A Novel Membrane Prepared from Sodium Alginate Cross-linked with Sodium Tartrate for CO2 Capture

doi:10.1016/S1004-9541(13)60574-1

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (10): 1098-1105.DOI: 10.1016/S1004-9541(13)60574-1

A Novel Membrane Prepared from Sodium Alginate Cross-linked with Sodium Tartrate for CO₂ Capture

朱娅群^1,2,3, 王志^1,2,3, 张晨昕^1,2,3, 王纪孝^1,2,3, 王世昌^1,3

1 Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2 State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300072, China;
3 Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin University, Tianjin 300072, China

收稿日期:2012-05-29 修回日期:2013-02-01 出版日期:2013-10-28 发布日期:2013-10-29
通讯作者: WANG Zhi
基金资助:
Supported by the National Natural Science Foundation of China (20836006), the National Basic Research Program (2009CB623405), the Science & Technology Pillar Program of Tianjin (10ZCKFSH01700), the Programme of Introducing Talents of Discipline to Universities (B06006) and the Cheung Kong Scholar Program for Innovative Teams of the Ministry of Education (IRT0641).

A Novel Membrane Prepared from Sodium Alginate Cross-linked with Sodium Tartrate for CO₂ Capture

ZHU Yaqun^1,2,3, WANG Zhi^1,2,3, ZHANG Chenxin^1,2,3, WANG Jixiao^1,2,3, WANG Shichang^1,3

1 Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2 State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300072, China;
3 Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin University, Tianjin 300072, China

Received:2012-05-29 Revised:2013-02-01 Online:2013-10-28 Published:2013-10-29
Contact: WANG Zhi
Supported by:
Supported by the National Natural Science Foundation of China (20836006), the National Basic Research Program (2009CB623405), the Science & Technology Pillar Program of Tianjin (10ZCKFSH01700), the Programme of Introducing Talents of Discipline to Universities (B06006) and the Cheung Kong Scholar Program for Innovative Teams of the Ministry of Education (IRT0641).

摘要/Abstract

摘要： The membrane-based CO₂ separation process has an advantage compared to traditional CO₂ separation technologies. The membrane is the key of the membrane separation process. In this paper, preparation, characterization and laboratory testing of the membrane, which was prepared from sodium alginate, hydrogen bond cross-linked with sodium tartrate and used for CO₂/N₂ separation, were reported. The resistance to SO₂ of the membrane was also investigated. The experimental results demonstrate that the membrane possesses a high resistance to SO₂. Finally, based on experimental results, the economic feasibility of the membrane used for CO₂/N₂ separation was evaluated, indicating the two-stage membrane process can compete with the traditional chemical absorption method.

关键词: carboxyl group, CO₂ separation, composite membrane, fixed carrier, sodium alginate

Abstract: The membrane-based CO₂ separation process has an advantage compared to traditional CO₂ separation technologies. The membrane is the key of the membrane separation process. In this paper, preparation, characterization and laboratory testing of the membrane, which was prepared from sodium alginate, hydrogen bond cross-linked with sodium tartrate and used for CO₂/N₂ separation, were reported. The resistance to SO₂ of the membrane was also investigated. The experimental results demonstrate that the membrane possesses a high resistance to SO₂. Finally, based on experimental results, the economic feasibility of the membrane used for CO₂/N₂ separation was evaluated, indicating the two-stage membrane process can compete with the traditional chemical absorption method.

Key words: carboxyl group, CO₂ separation, composite membrane, fixed carrier, sodium alginate

朱娅群, 王志, 张晨昕, 王纪孝, 王世昌. A Novel Membrane Prepared from Sodium Alginate Cross-linked with Sodium Tartrate for CO₂ Capture[J]. Chinese Journal of Chemical Engineering, 2013, 21(10): 1098-1105.

