Abstract: The synthesis of polyoxymethylene dimethyl ethers as an ideal diesel fuel additive is the current hot topic of modern petrochemical industry for their expedient properties in mitigating air pollutants emission during combustion. In this work, a series of spherical sulfated zirconia catalysts were prepared by a one-pot hydrothermal method assisted with surfactant cetyltrimethylammonium bromide (CTAB). The prepared sulfated zirconia catalysts were used to catalyze PODE_n synthesis from methanol and formaldehyde solution. Various characterization (XRD, BET, SEM, TGA, NH₃-TPD, FTIR, and Py-IR) were employed to elaborate the structure–activity relationship of the studied catalytic system. The results demonstrated that S/Zr molar ratio in precursor solution played an effective role on catalyst morphology and acidic properties, where the weak Brønsted acid sites and strong Lewis acid sites were favorable to the conversion of methanol and formation of long-chain PODE_n, respectively. The reaction parameters such as catalyst amount, molar ratio of FA/MeOH, reaction time, temperature and pressure were optimized. The speculated reaction pathway for PODE_n synthesis was proposed based on the synergy of Brønsted and Lewis acid sites, which suggested that Brønsted and Lewis acid sites might be advantageous to the activation of polyoxymethylene hemiformals [CH₃(OCH₂)_nOH] and methylene glycol (HOCH₂OH), respectively.

Key words: Polyoxymethylene dimethyl ethers, Spherical sulfated zirconia, Methanol, Formaldehyde, Reaction pathway, Synergistic effect

摘要： The synthesis of polyoxymethylene dimethyl ethers as an ideal diesel fuel additive is the current hot topic of modern petrochemical industry for their expedient properties in mitigating air pollutants emission during combustion. In this work, a series of spherical sulfated zirconia catalysts were prepared by a one-pot hydrothermal method assisted with surfactant cetyltrimethylammonium bromide (CTAB). The prepared sulfated zirconia catalysts were used to catalyze PODE_n synthesis from methanol and formaldehyde solution. Various characterization (XRD, BET, SEM, TGA, NH₃-TPD, FTIR, and Py-IR) were employed to elaborate the structure–activity relationship of the studied catalytic system. The results demonstrated that S/Zr molar ratio in precursor solution played an effective role on catalyst morphology and acidic properties, where the weak Brønsted acid sites and strong Lewis acid sites were favorable to the conversion of methanol and formation of long-chain PODE_n, respectively. The reaction parameters such as catalyst amount, molar ratio of FA/MeOH, reaction time, temperature and pressure were optimized. The speculated reaction pathway for PODE_n synthesis was proposed based on the synergy of Brønsted and Lewis acid sites, which suggested that Brønsted and Lewis acid sites might be advantageous to the activation of polyoxymethylene hemiformals [CH₃(OCH₂)_nOH] and methylene glycol (HOCH₂OH), respectively.

关键词: Polyoxymethylene dimethyl ethers, Spherical sulfated zirconia, Methanol, Formaldehyde, Reaction pathway, Synergistic effect