Impact of sugar type on thiophene hydrodesulfurization performance of three-dimensional porous CoMo bulk catalysts prepared via the sugar foaming method

doi:10.1016/j.cjche.2025.07.012

中国化学工程学报 ›› 2025, Vol. 88 ›› Issue (12): 310-320.DOI: 10.1016/j.cjche.2025.07.012

Impact of sugar type on thiophene hydrodesulfurization performance of three-dimensional porous CoMo bulk catalysts prepared via the sugar foaming method

Yeqiang Du¹, Fanfang Meng², Wenjing Song¹, Longzhou Ren¹, Qinqin Zhang³, Liancheng Bing¹, Fang Wang¹, Guangjian Wang¹, Haitao Fu⁴, Dezhi Han¹

1. State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
2. Petrochemical Research Institute, PetroChina, Beijing 102206, China;
3. Shandong Provincial Key Laboratory of Biochemical Engineering, College of Biological Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
4. School of Metallurgy, Northeastern University, Shenyang 110819, China

收稿日期:2025-04-01 修回日期:2025-07-21 接受日期:2025-07-27 出版日期:2026-02-09 发布日期:2025-08-16
通讯作者: Dezhi Han,E-mail:handzh@qust.edu.cn
基金资助:
This work was supported by the Natural Science Foundation of Shandong Province (ZR2022MB019, ZR2021MB134) and the National Natural Science Foundation of China (22008131, 51974086).

Impact of sugar type on thiophene hydrodesulfurization performance of three-dimensional porous CoMo bulk catalysts prepared via the sugar foaming method

Yeqiang Du¹, Fanfang Meng², Wenjing Song¹, Longzhou Ren¹, Qinqin Zhang³, Liancheng Bing¹, Fang Wang¹, Guangjian Wang¹, Haitao Fu⁴, Dezhi Han¹

1. State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
2. Petrochemical Research Institute, PetroChina, Beijing 102206, China;
3. Shandong Provincial Key Laboratory of Biochemical Engineering, College of Biological Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
4. School of Metallurgy, Northeastern University, Shenyang 110819, China

Received:2025-04-01 Revised:2025-07-21 Accepted:2025-07-27 Online:2026-02-09 Published:2025-08-16
Contact: Dezhi Han,E-mail:handzh@qust.edu.cn
Supported by:
This work was supported by the Natural Science Foundation of Shandong Province (ZR2022MB019, ZR2021MB134) and the National Natural Science Foundation of China (22008131, 51974086).

摘要/Abstract

摘要： The dispersibility of active components in hydrodesulfurization (HDS) catalysts significantly influences the corresponding catalytic performance. In this study, sugar-based materials (glucose, chitosan, soluble starch, and corn starch) were utilized to prepare CoMo bulk HDS catalysts through a sugar foaming process. The foaming intermediates were analyzed using TG, FTIR, and Raman techniques to investigate the pyrolysis and carbonization process, revealing the presence of graphitic carbon in the 3DPG, 3DPSS, and 3DPCS catalysts even after calcination in an air atmosphere. The catalysts were further characterized using SEM, XRD, TEM, low-temperature N₂ physical adsorption, and XPS. The 3DPSS catalyst exhibited a thiophene conversion of 94.8% at 360 ℃ and 1 MPa, which could be ascribed to its unique three-dimensional pore structure, high dispersion of MoS₂ (0.21), and high fraction of Mo⁴⁺ (83.14%). This study demonstrates the potential of using the sugar foaming technique to develop highly efficient HDS catalysts and provides new insights into the relationship between the physicochemical properties of the obtained catalysts and their catalytic performance.

关键词: HDS, Catalyst, Fixed-bed, Sugar foaming, Three-dimensional porous structure

Abstract: The dispersibility of active components in hydrodesulfurization (HDS) catalysts significantly influences the corresponding catalytic performance. In this study, sugar-based materials (glucose, chitosan, soluble starch, and corn starch) were utilized to prepare CoMo bulk HDS catalysts through a sugar foaming process. The foaming intermediates were analyzed using TG, FTIR, and Raman techniques to investigate the pyrolysis and carbonization process, revealing the presence of graphitic carbon in the 3DPG, 3DPSS, and 3DPCS catalysts even after calcination in an air atmosphere. The catalysts were further characterized using SEM, XRD, TEM, low-temperature N₂ physical adsorption, and XPS. The 3DPSS catalyst exhibited a thiophene conversion of 94.8% at 360 ℃ and 1 MPa, which could be ascribed to its unique three-dimensional pore structure, high dispersion of MoS₂ (0.21), and high fraction of Mo⁴⁺ (83.14%). This study demonstrates the potential of using the sugar foaming technique to develop highly efficient HDS catalysts and provides new insights into the relationship between the physicochemical properties of the obtained catalysts and their catalytic performance.