ZHU Yaqun, WANG Zhi, ZHANG Chenxin, WANG Jixiao, WANG Shichang. A Novel Membrane Prepared from Sodium Alginate Cross-linked with Sodium Tartrate for CO₂ Capture[J]. Chin.J.Chem.Eng., 2013, 21(10): 1098-1105.

参考文献

1 Hussain, A., Hägg, M.B., “A feasibility study of CO₂ capture from flue gas by a facilitated transport membrane”, J. Membr. Sci., 359 (1-2), 140-148 (2010).
2 Zhang, Y., Wang, Z., Wang, S.C., “Synthesis and characteristics of novel fixed carrier membrane for CO₂ separation”, Chem. Lett., 31 (4), 430-431 (2002).
3 Ho, M.T., Allinson, G.W., Wiley, D.E., “Reducing the cost of CO₂ capture from flue gases using membrane technology”, Ind. Eng. Chem. Res., 47 (5), 1562-1568 (2008).
4 Peters, L., Hussain, A., Follmann, M., Melin, T., Hägg, M.B., “CO₂ removal from natural gas by employing amine absorption and membrane technology—A technical and economical analysis”, Chem. Eng. J., 172 (2-3), 952-960 (2011).
5 Nunes, S.P., Peinemann, K.V., Membrane Technology in the Chemical Industry, Wiley-VCH Verlag GmbH, Weinheim (2001).
6 Wang, M.M., Wang, Z., Wang, J.X., Zhu, Y.Q., Wang, S.C., “An antioxidative composite membrane with the carboxylate group as a fixed carrier for CO₂ separation from flue gas”, Energy Environ. Sci., 4, 3955-3959 (2011).
7 Lee, H., Cho, M.H., Lee, B.S., Palgunadi, J., Kim, H., Kim, H.S., “Alkyl-fluoroalkylimidazolium-based ionic liquids as efficient CO₂ absorbents”, Energy Fuels, 24 (2), 6689-6692 (2010).
8 Isiklan, N., Kursun, F., Inal, M., “Graft copolymerization of itaconic acid onto sodium alginate using benzoyl peroxide”, Carbohydr. Polym., 79 (3), 665-672 (2010).
9 Kariduraganavar, M.Y., Kittur, A.A., Kulkarni, S.S., Ramesh, K., “Development of novel pervaporation membranes for the separation of water-isopropanol mixtures using sodium alginate and NaY zeolite”, J. Membr. Sci., 238 (1-2), 165-175 (2004).
10 El-Azzami, L.A., Grulke, E.A., “Carbon dioxide separation from hydrogen and nitrogen: Facilitated transport in arginine salt-chitosan membranes”, J. Membr. Sci., 328 (1-2), 15-22 (2009).
11 Yave, W., Car, A., Funari, S.S., Nunes, S.P., Peinemann, K.V., “CO₂-philic polymer membrane with extremely high separation performance”, Macromolecules, 43 (1), 326-333 (2010).
12 Haidara, H., Vonna, L., Vidal, L., “Unrevealed self-assembly and crystallization structures of Na-alginate, induced by the drying dynamics of wetting films of the aqueous polymer solution”, Macromolecules, 43 (5), 2421-2429 (2010).
13 Kanehashi, S., Kusakabe, A., Sato, S., Nagai, K., “Analysis of permeability, solubility and diffusivity of carbon dioxide, oxygen and nitrogen in crystalline and liquid crystalline polymers”, J. Membr. Sci., 365 (1-2), 40-51 (2010).
14 Mulder, M., Basic Principles of Membrane Technology, 2nd edition, Kluwer Academic Publishers, Dordrecht (1999).
15 Khonakdar, H.A., Morshedian, J., Wagenknecht, U., Jafari, S.H., “An investigation of chemical crosslinking effect on properties of high-density polyethylene”, Polymer, 44 (5), 4301-4309 (2003).
16 Yuan, S.J., Wang, Z., Qiao, Z.H., Wang, M.M., Wang, J.X., Wang, S.C., “Improvement of CO₂/N₂ separation characterisitics of polyvinylamine by modifying with ethylenediamine”, J. Membr. Sci., 378 (1-2), 425-437 (2011).
