Selective synthesis of triacetin from glycerol catalyzed by HZSM-5/MCM-41 micro/mesoporous molecular sieve

doi:10.1016/j.cjche.2018.09.013

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (5): 1073-1078.DOI: 10.1016/j.cjche.2018.09.013

Selective synthesis of triacetin from glycerol catalyzed by HZSM-5/MCM-41 micro/mesoporous molecular sieve

Jiangyong Liu¹, Zihao Wang¹, Yunlin Sun¹, Ruiqi Jian², Panming Jian¹, Dan Wang³

1 School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, China;
2 School of Medicine, Stanford University, Stanford, CA 94304, USA;
3 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

收稿日期:2018-05-16 修回日期:2018-09-04 出版日期:2019-05-28 发布日期:2019-06-27
通讯作者: Jiangyong Liu, Dan Wang
基金资助:
Supported by the National Natural Science Foundation of China (21620102007), the Natural Science Foundation for High Education of Jiangsu Province (17KJB530011), the Science and Technology Innovation Foundation of Yangzhou University (2017CXJ015), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Selective synthesis of triacetin from glycerol catalyzed by HZSM-5/MCM-41 micro/mesoporous molecular sieve

Jiangyong Liu¹, Zihao Wang¹, Yunlin Sun¹, Ruiqi Jian², Panming Jian¹, Dan Wang³

1 School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, China;
2 School of Medicine, Stanford University, Stanford, CA 94304, USA;
3 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

Received:2018-05-16 Revised:2018-09-04 Online:2019-05-28 Published:2019-06-27
Contact: Jiangyong Liu, Dan Wang
Supported by:
Supported by the National Natural Science Foundation of China (21620102007), the Natural Science Foundation for High Education of Jiangsu Province (17KJB530011), the Science and Technology Innovation Foundation of Yangzhou University (2017CXJ015), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

摘要/Abstract

摘要： HZSM-5/MCM-41 molecular sieve (H-ZM) catalysts with well-defined micro/mesoporous structures were synthesized and showed high performance for selective synthesis of triacetin via the esterification reaction of glycerol with acetic acid. The conversion of glycerol was demonstrated to be 100% and the triacetin selectivity was over 91%, which can be attributed to the synergistic effect regarding suitable acidic property, excellent diffusion efficiency and good stability derived from the combined advantages of microporous molecular sieve HZSM-5 and mesoporous molecular sieve MCM-41.

关键词: Mesoscale, Porous materials, Molecular sieve, Triacetin, Glycerol esterification

Abstract: HZSM-5/MCM-41 molecular sieve (H-ZM) catalysts with well-defined micro/mesoporous structures were synthesized and showed high performance for selective synthesis of triacetin via the esterification reaction of glycerol with acetic acid. The conversion of glycerol was demonstrated to be 100% and the triacetin selectivity was over 91%, which can be attributed to the synergistic effect regarding suitable acidic property, excellent diffusion efficiency and good stability derived from the combined advantages of microporous molecular sieve HZSM-5 and mesoporous molecular sieve MCM-41.

Key words: Mesoscale, Porous materials, Molecular sieve, Triacetin, Glycerol esterification

Jiangyong Liu, Zihao Wang, Yunlin Sun, Ruiqi Jian, Panming Jian, Dan Wang. Selective synthesis of triacetin from glycerol catalyzed by HZSM-5/MCM-41 micro/mesoporous molecular sieve[J]. 中国化学工程学报, 2019, 27(5): 1073-1078.

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Selective synthesis of triacetin from glycerol catalyzed by HZSM-5/MCM-41 micro/mesoporous molecular sieve

Selective synthesis of triacetin from glycerol catalyzed by HZSM-5/MCM-41 micro/mesoporous molecular sieve

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