SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (12): 1360-1369.DOI: 10.1016/S1004-9541(13)60635-7

• 化工热力学 • 上一篇    下一篇

Correlating and Predicting the Solubilities of Solid n-Alkanes in Supercritical Ethane Using Carnahan-Starling-van der Waals Model

李红茹1, 李淑芬2, 沈炳谦1   

  1. 1 College of Pharmacy, State Key Laboratory of Medicinal Chemical Biology and Tianjin Key Laboratory of Molecular Drug Research, Nankai University, Tianjin 300071, China;
    2 Key Laboratory for Green Chemical Technologies of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • 收稿日期:2012-12-26 修回日期:2013-03-04 出版日期:2013-12-28 发布日期:2013-12-27
  • 通讯作者: LI Hongru
  • 基金资助:

    Supported by the National Natural Science Foundation of China (21206077).

Correlating and Predicting the Solubilities of Solid n-Alkanes in Supercritical Ethane Using Carnahan-Starling-van der Waals Model

LI Hongru1, LI Shufen2, SHEN Bingqian1   

  1. 1 College of Pharmacy, State Key Laboratory of Medicinal Chemical Biology and Tianjin Key Laboratory of Molecular Drug Research, Nankai University, Tianjin 300071, China;
    2 Key Laboratory for Green Chemical Technologies of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • Received:2012-12-26 Revised:2013-03-04 Online:2013-12-28 Published:2013-12-27
  • Supported by:

    Supported by the National Natural Science Foundation of China (21206077).

摘要: The solubilities of some solid n-alkanes in supercritical ethane were correlated and predicted in this paper using the Carnahan-Starling-van der Waals model with a density-dependent parameter of a12. At a given temperature, the linear fit of the parameter of a12 and the density of the supercritical solvent was used for solubility correlation, resulting in an average absolute average relative deviation (AARD) of 8.68%, which was between the values of the semiempirical models and the other compressed gas models used in this article. In the linear fit of the parameter of a12 and the density of the solvent, the regressed slope m and intercept n of the linear fit can be correlated with the carbon atom number of solid n-alkanes and then the solubilities of solid n-alkanes in supercritical ethane can be predicted with the intercept n and slope m. The average AARD in solubility prediction was 26.99%.

关键词: supercritical ethane, solid n-alkanes, Carnahan-Starling-van der Waals model, solubility

Abstract: The solubilities of some solid n-alkanes in supercritical ethane were correlated and predicted in this paper using the Carnahan-Starling-van der Waals model with a density-dependent parameter of a12. At a given temperature, the linear fit of the parameter of a12 and the density of the supercritical solvent was used for solubility correlation, resulting in an average absolute average relative deviation (AARD) of 8.68%, which was between the values of the semiempirical models and the other compressed gas models used in this article. In the linear fit of the parameter of a12 and the density of the solvent, the regressed slope m and intercept n of the linear fit can be correlated with the carbon atom number of solid n-alkanes and then the solubilities of solid n-alkanes in supercritical ethane can be predicted with the intercept n and slope m. The average AARD in solubility prediction was 26.99%.

Key words: supercritical ethane, solid n-alkanes, Carnahan-Starling-van der Waals model, solubility