Cost-effective bifunctional lignin-derived carbon supported tin oxide with efficient production of 5-hydroxymethylfurfural from glucose

doi:10.1016/j.cjche.2024.07.002

中国化学工程学报 ›› 2024, Vol. 74 ›› Issue (10): 154-164.DOI: 10.1016/j.cjche.2024.07.002

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Cost-effective bifunctional lignin-derived carbon supported tin oxide with efficient production of 5-hydroxymethylfurfural from glucose

Sien Yan¹, Linhuo Gan^1,4, Kui Wang^2,3,4, Kang Sun^2,3,4

1 College of Chemical Engineering, Huaqiao University, Xiamen 361021, China;
2 Key Laboratory of Biomass Energy and Materials of Jiangsu Province, Nanjing 210042, China;
3 Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China;
4 Fujian Provincial Key Laboratory of Biomass Low-Carbon Conversion, Huaqiao University, Xiamen 361021, China

收稿日期:2023-12-26 修回日期:2024-06-12 接受日期:2024-07-09 出版日期:2024-10-28 发布日期:2024-08-06
通讯作者: Linhuo Gan,Tel.:+86 18959266106.E-mail:lhgan401@126.com
基金资助:
This work was supported by the independent research major project of Key Laboratory of Biomass Energy and Materials of Jiangsu Province, China (JSBEM-S-202202), the key project of Science and Technology Plan of Nanping, China (N2022B002), and the Open Research Fund of Academy of Advanced Carbon Conversion Technology, Huaqiao University, China.

Cost-effective bifunctional lignin-derived carbon supported tin oxide with efficient production of 5-hydroxymethylfurfural from glucose

Sien Yan¹, Linhuo Gan^1,4, Kui Wang^2,3,4, Kang Sun^2,3,4

1 College of Chemical Engineering, Huaqiao University, Xiamen 361021, China;
2 Key Laboratory of Biomass Energy and Materials of Jiangsu Province, Nanjing 210042, China;
3 Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China;
4 Fujian Provincial Key Laboratory of Biomass Low-Carbon Conversion, Huaqiao University, Xiamen 361021, China

Received:2023-12-26 Revised:2024-06-12 Accepted:2024-07-09 Online:2024-10-28 Published:2024-08-06
Contact: Linhuo Gan,Tel.:+86 18959266106.E-mail:lhgan401@126.com
Supported by:
This work was supported by the independent research major project of Key Laboratory of Biomass Energy and Materials of Jiangsu Province, China (JSBEM-S-202202), the key project of Science and Technology Plan of Nanping, China (N2022B002), and the Open Research Fund of Academy of Advanced Carbon Conversion Technology, Huaqiao University, China.

摘要/Abstract

摘要： 5-Hydroxymethylfurfural (5-HMF) is one of the important bio-based platform compounds, and the catalytic conversion of glucose to 5-HMF is a highly desirable approach that is receiving increasing attention. Herein, we reported the synthesis of lignin-derived carbon supported tin oxides (SnO/LC) catalyst via a two-step hydrothermal-pyrolytic method using wheat straw alkali lignin as a cost-effective carbon source with high carbon content. The key preparation conditions of the catalyst and its catalytic conditions for the conversion of glucose to 5-HMF were investigated, respectively. Results show that under the preparation conditions of tin tetrachloride dosage of 3.0 mmol and pyrolysis temperature of 500 ℃, the optimized catalyst (3.0-SnO/LC-500) with a high yield of 63.4% exhibits good catalytic performance of 5-HMF yield of 50.1% and reaction selectivity of 86.0% under the optimum conditions of reaction temperature and time of 190 ℃ and 3 h, initial glucose concentration of 10 %(mass), 3.0-SnO/LC-500 dosage of 100 mg in a biphasic solvent system of volume ratio of water to tetrahydrofuran of 1:4. In addition, 3.0-SnO/LC-500 exerts an excellent reusability in a five-cycle experiment. Furthermore, SnO/LC was characterized in detail using X-ray diffraction patterns (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET), ammonia temperature-programmed-desorption (NH₃-TPD), pyridine adsorption infrared spectroscopy (Py-FTIR), scanning electron microscope (SEM) and thermal gravimetric analysis (TGA). Results indicate that Brønsted acid sites and Lewis acid sites coexist on 3.0-SnO/LC-500, and more Sn⁴⁺, as well as a proper ratio of weak acidity to medium acidity, are conductive to its catalytic performance in glucose-to-5-HMF reaction.

关键词: Lignin, Biomass, Catalyst support, Selectivity, Biphasic solvent system

Abstract: 5-Hydroxymethylfurfural (5-HMF) is one of the important bio-based platform compounds, and the catalytic conversion of glucose to 5-HMF is a highly desirable approach that is receiving increasing attention. Herein, we reported the synthesis of lignin-derived carbon supported tin oxides (SnO/LC) catalyst via a two-step hydrothermal-pyrolytic method using wheat straw alkali lignin as a cost-effective carbon source with high carbon content. The key preparation conditions of the catalyst and its catalytic conditions for the conversion of glucose to 5-HMF were investigated, respectively. Results show that under the preparation conditions of tin tetrachloride dosage of 3.0 mmol and pyrolysis temperature of 500 ℃, the optimized catalyst (3.0-SnO/LC-500) with a high yield of 63.4% exhibits good catalytic performance of 5-HMF yield of 50.1% and reaction selectivity of 86.0% under the optimum conditions of reaction temperature and time of 190 ℃ and 3 h, initial glucose concentration of 10 %(mass), 3.0-SnO/LC-500 dosage of 100 mg in a biphasic solvent system of volume ratio of water to tetrahydrofuran of 1:4. In addition, 3.0-SnO/LC-500 exerts an excellent reusability in a five-cycle experiment. Furthermore, SnO/LC was characterized in detail using X-ray diffraction patterns (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET), ammonia temperature-programmed-desorption (NH₃-TPD), pyridine adsorption infrared spectroscopy (Py-FTIR), scanning electron microscope (SEM) and thermal gravimetric analysis (TGA). Results indicate that Brønsted acid sites and Lewis acid sites coexist on 3.0-SnO/LC-500, and more Sn⁴⁺, as well as a proper ratio of weak acidity to medium acidity, are conductive to its catalytic performance in glucose-to-5-HMF reaction.

Key words: Lignin, Biomass, Catalyst support, Selectivity, Biphasic solvent system

Sien Yan, Linhuo Gan, Kui Wang, Kang Sun. Cost-effective bifunctional lignin-derived carbon supported tin oxide with efficient production of 5-hydroxymethylfurfural from glucose[J]. 中国化学工程学报, 2024, 74(10): 154-164.

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Cost-effective bifunctional lignin-derived carbon supported tin oxide with efficient production of 5-hydroxymethylfurfural from glucose

Cost-effective bifunctional lignin-derived carbon supported tin oxide with efficient production of 5-hydroxymethylfurfural from glucose

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