bimetallic nickel-based catalysts for CO₂ reforming of methane, Chemphyschem 18 (22) (2017) 3117-3134.
[35] S.N.A. Rosli, S.Z. Abidin, O.U. Osazuwa, X.L. Fan, Y.L. Jiao, The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review, J. CO₂ Util. 63 (2022) 102109.
[36] D.L. Li, S.P. Xu, K. Song, C.Q. Chen, Y.Y. Zhan, L.L. Jiang, Hydrotalcite-derived Co/Mg(Al) O as a stable and coke-resistant catalyst for low-temperature carbon dioxide reforming of methane, Appl. Catal. A Gen. 552 (2018) 21-29.
[37] X.L. Fan, Z.T. Liu, Y.A. Zhu, G.S. Tong, J.D. Zhang, C. Engelbrekt, J. Ulstrup, K.K. Zhu, X.G. Zhou, Tuning the composition of metastable Co_x Ni _y Mg_100-x-y (OH)(OCH₃) nanoplates for optimizing robust methane dry reforming catalyst, J. Catal. 330 (2015) 106-119.
[38] B. Erdogan, H. Arbag, N. Yasyerli, SBA-15 supported mesoporous Ni and Co catalysts with high coke resistance for dry reforming of methane, Int. J. Hydrog. Energy 43 (3) (2018) 1396-1405.
[39] B. AlSabban, L. Falivene, S.M. Kozlov, A. Aguilar-Tapia, S. Ould-Chikh, J.L. Hazemann, L. Cavallo, J.M. Basset, K. Takanabe, In-operando elucidation of bimetallic CoNi nanoparticles during high-temperature CH₄/CO₂ reaction, Appl. Catal. B Environ. 213 (2017) 177-189.
[40] K.F. Sheng, D. Luan, H. Jiang, F. Zeng, B. Wei, F. Pang, J.P. Ge, Ni_xCo_y nanocatalyst supported by ZrO₂ hollow sphere for dry reforming of methane: Synergetic catalysis by Ni and co in alloy, ACS Appl. Mater. Interfaces 11 (27) (2019) 24078-24087.
[41] M.A. Vasiliades, P. Djinovic, A. Pintar, J. Kovac, A.M. Efstathiou, The effect of CeO₂-ZrO₂ structural differences on the origin and reactivity of carbon formed during methane dry reforming over NiCo/CeO₂-ZrO₂ catalysts studied by transient techniques, Catal. Sci. Technol. 7 (22) (2017) 5422-5434.
[42] M.A. Vasiliades, C.M. Damaskinos, P. Djinovic, A. Pintar, A.M. Efstathiou, Dry reforming of CH₄ over NiCo/Ce_0.75Zr_0.25O₂-δ: The effect of co on the site activity and carbon pathways studied by transient techniques, Catal. Commun. 149 (2021) 106237.
[43] M.A. Vasiliades, C.M. Damaskinos, P. Djinovic, A. Pintar, A.M. Efstathiou, A transient isotopic study for investigating important design parameters of NiCo/Ce0.75Zr0.25O₂-δ catalyst for the dry reforming of methane, Catal. Commun. 178 (2023) 106674.
[44] B. Gong, T.M. Su, X.L. Xie, H.B. Ji, Z.Z. Qin, Promotional effects of Mg-substituted Ni/MgxHAP catalysts on carbon resistance during dry reforming of methane, Ind. Eng. Chem. Res. 62 (33) (2023) 12935-12948.
[45] C.S. Wang, T.M. Su, Z.Z. Qin, H.B. Ji, Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: Effects of indium on the Ni/Al₂O₃ catalyst, Catal. Sci. Technol. 12 (15) (2022) 4826-4836.
[46] J. Horlyck, C. Lawrey, E.C. Lovell, R. Amal, J. Scott, Elucidating the impact of Ni and Co loading on the selectivity of bimetallic NiCo catalysts for dry reforming of methane, Chem. Eng. J. 352 (2018) 572-580.
[47] J. Horlyck, M. Sara, E.C. Lovell, R. Amal, J. Scott, Effect of metal-support interactions in mixed Co/Al catalysts for dry reforming of methane, ChemCatChem 11 (15) (2019) 3432-3440.
[48] I.V. Zagaynov, A.S. Loktev, A.L. Arashanova, V.K. Ivanov, A.G. Dedov, I.I. Moiseev, Ni(Co)-Gd_0.1Ti_0.1Zr_0.1Ce_0.7O₂ mesoporous materials in partial oxidation and dry reforming of methane into synthesis gas, Chem. Eng. J. 290 (2016) 193-200.