Key words: HDS, Catalyst, Fixed-bed, Sugar foaming, Three-dimensional porous structure

Yeqiang Du, Fanfang Meng, Wenjing Song, Longzhou Ren, Qinqin Zhang, Liancheng Bing, Fang Wang, Guangjian Wang, Haitao Fu, Dezhi Han. Impact of sugar type on thiophene hydrodesulfurization performance of three-dimensional porous CoMo bulk catalysts prepared via the sugar foaming method[J]. 中国化学工程学报, 2025, 88(12): 310-320.

参考文献

[1] L.F. Zhu, X.Y. Zhu, Energy policy, market environment and the economic benefits of enterprises: evidence from China’s petrochemical enterprises, Nat. Hazards 95 (1) (2019) 113-127.
[2] V. Chandra Srivastava, An evaluation of desulfurization technologies for sulfur removal from liquid fuels, RSC Adv. 2 (3) (2012) 759-783.
[3] R.G. Faria, D. Silva, F. Mirante, S. Gago, L. Cunha-Silva, S.S. Balula, Advanced technologies conciliating desulfurization and denitrogenation to prepare clean fuels, Catalysts 14 (2) (2024) 137.
[4] I. Shafiq, S. Shafique, P. Akhter, W.S. Yang, M. Hussain, Recent developments in alumina supported hydrodesulfurization catalysts for the production of sulfur-free refinery products: a technical review, Catal. Rev. 64 (1) (2022) 1-86.
[5] F. Schmidt, New catalyst preparation technologies: observed from an industrial viewpoint, Appl. Catal. A Gen. 221 (1-2) (2001) 15-21.
[6] S.A. Awad, S.A. Gheni, G.H. Abdullah, S.M.R. Ahmed, Design and evaluation of a co-Mo-supported nano alumina ultradeep hydrodesulfurization catalyst for production of environmentally friendly diesel fuel in a trickle bed reactor, ACS Omega 5 (21) (2020) 12081-12089.
[7] E.L. Wang, F.H. Yang, M.Y. Song, G.L. Chen, Q.Q. Zhang, F. Wang, L.C. Bing, G.J. Wang, D.Z. Han, Recent advances in the unsupported catalysts for the hydrodesulfurization of fuel, Fuel Process. Technol. 235 (2022) 107386.
[8] H.Y. Shang, C.G. Liu, Y.Q. Xu, J.S. Qiu, F. Wei, States of carbon nanotube supported Mo-based HDS catalysts, Fuel Process. Technol. 88 (2) (2007) 117-123.
[9] W.W. Zhou, L. Yang, L. Liu, Z.P. Chen, A.N. Zhou, Y.T. Zhang, X.F. He, F.X. Shi, Z.G. Zhao, Synthesis of novel NiMo catalysts supported on highly ordered TiO₂-Al₂O₃ composites and their superior catalytic performance for 4, 6-dimethyldibenzothiophene hydrodesulfurization, Appl. Catal. B Environ. 268 (2020) 118428.
[10] Plantenga F L, Cerfontain R, Eijsbouts S. 89 “Nebula”: A hydroprocessing catalyst with breakthrough activity. Studies in Surface Science and Catalysis 2003;145: 407-410.
[11] H.P. Zhang, H.F. Lin, Y. Zheng, Deactivation study of unsupported nano MoS₂ catalyst, Carbon Resour. Convers. 3 (2020) 60-66.
[12] S.Y. Chu, W.X. Zhou, C.Y. Zhang, Y. Zheng, Y. Liu, Y.J. Liu, Relationship between the structure and catalytic performance of MoS₂ with different surfactant-assisted syntheses in the hydrodesulfurization reaction of 4, 6-DMDBT, RSC Adv. 10 (13) (2020) 7600-7608.
[13] V. Hetier, D. Pena, A. Carvalho, L. Courtheoux, V. Flaud, E. Girard, D. Uzio, S. Brunet, P. Lacroix-Desmazes, A. Pradel, Influence of pluronic^® P123 addition in the synthesis of bulk Ni promoted MoS₂ catalyst. application to the selective hydrodesulfurization of sulfur model molecules representative of FCC gasoline, Catalysts 9 (10) (2019) 793.
