SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2010, Vol. 18 ›› Issue (4): 569-576.

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Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane

张景亚1,2, 张延武1, 张浩勤1, 党敬川1, 刘金盾1   

  1. 1. School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China;
    2. School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450008, China
  • 收稿日期:2009-03-26 修回日期:2010-06-22 出版日期:2010-08-28 发布日期:2010-08-28
  • 通讯作者: LIU Jindun, E-mail:liujindun@zzu.edu.cn
  • 基金资助:
    Supported by the National High Technology Research and Development Program of China(2008AA06Z330),the National Natural Science Foundation of China(20676125),and the Technician Service Enterprise Action Program(2009GJD00048).

Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane

ZHANG Jingya1,2, ZHANG Yanwu1, ZHANG Haoqin1, DANG Jingchuan1, LIU Jindun1   

  1. 1. School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China;
    2. School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450008, China
  • Received:2009-03-26 Revised:2010-06-22 Online:2010-08-28 Published:2010-08-28

摘要: A novel composite charged mosaic membrane (CCMM) was prepared via interfacial polymerization (IP) of polyamine[poly (epichlorohydrin amine) ]and trimesoyl chloride (TMC) on the polyethersulfone (PES) support. Fourier transform infrared spectroscopy (FT-IR),environmental scanning electron microscopy (ESEM),atomic force microscopy (AFM) and water contact angle analysis were applied to characterize the resulted CCMM.The FT-IR spectrum indicates that TMC reacts sufficiently with polyamine.ESEM and AFM pictures show that the IP process produces a dense selective layer on the support membrane.The water contact angle of the CCMM is smaller than that of the substrate membrane because of the cross-linked hydrophilic polyamine network.Several factors affecting the IP reaction and the performance of the CCMM,such as monomer concentration,reaction time,pH value of aqueous phase solution and post-treatment,were studied.The pure water flux of the optimized CCMM is 14.73 L·m -2 ·h -1 ·MPa -1 at the operating pressure of 0.4 MPa.The values of separation factorαfor NaCl/PEG1000/water and MgCl2/PEG1000/water are 11.89 and 9.96,respectively.These results demonstrate that CCMM is promising for the separation of low-molecular-weight organics from their salt aqueous solutions.

关键词: charged mosaic membranes, interfacial polymerization, polyamine, flux, retention

Abstract: A novel composite charged mosaic membrane (CCMM) was prepared via interfacial polymerization (IP) of polyamine[poly (epichlorohydrin amine) ]and trimesoyl chloride (TMC) on the polyethersulfone (PES) support. Fourier transform infrared spectroscopy (FT-IR),environmental scanning electron microscopy (ESEM),atomic force microscopy (AFM) and water contact angle analysis were applied to characterize the resulted CCMM.The FT-IR spectrum indicates that TMC reacts sufficiently with polyamine.ESEM and AFM pictures show that the IP process produces a dense selective layer on the support membrane.The water contact angle of the CCMM is smaller than that of the substrate membrane because of the cross-linked hydrophilic polyamine network.Several factors affecting the IP reaction and the performance of the CCMM,such as monomer concentration,reaction time,pH value of aqueous phase solution and post-treatment,were studied.The pure water flux of the optimized CCMM is 14.73 L·m -2 ·h -1 ·MPa -1 at the operating pressure of 0.4 MPa.The values of separation factorαfor NaCl/PEG1000/water and MgCl2/PEG1000/water are 11.89 and 9.96,respectively.These results demonstrate that CCMM is promising for the separation of low-molecular-weight organics from their salt aqueous solutions.

Key words: charged mosaic membranes, interfacial polymerization, polyamine, flux, retention