SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2022, Vol. 45 ›› Issue (5): 1-14.DOI: 10.1016/j.cjche.2022.01.027

• •    下一篇

Conjugated microporous polymer membranes for chemical separations

Zongyao Zhou, Zhen Li, Lubna M. Rehman, Zhiping Lai   

  1. Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
  • 收稿日期:2021-07-23 修回日期:2022-01-23 出版日期:2022-05-28 发布日期:2022-06-22
  • 通讯作者: Zhiping Lai,E-mail:Zhiping.lai@kaust.edu.sa
  • 基金资助:
    The work was supported by the King Abdullah University of Science and Technology, Saudi Arabia, under the competitive research grant URF/1/3769-01.

Conjugated microporous polymer membranes for chemical separations

Zongyao Zhou, Zhen Li, Lubna M. Rehman, Zhiping Lai   

  1. Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
  • Received:2021-07-23 Revised:2022-01-23 Online:2022-05-28 Published:2022-06-22
  • Contact: Zhiping Lai,E-mail:Zhiping.lai@kaust.edu.sa
  • Supported by:
    The work was supported by the King Abdullah University of Science and Technology, Saudi Arabia, under the competitive research grant URF/1/3769-01.

摘要: Conjugated microporous polymers (CMPs) are a unique class of porous organic materials, which are constructed with π-conjugation structures leading to intrinsic micropores. The CMPs properties such as high surface area, intrinsic and rich micropores, interlocking and rigid structure, extensive π-conjugation and tunable band-gap, chemical and thermal stability, together with tailored functionalities, contribute to its abundant potential for application in fields such as photocatalysis, optoelectronics, energy storage, and chemical sensors. Recently, CMPs have gained importance in the field of membranes for chemical separation. In this review, we briefly discuss the historical development of CMPs, followed by a detailed description of the progress in state-of-the-art design, preparation, and application of CMPs in membranes. Additionally, we provide inference on the future prospects of CMPs as membranes.

关键词: Conjugated microporous polymer, Membrane, Separation, Electropolymerization, Film

Abstract: Conjugated microporous polymers (CMPs) are a unique class of porous organic materials, which are constructed with π-conjugation structures leading to intrinsic micropores. The CMPs properties such as high surface area, intrinsic and rich micropores, interlocking and rigid structure, extensive π-conjugation and tunable band-gap, chemical and thermal stability, together with tailored functionalities, contribute to its abundant potential for application in fields such as photocatalysis, optoelectronics, energy storage, and chemical sensors. Recently, CMPs have gained importance in the field of membranes for chemical separation. In this review, we briefly discuss the historical development of CMPs, followed by a detailed description of the progress in state-of-the-art design, preparation, and application of CMPs in membranes. Additionally, we provide inference on the future prospects of CMPs as membranes.

Key words: Conjugated microporous polymer, Membrane, Separation, Electropolymerization, Film