SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (2): 593-597.DOI: 10.1016/j.cjche.2019.09.005

• Materials and Product Engineering • 上一篇    下一篇

Reversed ethane/ethylene adsorption in a metal-organic framework via introduction of oxygen

Ling Yang1, Wei Zhou2, Hao Li3, Ali Alsalme4, Litao Jia5, Jiangfeng Yang1, Jinping Li1, Libo Li1,5,6,7, Banglin Chen3   

  1. 1 College of Chemistry and Chemical Engineering, Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Taiyuan University of Technology, Taiyuan 030024, China;
    2 NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899-6102, United States;
    3 Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249-0698, United States;
    4 Chemistry Department, College of Science, King Saud University, P O Box 2455, Riyadh 11451, Saudi Arabia;
    5 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030024, China;
    6 Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China;
    7 Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Taiyuan 030024, China
  • 收稿日期:2019-08-01 修回日期:2019-09-03 出版日期:2020-02-28 发布日期:2020-05-21
  • 通讯作者: Libo Li, Banglin Chen
  • 基金资助:
    We gratefully acknowledge the financial support from the National Natural Science Foundation of China (Nos. 21606163 and 21878205), Coal Bed Methane Joint Foundation of Shanxi (2016012006), Foundation of State Key Laboratory of Coal Conversion (J18-19-610), Welch Foundation (grant AX-1730), and the Distinguished Scientist Fellowship Program (DSFP) at KSU.

Reversed ethane/ethylene adsorption in a metal-organic framework via introduction of oxygen

Ling Yang1, Wei Zhou2, Hao Li3, Ali Alsalme4, Litao Jia5, Jiangfeng Yang1, Jinping Li1, Libo Li1,5,6,7, Banglin Chen3   

  1. 1 College of Chemistry and Chemical Engineering, Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Taiyuan University of Technology, Taiyuan 030024, China;
    2 NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899-6102, United States;
    3 Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249-0698, United States;
    4 Chemistry Department, College of Science, King Saud University, P O Box 2455, Riyadh 11451, Saudi Arabia;
    5 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030024, China;
    6 Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China;
    7 Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Taiyuan 030024, China
  • Received:2019-08-01 Revised:2019-09-03 Online:2020-02-28 Published:2020-05-21
  • Contact: Libo Li, Banglin Chen
  • Supported by:
    We gratefully acknowledge the financial support from the National Natural Science Foundation of China (Nos. 21606163 and 21878205), Coal Bed Methane Joint Foundation of Shanxi (2016012006), Foundation of State Key Laboratory of Coal Conversion (J18-19-610), Welch Foundation (grant AX-1730), and the Distinguished Scientist Fellowship Program (DSFP) at KSU.

摘要: Separation of ethane from ethylene is a very important but challenging process in the petrochemical industry. Finding an alternative method would reduce the energy needed to make 170 million tons of ethylene manufactured worldwide each year. Adsorptive separation using C2H6-selective porous materials to directly produce high-purity C2H4 is more energy-efficient. We herein report the “reversed C2H6/C2H4 adsorption” in a metal-organic framework Cr-BTC via the introduction of oxygen on its open metal sites. The oxidized Cr-BTC(O2) can bind C2H6 over C2H4 through the active Cr-superoxo sites, which was elucidated by the gas sorption isotherms and density functional theory calculations. This material thus exhibits a good performance for the separation of 50/50 C2H6/C2H4 mixtures to produce 99.99% pure C2H4 in a single separation operation.

关键词: Metal-organic frameworks, Adsorptive separation, Open metal sites, Reversed ethane/ethylene adsorption, Density-functional theory calculation, Breakthrough curves

Abstract: Separation of ethane from ethylene is a very important but challenging process in the petrochemical industry. Finding an alternative method would reduce the energy needed to make 170 million tons of ethylene manufactured worldwide each year. Adsorptive separation using C2H6-selective porous materials to directly produce high-purity C2H4 is more energy-efficient. We herein report the “reversed C2H6/C2H4 adsorption” in a metal-organic framework Cr-BTC via the introduction of oxygen on its open metal sites. The oxidized Cr-BTC(O2) can bind C2H6 over C2H4 through the active Cr-superoxo sites, which was elucidated by the gas sorption isotherms and density functional theory calculations. This material thus exhibits a good performance for the separation of 50/50 C2H6/C2H4 mixtures to produce 99.99% pure C2H4 in a single separation operation.

Key words: Metal-organic frameworks, Adsorptive separation, Open metal sites, Reversed ethane/ethylene adsorption, Density-functional theory calculation, Breakthrough curves