The removal of Cr(VI) through polymeric supported liquid membrane by using calix[4]arene as a carrier

doi:10.1016/j.cjche.2018.01.029

Chinese Journal of Chemical Engineering ›› 2019, Vol. 27 ›› Issue (1): 85-91.DOI: 10.1016/j.cjche.2018.01.029

• Separation Science and Engineering • 上一篇下一篇

The removal of Cr(VI) through polymeric supported liquid membrane by using calix[4]arene as a carrier

Canan Onac, Ahmet Kaya, Duygu Ataman, Nefise Ayhan Gunduz, H. Korkmaz Alpoguz

Department of Chemistry, Pamukkale University, 20070 Campus, Denizli, Turkey

收稿日期:2017-11-29 修回日期:2018-01-11 出版日期:2019-01-28 发布日期:2019-01-31
通讯作者: H. Korkmaz Alpoguz

The removal of Cr(VI) through polymeric supported liquid membrane by using calix[4]arene as a carrier

Canan Onac, Ahmet Kaya, Duygu Ataman, Nefise Ayhan Gunduz, H. Korkmaz Alpoguz

Department of Chemistry, Pamukkale University, 20070 Campus, Denizli, Turkey

Received:2017-11-29 Revised:2018-01-11 Online:2019-01-28 Published:2019-01-31
Contact: H. Korkmaz Alpoguz

摘要/Abstract

摘要： In this work, the transport and removal of Cr(VI) were achieved through supported liquid membrane (SLM) by using a 5,17, di-tert-butyl-11,23-bis[(1,4-dioxa-8-azaspiro[4,5]decanyl)methyl]-25,26,27,28-tetrahydroxy calix[4]arene carrier, dissolved in 2-nitrophenyl octyl ether dichloromethane. The studied parameters are the solvent effect in the membrane phase, the effect of carrier concentration, and the acid type in the donor phase. The Celgard 2500 was used as a membrane support. We used the Danesi mass transfer model to calculate the permeability coefficients for each studied parameter. In addition, AFM and SEM techniques were used to characterize the surface morphology of the prepared Celgard 2500 membrane that included the calix[4]arene carrier.

关键词: Resorcinarene, Liquid membrane, Cr(VI), Surface characterization

Abstract: In this work, the transport and removal of Cr(VI) were achieved through supported liquid membrane (SLM) by using a 5,17, di-tert-butyl-11,23-bis[(1,4-dioxa-8-azaspiro[4,5]decanyl)methyl]-25,26,27,28-tetrahydroxy calix[4]arene carrier, dissolved in 2-nitrophenyl octyl ether dichloromethane. The studied parameters are the solvent effect in the membrane phase, the effect of carrier concentration, and the acid type in the donor phase. The Celgard 2500 was used as a membrane support. We used the Danesi mass transfer model to calculate the permeability coefficients for each studied parameter. In addition, AFM and SEM techniques were used to characterize the surface morphology of the prepared Celgard 2500 membrane that included the calix[4]arene carrier.

Key words: Resorcinarene, Liquid membrane, Cr(VI), Surface characterization

Canan Onac, Ahmet Kaya, Duygu Ataman, Nefise Ayhan Gunduz, H. Korkmaz Alpoguz. The removal of Cr(VI) through polymeric supported liquid membrane by using calix[4]arene as a carrier[J]. Chinese Journal of Chemical Engineering, 2019, 27(1): 85-91.

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The removal of Cr(VI) through polymeric supported liquid membrane by using calix[4]arene as a carrier

The removal of Cr(VI) through polymeric supported liquid membrane by using calix[4]arene as a carrier

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