[49] Q. Song, R. Ran, X.D. Wu, Z.C. Si, D. Weng, Dry reforming of methane over Ni catalysts supported on micro- and mesoporous silica, J. CO₂ Util. 68 (2023) 102387.
[50] Y.X. Lin, C. Yang, W. Zhang, H. Machida, K. Norinaga, Lattice Boltzmann study on the effect of hierarchical pore structure on fluid flow and coke formation characteristics in open-cell foam for dry reforming of methane, Chem. Eng. Sci. 268 (2023) 118380.
[51] Z. Boukha, M. Kacimi, M.F.R. Pereira, J.L. Faria, J.L. Figueiredo, M. Ziyad, Methane dry reforming on Ni loaded hydroxyapatite and fluoroapatite, Appl. Catal. A Gen. 317 (2) (2007) 299-309.
[52] J.H. Park, S. Yeo, T.J. Kang, I. Heo, K.Y. Lee, T.S. Chang, Enhanced stability of Co catalysts supported on phosphorus-modified Al₂O₃ for dry reforming of CH₄, Fuel 212 (2018) 77-87.
[53] X.M. Lei, X.Z. Du, H. Xin, X.Q. Chen, H.R. Yang, L.Y. Zhou, Y. Zeng, H.L. Zhang, Y.F. Tian, D. Li, C.W. Hu, Chemical-switching strategy for the production of green biofuel on NiCo/MCM-41 catalysts by tuning atmosphere, Fuel 315 (2022) 123118.
[54] K. Liu, F.L. Xing, Y.Y. Xiao, N. Yan, K.I. Shimizu, S. Furukawa, Development of a highly stable ternary alloy catalyst for dry reforming of methane, ACS Catal. 13 (6) (2023) 3541-3548.
[55] L.L. Wang, G.G. Tang, S. Liu, H.L. Dong, Q.Q. Liu, J.F. Sun, H. Tang, Interfacial active-site-rich 0D Co₃O₄/1D TiO₂ p-n heterojunction for enhanced photocatalytic hydrogen evolution, Chem. Eng. J. 428 (2022) 131338.
[56] Y.X. Shi, L.L. Li, Z. Xu, F. Guo, W.L. Shi, Construction of full solar-spectrum available S-scheme heterojunction for boosted photothermal-assisted photocatalytic H₂ production, Chem. Eng. J. 459 (2023) 141549.
[57] C. Han, X.D. Zhang, S.S. Huang, Y. Hu, Z. Yang, T.T. Li, Q.P. Li, J.J. Qian, MOF-on-MOF-derived hollow Co₃ O₄/In₂ O₃ nanostructure for efficient photocatalytic CO₂ reduction, Adv. Sci. 10 (19) (2023) e2300797.
[58] J.N. Xin, H.J. Cui, Z.M. Cheng, Z.M. Zhou, Bimetallic Ni-Co/SBA-15 catalysts prepared by urea co-precipitation for dry reforming of methane, Appl. Catal. A Gen. 554 (2018) 95-104.
[59] M. Abbas, U. Sikander, M.T. Mehran, S.H. Kim, Exceptional stability of hydrotalcite derived spinel Mg(Ni)Al₂O₄ catalyst for dry reforming of methane, Catal. Today 403 (2022) 74-85.
[60] A.N.T. Cao, C.Q. Pham, T.M. Nguyen, T. Van Tran, P.T.T. Phuong, D.V N. Vo, Dysprosium promotion on Co/Al₂O₃ catalysts towards enhanced hydrogen generation from methane dry reforming, Fuel 324 (2022) 124818.
[61] Y. Kwon, J.E. Eichler, C.B. Mullins, NiAl₂O₄ as a beneficial precursor for Ni/Al₂O₃ catalysts for the dry reforming of methane, J. CO₂ Util. 63 (2022) 102112.
[62] J.C.S. Araujo, A.L.G. Pinheiro, A.C. Oliveira, M.G.A. Cruz, J.M.C. Bueno, R.S. Araujo, R. Lang, Catalytic assessment of nanostructured Pt/xLa2O₃-Al₂O₃ oxides for hydrogen production by dry reforming of methane: Effects of the lanthana content on the catalytic activity, Catal. Today 349 (2020) 141-149.
[63] J. Sun, D. Yamaguchi, L.G. Tang, S. Periasamy, H.Y. Ma, J.N. Hart, C.A. Ken, Enhancement of oxygen exchanging capability by loading a small amount of ruthenium over ceria-zirconia on dry reforming of methane, Adv. Powder Technol. 33 (2) (2022) 103407.
