Experimental and modeling investigation of dynamic interfacial tension of asphaltenic-acidic crude oil/aqueous phase containing different ions

doi:10.1016/j.cjche.2017.02.004

摘要/Abstract

摘要： In this way, after experimentalmeasurement of interfacial tension, different models includingmono-exponential decay, dynamic adsorptionmodels and empirical equation are used to correlate this time-dependent behavior of interfacial tension (IFT). During the modeling approach, the induction, adsorption, equilibrium, and mesoequilibrium times as well as diffusivity of surface active components known as natural surfactant including asphaltene and resin from crude oil to the interface are obtained. In addition, the surface excess concentration of surface active components at the interface and Gibbs adsorption isothermare utilized to analyze the measured dynamic IFTs. Finally, the mechanisms of crude oil/aqueous solution IFT including (a) the activity of surfaceactive components and (b) surface excess concentration of them at fluid/fluid interface are proposed and discussed in details.

关键词: Dynamic IFT, Adsorption, Ion, Crude oil, EOR

Abstract: In this way, after experimentalmeasurement of interfacial tension, different models includingmono-exponential decay, dynamic adsorptionmodels and empirical equation are used to correlate this time-dependent behavior of interfacial tension (IFT). During the modeling approach, the induction, adsorption, equilibrium, and mesoequilibrium times as well as diffusivity of surface active components known as natural surfactant including asphaltene and resin from crude oil to the interface are obtained. In addition, the surface excess concentration of surface active components at the interface and Gibbs adsorption isothermare utilized to analyze the measured dynamic IFTs. Finally, the mechanisms of crude oil/aqueous solution IFT including (a) the activity of surfaceactive components and (b) surface excess concentration of them at fluid/fluid interface are proposed and discussed in details.

Key words: Dynamic IFT, Adsorption, Ion, Crude oil, EOR

Mostafa Lashkarbolooki, Shahab Ayatollahi. Experimental and modeling investigation of dynamic interfacial tension of asphaltenic-acidic crude oil/aqueous phase containing different ions[J]. Chinese Journal of Chemical Engineering, 2017, 25(12): 1820-1830.

参考文献

[1] A. Mirzaei-Paiaman, M. Masihi, Scaling of recovery by cocurrent spontaneous imbibition in fractured petroleum reservoirs, Energy Technol. 2 (2014) 166-175.

[2] A. Zeinolabedini Hezave, S. Dorostkar, S. Ayatollahi,M. Nabipour, B. Hemmateenejad, Investigating the effect of ionic liquid (1-dodecyl-3-methylimidazolium chloride ([C₁₂mim] [Cl])) on the water/oil interfacial tension as a novel surfactant, Colloid Surf. A 421 (2013) 63-71.

[3] K. Babu, N. Pal, V.K. Saxena, A. Mandal, Synthesis and characterization of a new polymeric surfactant for chemical enhanced oil recovery, Korean J. Chem. Eng. 33 (2016) 711-719.

[4] M.S. Benzagouta, I.M. AlNashef, W. Karnanda, K. Al-Khidir, Ionic liquids as novel surfactants for potential use in enhanced oil recovery, Korean J. Chem. Eng. 30 (2013) 2108-2117.

[5] B. Kumar, Effect of Salinity on the Interfacial Tension of Model and Crude Oil Systems, MS Thesis, Calgary, Alberta September 2012.

[6] N. Ikeda, M. Araton, K. Motomura, Thermodynamic study on the adsorption of sodium chloride at the water/hexane interface, J. Colloid Interface Sci. 149 (1992) 208-215.

[7] B. Cai, J. Yang, T. Guo, Interfacial tension of hydrocarbon + water/brine systems under high pressure, J. Chem. Eng. Data 41 (1996) 493-496.

[8] A. Badakshan, P. Bakes, The influence of temperature and surfactant concentration on interfacial tension of saline water and hydrocarbon system in relation to enhanced oil recovery by chemical flooding, SPE Paper Number 20290, 1990.

[9] E. Isaacs, K. Smolek, Interfacial tension behavior of athabasca bitumen/aqueous surfactant systems, Can. J. Chem. Eng. 61 (1983) 233-240.

