SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (4): 348-356.DOI: 10.1016/S1004-9541(13)60478-4

• 分离科学与工程 • 上一篇    下一篇

Ceramic Supported PDMS and PEGDA Composite Membranes for CO2 Separation

刘赛男, 刘公平, 卫旺, 相里粉娟, 金万勤   

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
  • 收稿日期:2011-12-02 修回日期:2012-11-04 出版日期:2013-04-28 发布日期:2013-04-26
  • 通讯作者: JIN Wanqin
  • 基金资助:

    Supported by the National Basic Research Program of China (2009CB623406), the National Natural Science Foundation of China (20990222) and the Natural Science Foundation of Jiangsu Province (BK2009021, SBK200930313).

Ceramic Supported PDMS and PEGDA Composite Membranes for CO2 Separation

LIU Sainan, LIU Gongping, WEI Wang, XIANGLI Fenjuan, JIN Wanqin   

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
  • Received:2011-12-02 Revised:2012-11-04 Online:2013-04-28 Published:2013-04-26
  • Supported by:

    Supported by the National Basic Research Program of China (2009CB623406), the National Natural Science Foundation of China (20990222) and the Natural Science Foundation of Jiangsu Province (BK2009021, SBK200930313).

摘要: Composite membranes have attracted increasing attentions owing to their potential applications for CO2 separation. In this work, ceramic supported polydimethylsiloxane (PDMS) and poly (ethylene glycol) diacrylate (PEGDA) composite membranes were prepared. The microstructure and physicochemical properties of the composite membranes were characterized. Preparation conditions were systematically optimized. The gas separation performance of the as-prepared membranes was studied by pure gas and binary gas permeation measurement of CO2, N2 and H2. Experiments showed that PDMS, as silicone rubber, exhibited larger permeance and lower separation factors. Conversely, PEGDA composite membrane presented smaller gas permeance but higher ideal selectivity for CO2/N2. Compared to the performance of those membranes using polymeric supports or freestanding membranes, the two kinds of ceramic supported composite membranes exhibited higher gas permeance and acceptable selectivity. Therefore, the ceramic supported composite membrane can be expected as a candidate for CO2 separation from light gases.

关键词: polydimethylsiloxane, PEGDA, ceramic support, composite membrane, CO2 separation

Abstract: Composite membranes have attracted increasing attentions owing to their potential applications for CO2 separation. In this work, ceramic supported polydimethylsiloxane (PDMS) and poly (ethylene glycol) diacrylate (PEGDA) composite membranes were prepared. The microstructure and physicochemical properties of the composite membranes were characterized. Preparation conditions were systematically optimized. The gas separation performance of the as-prepared membranes was studied by pure gas and binary gas permeation measurement of CO2, N2 and H2. Experiments showed that PDMS, as silicone rubber, exhibited larger permeance and lower separation factors. Conversely, PEGDA composite membrane presented smaller gas permeance but higher ideal selectivity for CO2/N2. Compared to the performance of those membranes using polymeric supports or freestanding membranes, the two kinds of ceramic supported composite membranes exhibited higher gas permeance and acceptable selectivity. Therefore, the ceramic supported composite membrane can be expected as a candidate for CO2 separation from light gases.

Key words: polydimethylsiloxane, PEGDA, ceramic support, composite membrane, CO2 separation