[14] J. Escobar, M.C. Barrera, J.A. Toledo, M.A. Cortes-Jacome, C. Angeles-Chavez, S. Nunez, V. Santes, E. Gomez, L. Diaz, E. Romero, J.G. Pacheco, Effect of ethyleneglycol addition on the properties of P-doped NiMo/Al₂O₃ HDS catalysts: Part I. Materials preparation and characterization, Appl. Catal. B Environ. 88 (3-4) (2009) 564-575.
[15] J.X. Yang, D.D. Hu, W. Li, S.H. Yi, Highly efficient microreactors with simultaneous separation of catalysts and products in deep desulfurization, Chem. Eng. J. 267 (2015) 93-101.
[16] D.Z. Han, Q.H. Li, E.L. Wang, W.P. Xie, G.L. Chen, Q.Q. Zhang, L.C. Bing, F. Wang, H.T. Fu, G.J. Wang, The evolution of NiMo unsupported catalysts with 3DOM structure for thiophene hydrodesulfurization, Catal. Today 405-406 (2022) 329-336.
[17] F.H. Yang, M.Y. Song, Y.Q. Du, Z.Q. Wan, E.L. Wang, Q.Q. Zhang, L.C. Bing, F. Wang, G.J. Wang, H.T. Fu, D.Z. Han, Enhanced hydrodesulfurization activity of thiophene over hollow tubular CoMo unsupported catalysts, React. Kinet. Mech. Catal. 137 (4) (2024) 1899-1910.
[18] Z.W. Zhang, P. Wang, F. Wang, Y.Q. Li, W. Lu, X.M. Jiang, X. Gui, Z. Yun, Controlling dispersion and morphology of MoS₂ nanospheres by hydrothermal method using SiO₂ as template, Chin. J. Chem. Eng. 26 (5) (2018) 1229-1234.
[19] N. Prabhu, A.K. Dalai, J. Adjaye, Hydrodesulphurization and hydrodenitrogenation of light gas oil using NiMo catalyst supported on functionalized mesoporous carbon, Appl. Catal. A Gen. 401 (1-2) (2011) 1-11.
[20] J.L. Liang, M.W. Fan, M.M. Wu, J.W. Hua, W.S. Cai, T.T. Huang, Y.Q. Liu, C.G. Liu, In situ synthesis of MoS₂ nanoflakes within a 3D mesoporous carbon framework for hydrodesulfurization of DBT, J. Catal. 415 (2022) 153-164.
[21] M.Y. Song, F.H. Yang, Y.Q. Du, Z.Q. Wan, L.C. Bing, Q.Q. Zhang, F. Wang, H.T. Fu, G.J. Wang, D.Z. Han, In-situ sulfurization synthesis of three-dimensional porous CoMoS/CMF catalysts for thiophene hydrodesulfurization, Catal. Lett. 154 (10) (2024) 5487-5494.
[22] D.G. Gu, F.F. Wang, K. Yan, R.G. Ma, J.C. Wang, A thermally decomposable template route to synthesize nitrogen-doped wrinkled carbon nanosheets as highly efficient and stable electrocatalysts for the oxygen reduction reaction, ACS Sustainable Chem. Eng. 6 (2) (2018) 1951-1960.
[23] C. Li, E. Lepre, M. Bi, M. Antonietti, J.W. Zhu, Y.S. Fu, N. Lopez-Salas, Oxygen-rich carbon nitrides from an eutectic template strategy stabilize Ni, Fe nanosites for electrocatalytic oxygen evolution, Adv. Sci. (Weinh) 10 (22) (2023) e2300526.
[24] Z.X. Xu, X.Q. Deng, S. Zhang, Y.F. Shen, Y.Q. Shan, Z.M. Zhang, R. Luque, P.G. Duan, X. Hu, Benign-by-design N-doped carbonaceous materials obtained from the hydrothermal carbonization of sewage sludge for supercapacitor applications, Green Chem. 22 (12) (2020) 3885-3895.
