Empirical correction of kinetic model for polymer thermal reaction process based on first order reaction kinetics

doi:10.1016/j.cjche.2020.09.023

中国化学工程学报 ›› 2021, Vol. 38 ›› Issue (10): 132-144.DOI: 10.1016/j.cjche.2020.09.023

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Empirical correction of kinetic model for polymer thermal reaction process based on first order reaction kinetics

Zhaoxiang Zhang^1,2,3, Fei Guo^1,2, Wei Song⁴, Xiaohong Jia^1,2, Yuming Wang^1,2

1. State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China;
2. Joint Research Center for Rubber and Plastic Seals, Tsinghua University, Beijing 100084, China;
3. State Key Laboratory of Advanced Forming Technology & Equipment, China Academy of Machinery Science & Technology, Beijing 100044, China;
4. Tianding Sealing Technology (Beijing) Co., Ltd., Beijing 100072, China

收稿日期:2020-05-14 修回日期:2020-08-07 出版日期:2021-10-28 发布日期:2021-12-02
通讯作者: Fei Guo
基金资助:
This work was supported by the National Key Research and Development Program of China (Grant No. 2018YFB2001002).

Empirical correction of kinetic model for polymer thermal reaction process based on first order reaction kinetics

Zhaoxiang Zhang^1,2,3, Fei Guo^1,2, Wei Song⁴, Xiaohong Jia^1,2, Yuming Wang^1,2

1. State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China;
2. Joint Research Center for Rubber and Plastic Seals, Tsinghua University, Beijing 100084, China;
3. State Key Laboratory of Advanced Forming Technology & Equipment, China Academy of Machinery Science & Technology, Beijing 100044, China;
4. Tianding Sealing Technology (Beijing) Co., Ltd., Beijing 100072, China

Received:2020-05-14 Revised:2020-08-07 Online:2021-10-28 Published:2021-12-02
Contact: Fei Guo
Supported by:
This work was supported by the National Key Research and Development Program of China (Grant No. 2018YFB2001002).

摘要/Abstract

摘要： Based on the theory of first-order reaction kinetics, a thermal reaction kinetic model in integral form has been derive. To make the model more applicable, the effects of time and the conversion degree on the reaction rate parameters were considered. Two types of undetermined functions were used to compensate for the intrinsic variation of the reaction rate, and two types of correction methods are provided. The model was explained and verified using published experimental data of different polymer thermal reaction systems, and its effectiveness and wide adaptability were confirmed. For the given kinetic model, only one parameter needs to be determined. The proposed empirical model is expected to be used in the numerical simulation of polymer thermal reaction process.

关键词: Thermal reaction, Polymer processing, Reaction kinetics, Mathematical modeling, Empirical correction

Abstract: Based on the theory of first-order reaction kinetics, a thermal reaction kinetic model in integral form has been derive. To make the model more applicable, the effects of time and the conversion degree on the reaction rate parameters were considered. Two types of undetermined functions were used to compensate for the intrinsic variation of the reaction rate, and two types of correction methods are provided. The model was explained and verified using published experimental data of different polymer thermal reaction systems, and its effectiveness and wide adaptability were confirmed. For the given kinetic model, only one parameter needs to be determined. The proposed empirical model is expected to be used in the numerical simulation of polymer thermal reaction process.

Key words: Thermal reaction, Polymer processing, Reaction kinetics, Mathematical modeling, Empirical correction

Zhaoxiang Zhang, Fei Guo, Wei Song, Xiaohong Jia, Yuming Wang. Empirical correction of kinetic model for polymer thermal reaction process based on first order reaction kinetics[J]. 中国化学工程学报, 2021, 38(10): 132-144.

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Empirical correction of kinetic model for polymer thermal reaction process based on first order reaction kinetics

Empirical correction of kinetic model for polymer thermal reaction process based on first order reaction kinetics

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