SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2019, Vol. 27 ›› Issue (2): 467-475.DOI: 10.1016/j.cjche.2018.06.021

• Materials and Product Engineering • 上一篇    下一篇

TIPS behavior for IPP/nano-SiO2 blend membrane formation and its contribution to membrane morphology and performance

Zhensheng Yang1, Zheng Sun1, Dongsheng Cui1, Pingli Li2, Zhiying Wang1   

  1. 1 School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China;
    2 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • 收稿日期:2018-01-30 修回日期:2018-06-12 出版日期:2019-02-28 发布日期:2019-03-18
  • 通讯作者: Zhensheng Yang
  • 基金资助:

    Supported by the Key Project of Scientific and Technological Research of Hebei Provincial University (ZD2015107)

TIPS behavior for IPP/nano-SiO2 blend membrane formation and its contribution to membrane morphology and performance

Zhensheng Yang1, Zheng Sun1, Dongsheng Cui1, Pingli Li2, Zhiying Wang1   

  1. 1 School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China;
    2 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • Received:2018-01-30 Revised:2018-06-12 Online:2019-02-28 Published:2019-03-18
  • Contact: Zhensheng Yang
  • Supported by:

    Supported by the Key Project of Scientific and Technological Research of Hebei Provincial University (ZD2015107)

摘要: In the present work, the TIPS behavior of isotactic polypropylene (iPP)/di-n-butyl phthalate (DBP)/dioctyl phthalate (DOP)/nano-SiO2 system and the competition relation between liquid-liquid phase separation and polymer crystallization are successfully adjusted by adding nano-SiO2. The liquid-liquid phase separation temperature of the system increases with increasing nano-SiO2 content. Besides, iPP crystallization temperature is also changed after adding nano-SiO2. IPP/nano-SiO2 blend hollow fiber microporous membrane is prepared via TIPS method. SEM photos show that the membrane exhibits mixed morphology combining cellular structure relating to liquid-liquid phase separation and branch structure originating from polymer crystallization. The relative weight of cellular structure first decreases and then increases with the increase of nano-SiO2 content. Furthermore, porosity, connectivity among pores and pure water flux of the membrane first increase and then decrease with increasing nano-SiO2 content. However, mechanical performance of the membrane is improved at all times with increasing nano-SiO2 content.

关键词: Isotactic polypropylene, Nanoparticles, Blend, Membrane, Thermally induced phase separation

Abstract: In the present work, the TIPS behavior of isotactic polypropylene (iPP)/di-n-butyl phthalate (DBP)/dioctyl phthalate (DOP)/nano-SiO2 system and the competition relation between liquid-liquid phase separation and polymer crystallization are successfully adjusted by adding nano-SiO2. The liquid-liquid phase separation temperature of the system increases with increasing nano-SiO2 content. Besides, iPP crystallization temperature is also changed after adding nano-SiO2. IPP/nano-SiO2 blend hollow fiber microporous membrane is prepared via TIPS method. SEM photos show that the membrane exhibits mixed morphology combining cellular structure relating to liquid-liquid phase separation and branch structure originating from polymer crystallization. The relative weight of cellular structure first decreases and then increases with the increase of nano-SiO2 content. Furthermore, porosity, connectivity among pores and pure water flux of the membrane first increase and then decrease with increasing nano-SiO2 content. However, mechanical performance of the membrane is improved at all times with increasing nano-SiO2 content.

Key words: Isotactic polypropylene, Nanoparticles, Blend, Membrane, Thermally induced phase separation