[25] A. Deshpande, S. Rawat, I.M. Patil, S. Rane, T. Bhaskar, S.B. Ogale, S. Hotha, Converting renewable saccharides to heteroatom doped porous carbons as supercapacitor electrodes, Carbon 214 (2023) 118368.
[26] X.B. Wang, Y.J. Zhang, C.Y. Zhi, X. Wang, D.M. Tang, Y.B. Xu, Q.H. Weng, X.F. Jiang, M. Mitome, D. Golberg, Y. Bando, Three-dimensional strutted graphene grown by substrate-free sugar blowing for high-power-density supercapacitors, Nat. Commun. 4 (2013) 2905.
[27] Q.C. Li, Y.W. Tong, Y.B. Zeng, X.K. Gu, M.Y. Ding, Carbohydrate-regulated synthesis of ultrathin porous nitrogen-vacancy polymeric carbon nitride for highly efficient Visible-light hydrogen evolution, Chem. Eng. J. 450 (2022) 138010.
[28] Z.L. Chen, H.X. Jia, Y.C. Guo, Y. Li, Z.G. Liu, Nitrogen-doped hydrochars from shrimp waste as visible-light photocatalysts: Roles of nitrogen species, Environ. Res. 208 (2022) 112695.
[29] Y.H. Li, F.M. Chang, B. Huang, Y.P. Song, H.Y. Zhao, K.J. Wang, Activated carbon preparation from pyrolysis char of sewage sludge and its adsorption performance for organic compounds in sewage, Fuel 266 (2020) 117053.
[30] F. Bernsmann, B. Frisch, C. Ringwald, V. Ball, Protein adsorption on dopamine-melanin films: role of electrostatic interactions inferred from zeta-potential measurements versus chemisorption, J. Colloid Interface Sci. 344 (1) (2010) 54-60.
[31] T. Ouyang, T.Y. Zhang, H.Z. Wang, F. Yang, J. Yan, K. Zhu, K. Ye, G.L. Wang, L.M. Zhou, K. Cheng, D.X. Cao, High-throughput fabrication of porous carbon by chemical foaming strategy for high performance supercapacitor, Chem. Eng. J. 352 (2018) 459-468.
[32] Z. Ozcifci, M. Emirik, H.T. Akcay, T. Yumak, Production and characterization of activated carbon foams with various activation agents for electrochemical double layer capacitors (EDLCs) applications, Colloids Surf. A Physicochem. Eng. Aspects 690 (2024) 133851.
[33] Z.F. Hu, Z.R. Shen, J.C. Yu, Converting carbohydrates to carbon-based photocatalysts for environmental treatment, Environ. Sci. Technol. 51 (12) (2017) 7076-7083.
[34] X.Y. Zhang, T.W. Zhang, J.Q. Guo, W.Y. Zhu, M.R. Khan, H.N. Xiao, J.L. Song, Preparation of sucrose-derived activated carbon in one pot with desirable hierarchically porous structure for efficient dyes removal, Appl. Surf. Sci. Adv. 19 (2024) 100556.
[35] C.Z. Zhu, S.F. Fu, B.Z. Xu, J.H. Song, Q.R. Shi, M.H. Engelhard, X.L. Li, S.P. Beckman, J.M. Sun, D. Du, Y.H. Lin, Sugar blowing-induced porous cobalt phosphide/nitrogen-doped carbon nanostructures with enhanced electrochemical oxidation performance toward water and other small molecules, Small 13 (33) (2017). DOI: 10.1002/smll.201700796.
[36] M. Skorupska, P. Kamedulski, J.P. Lukaszewicz, A. Ilnicka, The improvement of energy storage performance by sucrose-derived carbon foams via incorporating nitrogen atoms, Nanomaterials (Basel) 11 (3) (2021) 760.
[37] S. Liu, Y.Q. Zhang, S. Gao, T. Fei, T. Zhang, A universal sugar-blowing approach to synthesize fluorescent nitrogen-doped carbon nanodots for detection of Hg(II), Appl. Surf. Sci. 544 (2021) 148725.