[10] F. Moeini, H. Hemmati-Sarapardeh, M.H. Ghazanfari, M. Masihi, S. Ayatollahi, Toward mechanistic understanding of heavy crude oil/brine interfacial tension: the roles of salinity, temperature and pressure, Fluid Phase Equilib. 375 (2014) 191-200.

[11] W. Xu, Experimental Investigation of Dynamic Interfacial Interactions at Reservoir Conditions, MSc. Thesis, Louisiana State University, Louisiana, 2005.

[12] A.A. Yousef, S. Al-Saleh, M. Al-Jawfi, S. Aramco, Improved/enhanced oil recovery from carbonate reservoirs by tuning injection water salinity and ionic content, Soc. Pet. Eng. (2012) (SPE-154076-MS).

[13] C. Vijapurapu, D. Rao, Compositional effects of fluid on spreading, adhesion and wettability in porous media, Colloids Surf. A Physicochem. Eng. Asp. 241 (2004) 335-342.

[14] M. Lashkarbolooki, S. Ayatollahi,M. Riazi, The impacts of aqueous ions on interfacial tension and wettability of an asphaltenic-acidic crude oil reservoir during smart water injection, J. Chem. Eng. Data 59 (2014) 3624-3634.

[15] M. Lashkarbolooki, S. Ayatollahi, M. Riazi, Effect of salinity, resin, and asphaltene on the surface properties of acidic crude oil/smart water/rock system, Energy Fuel 28 (2014) 6820-6829.

[16] M. Lashkarbolooki,M. Riazi, S. Ayatollahi, A. Zeinolabedini Hezave, Synergy effects of ions, resin, and asphaltene on interfacial tension of acidic crude oil and low-high salinity brines, Fuel 165 (2016) 75-85.

[17] A.F.H. Ward, L. Tordai, Time-dependence of boundary tensions of solutions. I. The role of diffusion in time-effects, J. Chem. Phys. 14 (1946) 453-461.

[18] M. Lashkarbolooki,M. Riazi, S. Ayatollahi, Investigation of effects of salinity, temperature, pressure, and crude oil type on the dynamic interfacial tensions, Chem. Eng. Res. Des. 115 (2016) 53-65.

[19] M. Lashkarbolooki, S. Ayatollahi, M. Riazi, Mechanistic study on the dynamic interfacial tension of crude oil+water systems: experimental and modeling approaches, J. Ind. Eng. Chem. 35 (2016) 408-416.

[20] M.V. Kok, K.G. Gul, Thermal characteristics and kinetics of crude oils and SARA fractions, Thermochim. Acta 569 (2013) 66-70.

[21] P. Delahay, I. Trachtenberg, Adsorption kinetics and electrode processes, J. Chem. Soc. 79 (1957) 2355-2362.

[22] S. Zarkar, V. Pauchard, U. Farooq, A. Couzis, S. Banerjee, Interfacial properties of asphaltenes at toluene-water interfaces, Langmuir 31 (2015) 4878-4886.

[23] P. Joos, J.P. Fang, G. Serrien, Comments on some dynamic surface tension measurements by the dynamic bubble pressure method, J. Colloid Interface Sci. 151 (1992) 144-149.

[24] M. Jeribi, B. Almir-Assad, D. Langevin, I. Hénaut, J.F. Argillier, Adsorption kinetics of asphaltenes at liquid interfaces, J. Colloid Interface Sci. 256 (2002) 268-272.

[25] X.Y. Hua, M.J. Rosen, Dynamic surface tension of aqueous surfactant solutions 3. Some effects of molecular structure and environment, J. Colloid Interface Sci. 141 (1991) 180-190.

[26] X.Y. Hua, M.J. Rosen, Dynamic surface tension of aqueous surfactant solutions: 1. Basic parameters, J. Colloid Interface Sci. 124 (1998) 652-659.

[27] H. Butt, K. Graf, M. Kappl, Physics and Chemistry of Interfaces, Wiley-VCH, Weinheim, 2006.

[28] J. Drelich, C. Fang, C.L. White, Measurement of interfacial tension in fluid-fluid systems, Encycl. Surf. Colloid Sci. (2002) 3152-3166.