[64] J.G. Meng, T.T. Gu, W. Pan, C.S. Bu, J.B. Zhang, X.Y. Wang, C.Q. Liu, H. Xie, G.L. Piao, Promotional effects of defects on Ni/HAP catalyst for carbon resistance and durability during dry reforming of methane, Fuel 310 (2022) 122363.

Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane

Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Xufang Chen, Xin Shu, Yanru Zhu, Jian Zhang, Zhigang Chai, Hongyan Song, Zhe An, Jing He. Highly dispersed MgInCe-mixed metal oxides catalyzed direct carbonylation of glycerol and CO₂ into glycerol carbonate[J]. 中国化学工程学报, 2024, 72(8): 153-163.
[2]	Junjie Cai, Xijian Li, Hao Sui, Honggao Xie. Study on the evolution of solid–liquid–gas in multi-scale pore methane in tectonic coal[J]. 中国化学工程学报, 2024, 71(7): 122-131.
[3]	Shutong Pang, Hualiang An, Xinqiang Zhao, Yanji Wang. Ionic liquid-assisted preparation of hydroxyapatite and its catalytic performance for decarboxylation of itaconic acid[J]. 中国化学工程学报, 2024, 67(3): 9-15.
[4]	Haixin Sun, Jianlei Qi, Jianfei Sun, Lin Li, Kunpeng Yu, Jintao Wu, Jianzhong Yin. Solubility of iron(III) and nickel(II) acetylacetonates in supercritical carbon dioxide[J]. 中国化学工程学报, 2024, 65(1): 29-34.
[5]	Songling Guo, Xun Tao, Fan Zhou, Mengyan Yu, Yufan Wu, Yunfei Gao, Lu Ding, Fuchen Wang. Investigation of oxy-fuel combustion for methane and acid gas in a diffusion flame[J]. 中国化学工程学报, 2024, 65(1): 106-116.
[6]	Chaojie Li, Xianxin Fang, Meiling Sun, Jihai Duan, Weiwen Wang. Study on two-phase cloud dispersion from liquefied CO₂ release[J]. 中国化学工程学报, 2023, 60(8): 37-45.
[7]	Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang. Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling[J]. 中国化学工程学报, 2023, 59(7): 105-117.
[8]	Yi Wu, Pengfei Song, Ningyan Li, Yanan Jiang, Yuan Liu. Molybdenum tailored Co⁰/Co²⁺ active pairs on a perovskite-type oxide for direct ethanol synthesis from syngas[J]. 中国化学工程学报, 2023, 59(7): 279-289.
[9]	Tatyana P. Adamova, Sergey S. Skiba, Andrey Yu. Manakov, Sergey Y. Misyura. Growth rate of CO₂ hydrate film on water–oil and water–gaseous CO₂ interface[J]. 中国化学工程学报, 2023, 56(4): 266-272.
[10]	Bowen Jiang, Jia Liu, Guoqiang Yang, Zhibing Zhang. Efficient conversion of CO₂ into cyclic carbonates under atmospheric by halogen and metal-free poly(ionic liquid)s[J]. 中国化学工程学报, 2023, 55(3): 202-211.
[11]	Mingdong Sun, Dongxin Pan, Tingting Ye, Jing Gu, Yu Zhou, Jun Wang. Ionic porous polyamide derived N-doped carbon towards highly selective electroreduction of CO₂[J]. 中国化学工程学报, 2023, 55(3): 212-221.
[12]	Yu Wang, Qunfeng Zhang, Xinlei Liu, Junqi Weng, Guanghua Ye, Xinggui Zhou. Probing deactivation by coking in catalyst pellets for dry reforming of methane using a pore network model[J]. 中国化学工程学报, 2023, 55(3): 293-303.
[13]	Mengge Shang, Jing Zhang, Jinqiang Sun, Shimo Yu, Feng Hua, Xiaoxu Xuan, Xun Sun, Serguei Filatov, Xibin Yi. Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption[J]. 中国化学工程学报, 2023, 54(2): 36-43.
[14]	Xianglin Liu, Minjie Xu, Chenxi Cao, Zixu Yang, Jing Xu. Effects of zinc on χ-Fe₅C₂ for carbon dioxide hydrogenation to olefins: Insights from experimental and density function theory calculations[J]. 中国化学工程学报, 2023, 54(2): 206-214.
[15]	Zhongyao Zhang, Ming Gao, Xiaopeng Chen, Xiaojie Wei, Jiezhen Liang, Chenghong Wu, Linlin Wang. The Joule–Thomson effect of (CO₂ + H₂) binary system relevant to gas switching reforming with carbon capture and storage (CCS)[J]. 中国化学工程学报, 2023, 54(2): 215-231.