[38] C.Y. Ding, C.S. Shao, Z.Y. Li, Y. Ma, X.Z. Ren, S.S. Wu, C.C. Wei, L. Xia, B. Zhong, G.W. Wen, X.X. Huang, Divalent metal-ions blowing strategy achieved 3D luffa aerogels heterostructure for lightweight broadband microwave absorber, Carbon 219 (2024) 118787.
[39] K.S. Liu, H.R. Jin, L.W. Huang, Y.X. Luo, Z.H. Zhu, S.M. Dai, X.Y. Zhuang, Z.D. Wang, L. Huang, J. Zhou, Puffing ultrathin oxides with nonlayered structures, Sci. Adv. 8 (20) (2022) eabn2030.
[40] E. Wojaczynska, F. Steppeler, D. Iwan, M.C. Scherrmann, A. Marra, Synthesis and applications of carbohydrate-based organocatalysts, Molecules 26 (23) (2021) 7291.
[41] Y.Q. Du, L.Z. Ren, W.J. Song, Z.Q. Wan, Q.Q. Zhang, L.C. Bing, F. Wang, G.J. Wang, H.T. Fu, D.Z. Han, Low-temperature glucose foaming to construct three-dimensionally porous bulk CoMo catalyst for thiophene hydrodesulfurization, Fuel 379 (2025) 132997.
[42] M.G. Jin, L. Cheng, W. Zheng, Y. Ding, Y.M. Zhu, L.M. Jia, F. Huang, Raman tensor of graphite: Symmetry of G, D and D’ phonons, Sci. China Mater. 65 (1) (2022) 268-272.
[43] V.B. Mohan, M. Nieuwoudt, K. Jayaraman, D. Bhattacharyya, Quantification and analysis of Raman spectra of graphene materials, Graphene Technol. 2 (3) (2017) 47-62.
[44] J.B. Wu, M.L. Lin, X. Cong, H.N. Liu, P.H. Tan, Raman spectroscopy of graphene-based materials and its applications in related devices, Chem. Soc. Rev. 47 (5) (2018) 1822-1873.
[45] X.H. Liu, E.H. Wang, G.L. Feng, Z.G. Wu, W. Xiang, X.D. Guo, J.T. Li, B.H. Zhong, Z. Zheng, Compared investigation of carbon-decorated Na3V2(PO₄)3 with saccharides of different molecular weights as cathode of sodium ion batteries, Electrochim. Acta 286 (2018) 231-241.
[46] P.S. Shuttleworth, V. Budarin, R.J. White, V.M. Gun’ko, R. Luque, J.H. Clark, Molecular-level understanding of the carbonisation of polysaccharides, Chemistry 19 (28) (2013) 9351-9357.
[47] Z.L. Li, L.B. Deng, I.A. Kinloch, R.J. Young, Raman spectroscopy of carbon materials and their composites: Graphene, nanotubes and fibres, Prog. Mater. Sci. 135 (2023) 101089.
[48] M.A. Kazakova, A.A. Salomatina, V.Y. Pereyma, I.P. Prosvirin, A.V. Ishchenko, O.V. Klimov, A.S. Noskov, M.O. Kazakov, Selective hydrodesulfurization of FCC naphtha over carbon coated alumina supported CoMoS catalysts, Fuel 354 (2023) 129394.
[49] S.H. Joo, S.J. Choi, I. Oh, J. Kwak, Z. Liu, O. Terasaki, R. Ryoo, Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles, Nature 412 (6843) (2001) 169-172.
[50] C.X. Zhao, Y.X. Yang, Z.X. Wu, M. Field, X.Y. Fang, N. Burke, C.A. Ken, Synthesis and facile size control of well-dispersed cobalt nanoparticles supported on ordered mesoporous carbon, J. Mater. Chem. A 2 (46) (2014) 19903-19913.
[51] Z. Baig, O. Mamat, M. Mustapha, Recent progress on the dispersion and the strengthening effect of carbon nanotubes and graphene-reinforced metal nanocomposites: a review, Crit. Rev. Solid State Mater. Sci. 43 (1) (2018) 1-46.
[52] G. Berhault, A. Mehta, A.C. Pavel, J.Z. Yang, L. Rendon, M.J. Yacaman, L.C. Araiza, A.D. Moller, R.R. Chianelli, The role of structural carbon in transition metal sulfides hydrotreating catalysts, J. Catal. 198 (1) (2001) 9-19.