[29] A. Boonma, P. Gieles, C.H. Massen, J. Egberts, Dynamic surface tension measurements on surface active materials, Thermochim. Acta 103 (1986) 107-112.

[30] A.I. Rusanov, V.A. Prokhorov, Interfacial Tensiometry, Elsevier, Amsterdam, 1996.

[31] S.Y. Lin, K. Mckeigue, C. Maldarelli, The gas-oil interfacial behavior during gas injection into an asphaltenic oil reservoir, AIChE J. 36 (1990) 1785-1795.

[32] Z. Yang, M. Li, B. Peng, M. Lin, Z. Dong, Y. Ling, Interfacial tension of CO₂ and organic liquid under high pressure and temperature, Chin. J. Chem. Eng. 22 (2014) 1302-1306.

[33] A. Zolghadr, M. Escrochi, S. Ayatollahi, Temperature and composition effect on CO₂ miscibility by interfacial tension measurement, J. Chem. Eng. Data 58 (2013) 1168-1175.

[34] M. Lashkarbolooki, S. Ayatollahi, Effect of asphaltene and resin on interfacial tension of acidic crude oil/sulfate aqueous solution: experimental study, Fluid Phase Equilib. 414 (2016) 149-155.

[35] Y. Rotenberg, L. Boruvka, A.W. Neumann, Determination of surface tension and contact angle from the shapes of axisymmetric fluid interfaces, J. Colloid Interface Sci. 93 (1983) 169-183.

[36] Standard test method for acid number of petroleum products by potentiometric titration, An American National Standard, British Standard 4457, Designation 177/96, ASTM International,West Conshohocken, PA, 2004.

[37] C. Xinheng, T. Songbai, Review and comprehensive analysis of composition and origin of high acidity crude oils, China Pet. Process. Petrochem. Technol. 13 (2011) 6-15.

[38] C.M. Phan, A.V. Nguyen, G.M. Evans, Dynamic adsorption of sodiumdodecylbenzene sulphonate and Dowfroth 250 onto the air-water interface, Min. Eng. 18 (2005) 599-603.

[39] A.V.Nguyen, C.M. Phan, G.M. Evans, Effect of the bubble size on the dynamic adsorption of frothers and collectors in flotation, Int. J. Miner. Process. 79 (2006) 18-26.

[40] D. Pradilla, S. Simon, J. Sjöblom, Mixed interfaces of asphaltenes and model demulsifiers part I: adsorption and desorption of single components, Colloids Surf. A Physicochem. Eng. Asp. 466 (2015) 45-56.

[41] J.P. Rane, S. Zarkar, V. Pauchard, O.C. Mullins, D. Christie, A.B. Andrews, A.E. Pomerantz, S. Banerjee, Applicability of the Langmuir equation of state for asphaltene adsorption at the oil-water interface: coal-derived, petroleum, and synthetic asphaltenes, Energy Fuel 29 (2015) 3584-3590.

[42] J.P. Rane, V. Pauchard, A. Couzis, S. Banerjee, Interfacial rheology of asphaltenes at oil-water interfaces and interpretation of the equation of state, Langmuir 29 (2013) 4750-4759.

[43] P.C. Hiemenz, R. Rajagopalan, Principles of Colloid and Surface Chemistry, Revised and Expanded, vol. 14, CRC press, USA, 1997.

[44] E.Guggenheim, N. Adam,The thermodynamics of adsorption at the surface of solutions, Proc. R. Soc. London Ser. A 139 (1933) 218-236.

[45] A. Adamson, A. Gast, Physical Chemistry of Surfaces, sixth ed. Wiley-Interscience, New York, 1997.

[46] J. Kotz, P. Treichel, J. Townsend, Chemistry and Chemical Reactivity, seventh ed. Stamford, CT, Cengage Learning, 2009.

[47] X. Hu, Y. Li, H. Sun, X. Song, Q. Li, X. Cao, X. Li, Effect of divalent cationic ions on the adsorption behavior of zwitterionic surfactant at silica/solution interface, J. Phys. Chem. B 114 (2010) 8910-8916.