17 Yu, X.W., Wang, Z., Wei, Z.H., Yuan, S.J., Zhao, J., Wang, J.X., Wang, S.C., “Novel tertiary amino containing thin film composite membranes prepared by interfacial polymerization for CO₂ capture”, J. Membr. Sci., 362 (1-2), 265-278 (2010).
18 Bellamy, L.J., The Infrared Spectra of Complex Molecules, 2nd edition, Chapman Hall, London and New York (1980).
19 Socrates, G., Infrared and Raman Characteristic Group Frequencies: Tables and Charts, 3rd edition, John Wiley & Sons Ltd., Chichester (2001).
20 Zhai, H., Zhang, A.Q., Li, L., Long, S., “Partial hydrogenation of benzene catalyzed by Pt/N-n-propyl chitosan hybrid membrane”, J. Appl. Polym. Sci., 123 (4), 2140-2146 (2012).
21 Bhadra, S., Kim, N.H., Rhee, K.Y., Lee, J.H., “Preparation of nanosize polyaniline by solid-state polymerization and determination of crystal structure”, Polym. Int., 58 (10), 1173-1180 (2009).
22 Qiao, Z.H., Wang, Z., Zhang, C.X., Yuan, S.J., Wang, J.X., Wang, S.C., “PVAm-PIP/PS composite membrane with high performance for CO₂/N₂ separation”, AIChE J., 59 (1), 215-228 (2012).
23 Yi, C.H., Wang, Z., Li, M., Wang, J.X., Wang, S.C., “Facilitated transport of CO₂ through polyvinylamine/polyethylene glycol blend membranes”, Desalination, 193 (1-3), 90-96 (2006).
24 Francisco, G.J., Chakma, A., Feng, X., “Membranes comprising of alkanolamines incorporated into poly (vinyl alcohol) matrix for CO₂/N₂ separation”, J. Membr. Sci., 303 (1-2), 54-63 (2007).
25 Yang, D.X., Wang, Z., Wang, J.X., Wang, S.C., “Potential of two-stage membrane system with recycle stream for CO₂ capture from postcombustion gas”, Energy Fuels, 23 (10), 4755-4762 (2009).
26 Liu, L., Chakma, A., Feng, X.S., “CO₂/N₂ separation by poly (ether block amide) thin film hollow fiber composite membranes”, Ind. Eng. Chem. Res., 44 (17), 6874-6882 (2005)
27 Liu, L., Chakma, A., Feng, X.S., “Preparation of hollow fiber poly (ether block amide)/polysulfone composite membranes for separation of carbon dioxide from nitrogen”, Chem. Eng. J., 105 (1-2), 43-51 (2004).
28 Peter, J., Peinemann, K.V., “Multilayer composite membranes for gas separation based on crosslinked PTMSP gutter layer and partially crosslinked Matrimid^® 5218 selective layer”, J. Membr. Sci., 340 (1-2), 62-72 (2009).
29 Lavalley, J.C., “Infrared spectrometric studies of the surface basicity of metal oxides and zeolites using adsorbed probe molecules”, Catal. Today, 27 (3-4), 377-401 (1996).
30 Yang, D.X., Wang, Z., Wang, J.X., Wang, S.C., “Parametric study of the membrane process for carbon dioxide removal from natural gas”, Ind. Eng. Chem. Res., 48 (19), 9013-9022 (2009).
31 Zhao, L., Menzer, R., Riensche, E., Blum, L., Stolten, D., “Concepts and investment cost analyses of multi-stage membrane systems used in post-combustion processes”, Energy Procedia, 1 (1), 269-278 (2009).

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A Novel Membrane Prepared from Sodium Alginate Cross-linked with Sodium Tartrate for CO₂ Capture

A Novel Membrane Prepared from Sodium Alginate Cross-linked with Sodium Tartrate for CO₂ Capture

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