[53] F.S. Pereira, S. Lanfredi, E.R.P. Gonzalez, D.L. da Silva Agostini, H.M. Gomes, R. dos Santos Medeiros, Thermal and morphological study of chitosan metal complexes, J. Therm. Anal. Calorim. 129 (1) (2017) 291-301.
[54] A. Pawlak, M. Mucha, Thermogravimetric and FTIR studies of chitosan blends, Thermochim. Acta 396 (1-2) (2003) 153-166.
[55] G. Chinnasamy, K. Dekeba, V.P. Sundramurthy, B. Dereje, Physicochemical properties of tef starch: morphological, thermal, thermogravimetric, and pasting properties, Int. J. Food Prop. 25 (1) (2022) 1668-1682.
[56] Y. Liu, L.T. Yang, C.P. Ma, Y.Z. Zhang, Thermal behavior of sweet potato starch by non-isothermal thermogravimetric analysis, Materials (Basel) 12 (5) (2019) 699.
[57] Z.L. Wu, Y. Yu, H.W. Wu, Hydrothermal reactions of biomass-derived platform molecules: mechanistic insights into 5-hydroxymethylfurfural (5-HMF) formation during glucose and fructose decomposition, Energy Fuels 37 (3) (2023) 2115-2126.
[58] C. Chatterjee, F. Pong, A. Sen, Chemical conversion pathways for carbohydrates, Green Chem. 17 (1) (2015) 40-71.
[59] C.B. Rasrendra, M. Windt, Y. Wang, S. Adisasmito, I.G.B.N. Makertihartha, E.R.H. van Eck, D. Meier, H.J. Heeres, Experimental studies on the pyrolysis of humins from the acid-catalysed dehydration of C6-sugars, J. Anal. Appl. Pyrolysis 104 (2013) 299-307.
[60] Q. Wang, Y.F. Wang, S.-H. Luo, P.W. Li, S.X. Yan, Y.H. Zhang, X. Liu, W.N. Mu, F. Teng, Y.L. Wang, X.F. Lei, High-performance LiFePO₄ cathode material was prepared by multiple intensification process with acid-washed iron red as raw material, Int. J. Energy Res. 45 (12) (2021) 18245-18256.
[61] J.S. Ramos-Figueroa, T.J. Tse, J.H. Shen, S.K. Purdy, J.K. Kim, Y.J. Kim, B.K. Han, J.Y. Hong, Y.Y. Shim, M.J.T. Reaney, Foaming with starch: exploring faba bean aquafaba as a green alternative, Foods 12 (18) (2023) 3391.
[62] G.J. Wang, G.L. Chen, W.P. Xie, W.T. Wang, L.C. Bing, Q.Q. Zhang, H.T. Fu, F. Wang, D.Z. Han, Three-dimensionally ordered macroporous bulk catalysts with enhanced catalytic performance for thiophene hydrodesulfurization, Fuel Process. Technol. 199 (2020) 106268.
[63] D.Z. Han, X. Li, L. Zhang, Y.H. Wang, Z.F. Yan, S.M. Liu, Hierarchically ordered meso/macroporous γ-alumina for enhanced hydrodesulfurization performance, Microporous Mesoporous Mater. 158 (2012) 1-6.
[64] M.Y. Sun, P.J. Kooyman, R. Prins, A high-resolution transmission electron microscopy study of the influence of fluorine on the morphology and dispersion of WS₂ in sulfided W/Al₂O₃ and NiW/Al₂O₃ catalysts, J. Catal. 206 (2) (2002) 368-375.
[65] L. Vradman, M.V. Landau, M. Herskowitz, Hydrodearomatization of petroleum fuel fractions on silica supported Ni-W sulphide with increased stacking number of the WS₂ phase, Fuel 82 (6) (2003) 633-639.
[66] R.G. de Castro, E. Devers, M. Digne, A.F. Lamic-Humblot, G.D. Pirngruber, X. Carrier, Surface-dependent activity of model CoMoS hydrotreating catalysts, J. Catal. 403 (2021) 16-31.

Impact of sugar type on thiophene hydrodesulfurization performance of three-dimensional porous CoMo bulk catalysts prepared via the sugar foaming method

Impact of sugar type on thiophene hydrodesulfurization performance of three-dimensional porous CoMo bulk catalysts prepared via the sugar foaming method

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Zhenxing Feng, Bin Song, Zongcheng Zhan, Lei Xu, Hanlei Sun, Shuo Yao, Hongzhi Wang, Licheng Liu. The sulfur and water resistance improvement of Pt/TiO₂ catalyst for CO oxidation reaction by anatase and rutile TiO₂ crystal interfaces[J]. 中国化学工程学报, 2025, 85(9): 128-139.
[2]	Hansheng Wang, Xintian Luo, Kaixuan Chen, Benduan Xiao, Xu Zhang, Qingjun Meng, Huibing He, Jing Xu, Yong Jin. Research progress on the copper-based catalyst design for dimethyl oxalate hydrogenation to ethylene glycol[J]. 中国化学工程学报, 2025, 85(9): 189-205.
[3]	Yongbin Shen, Qihe Ma, Hua Yuan, Chuang Liu, Likun Yang, Hao Huang, Bowen Shi, Zhenhua Li, Shunyu Liang, Hu Li, Zhengping Dong. Selective catalytic deoxygenation of 1-octanol from Fischer-Tropsch C10 mixed oil[J]. 中国化学工程学报, 2025, 85(9): 270-279.
[4]	Qingyu Wang, Duiping Liu, Yong Lu, Jibin Zhou, Xiangang Ma, Mao Ye. Deep learning approach for morphology classification and particle sizing of industrial methanol-to-olefins (MTO) catalyst[J]. 中国化学工程学报, 2025, 84(8): 1-10.
[5]	Tiantong Zhang, Haolin Cheng, Yao Nian, Jinli Zhang, Qingbiao Li, You Han. Application of generative artificial intelligence in catalysis[J]. 中国化学工程学报, 2025, 84(8): 86-95.
[6]	Zhi Ma, Peng Cui, Xu Wang, Lanyu Li, Haoxiang Xu, Adrian Fisher, Daojian Cheng. The integration of artificial intelligence and high-throughput experiments: An innovative driving force in catalyst design[J]. 中国化学工程学报, 2025, 84(8): 117-132.
[7]	Mika Sillanpää, Mohammad Reza kimiaei, Soheil Balsini Gavanaroudi, Nezamaddin Mengelizadeh, Najmeh Ahmadi, Davoud Balarak. Synthesis of magnetically separable and recyclable MnFe₂O₄@SiO₂@NH₂ nanocomposite coupled-acylated MWCNTS with enhanced photocatalytic performance under visible-light irradiation[J]. 中国化学工程学报, 2025, 83(7): 229-243.
[8]	Mingqiang Chen, Tingting Zhu, Yishuang Wang, Defang Liang, Chang Li, Haosheng Xin, Jun Wang. Catalytic oxidation of methane for methanol production over copper sepiolite: Effect of noble metals[J]. 中国化学工程学报, 2025, 82(6): 1-14.
[9]	Bo Pan, Muneeb Ul Hassan Naseer, Hao Du, Shaona Wang, Yeqing Lyu, Biao Liu, Haixu Wang, Lanjie Li. Separation and recovery of V/W/Na from waste SCR catalyst leaching solution using membrane electrolysis—Ion morphology pretreatment solvent extraction-stripping method[J]. 中国化学工程学报, 2025, 82(6): 153-164.
[10]	Baowei Wang, Jiangzhou Kong, Xiaoyan Li. Preparation of MoO₃/γ-Al₂O₃ sulfur-resistant methanation catalyst with segmented plasma fluidized bed[J]. 中国化学工程学报, 2025, 81(5): 142-150.
[11]	Mengting Chen, Minjie Zhu, Tingyu Zhou, Qifeng Zhong, Meihua Zhang, Yingxin Liu, Zuojun Wei. Enhanced activity and stability of SAPO-5 zeolite supported RuMn catalyst for aqueous-phase selective hydrodeoxygenation of guaiacol to cyclohexanol[J]. 中国化学工程学报, 2025, 81(5): 200-207.
[12]	Zhenhui Lv, Jianan Li, Tao Yang, Yibao Li, Chong Peng. Effect of carbon modifications on the performance of hydrogenation catalysts[J]. 中国化学工程学报, 2025, 81(5): 270-276.
[13]	Yaqi Qu, Hualiang An, Xinqiang Zhao, Yanji Wang. Heterogeneously catalyzed self-condensation of n-butanal[J]. 中国化学工程学报, 2025, 80(4): 89-99.
[14]	Xiangli Liu, Yiqing Zeng, Jiahao Chen, Zhaoxiang Zhong, Weihong Xing. Research progress on the monolithic catalyst for hydrogenation of CO₂ to methane[J]. 中国化学工程学报, 2025, 80(4): 184-197.
[15]	Jiayi Xu, Shuang Li, Wei Zhang, Guangli Xiu. Fe, N-decorated carbocatalyst based on Fe-MOF as PDS activator for efficient sulfadiazine degradation: An electron transfer process[J]. 中国化学工程学报, 2025, 80(4): 248-260.