Ultra-high specific surface area activated carbon from Taihu cyanobacteria via KOH activation for enhanced methylene blue adsorption

doi:10.1016/j.cjche.2023.12.002

中国化学工程学报 ›› 2024, Vol. 67 ›› Issue (3): 106-116.DOI: 10.1016/j.cjche.2023.12.002

Ultra-high specific surface area activated carbon from Taihu cyanobacteria via KOH activation for enhanced methylene blue adsorption

Yifang Mi¹, Wenqiang Wang¹, Sen Zhang¹, Yalong Guo¹, Yufeng Zhao², Guojin Sun², Zhihai Cao¹

1 Key Laboratory of Advanced Textile Materials and Manufacturing Technology and Engineering Research Center for Eco-Dyeing & Finishing of Textiles, Ministry of Education, Zhejiang Provincial Engineering Research Center for Green and Low-carbon Dyeing & Finishing, Zhejiang Sci-Tech University, Hangzhou 310018, China;
2 Key Laboratory for Technology in Rural Water Management of Zhejiang Province, Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, China

收稿日期:2023-09-28 修回日期:2023-11-23 出版日期:2024-03-28 发布日期:2024-06-01
通讯作者: Guojin Sun,E-mail address:sungj@zjweu.edu.cn;Zhihai Cao,E-mail address:zhcao@zstu.edu.cn.
基金资助:
This work was financially supported by the Key Research & Development program of Zhejiang Province (2021C03196), the National Key Research and Development Program of China (2022YFE0128600), and the Natural Science Foundation of Zhejiang Province (LY22B060011).

Ultra-high specific surface area activated carbon from Taihu cyanobacteria via KOH activation for enhanced methylene blue adsorption

Yifang Mi¹, Wenqiang Wang¹, Sen Zhang¹, Yalong Guo¹, Yufeng Zhao², Guojin Sun², Zhihai Cao¹

1 Key Laboratory of Advanced Textile Materials and Manufacturing Technology and Engineering Research Center for Eco-Dyeing & Finishing of Textiles, Ministry of Education, Zhejiang Provincial Engineering Research Center for Green and Low-carbon Dyeing & Finishing, Zhejiang Sci-Tech University, Hangzhou 310018, China;
2 Key Laboratory for Technology in Rural Water Management of Zhejiang Province, Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, China

Received:2023-09-28 Revised:2023-11-23 Online:2024-03-28 Published:2024-06-01
Contact: Guojin Sun,E-mail address:sungj@zjweu.edu.cn;Zhihai Cao,E-mail address:zhcao@zstu.edu.cn.
Supported by:
This work was financially supported by the Key Research & Development program of Zhejiang Province (2021C03196), the National Key Research and Development Program of China (2022YFE0128600), and the Natural Science Foundation of Zhejiang Province (LY22B060011).

摘要/Abstract

摘要： Cyanobacteria-based activated carbon (CBAC) was successfully prepared by pyrolysis-activation of Taihu cyanobacteria. When the impregnation ratio and activated temperature were 2 and 800 ℃, respectively, the optimal CBACs possessed an ultra-high specific surface (2178.90 m²·g^-1) and plenty of micro- and meso-pores, as well as a high pore volume (1.01 cm³·g^-1). Ascribed to ultra-high surface area,π-π interaction, electrostatic interaction, as well as hydrogen-bonding interactions, the CBACs displayed huge superiority in efficient dye removal. The saturated methylene blue adsorption capacity by CBACs could be as high as 1143.4 mg·g^-1, superior to that of other reported biomass-activated carbons. The adsorption was endothermic and modeled well by the pseudo-second-order kinetic, intra-particle diffusion, and Langmuir models. This work presented the effectiveness of Taihu cyanobacteria adsorbent ascribed to its super large specific surface area and high adsorption ability.

关键词: Activated carbon, Biomass, Dye adsorption, Taihu cyanobacteria

Abstract: Cyanobacteria-based activated carbon (CBAC) was successfully prepared by pyrolysis-activation of Taihu cyanobacteria. When the impregnation ratio and activated temperature were 2 and 800 ℃, respectively, the optimal CBACs possessed an ultra-high specific surface (2178.90 m²·g^-1) and plenty of micro- and meso-pores, as well as a high pore volume (1.01 cm³·g^-1). Ascribed to ultra-high surface area,π-π interaction, electrostatic interaction, as well as hydrogen-bonding interactions, the CBACs displayed huge superiority in efficient dye removal. The saturated methylene blue adsorption capacity by CBACs could be as high as 1143.4 mg·g^-1, superior to that of other reported biomass-activated carbons. The adsorption was endothermic and modeled well by the pseudo-second-order kinetic, intra-particle diffusion, and Langmuir models. This work presented the effectiveness of Taihu cyanobacteria adsorbent ascribed to its super large specific surface area and high adsorption ability.

Key words: Activated carbon, Biomass, Dye adsorption, Taihu cyanobacteria

Yifang Mi, Wenqiang Wang, Sen Zhang, Yalong Guo, Yufeng Zhao, Guojin Sun, Zhihai Cao. Ultra-high specific surface area activated carbon from Taihu cyanobacteria via KOH activation for enhanced methylene blue adsorption[J]. 中国化学工程学报, 2024, 67(3): 106-116.

参考文献

[1] W. Xiao, Z.N. Garba, S.C. Sun, I. Lawan, L.W. Wang, M. Lin, Z.H. Yuan, Preparation and evaluation of an effective activated carbon from white sugar for the adsorption of rhodamine B dye, J. Clean. Prod. 253(2020)119989.
[2] H.J. Xue, X. Gao, M.K. Seliem, M. Mobarak, R.T. Dong, X.M. Wang, K.L. Fu, Q. Li, Z.C. Li, Efficient adsorption of anionic azo dyes on porous heterostructured MXene/biomass activated carbon composites:Experiments, characterization, and theoretical analysis via advanced statistical physics models, Chem. Eng. J. 451(2023)138735.
[3] J.L. Wang, R. Wang, J.Q. Ma, Y.J. Sun, Study on the application of shell-activated carbon for the adsorption of dyes and antibiotics, Water 14(22)(2022)3752.
[4] N.S. Razali, A.S. Abdulhameed, A.H. Jawad, Z.A. Alothman, T.A. Yousef, O.K. AlDuaij, N.S. Alsaiari, High-surface-area-activated carbon derived from mango peels and seeds wastes via microwave-induced ZnCl₂ activation for adsorption of methylene blue dye molecules:Statistical optimization and mechanism, Molecules 27(20)(2022)6947.
[5] A.H. Jawad, S.E.M. Saber, A.S. Abdulhameed, A. Reghioua, Z.A. Alothman, L.D. Wilson, Mesoporous activated carbon from mangosteen (Garcinia mangostana) peels by H₃PO₄ assisted microwave:Optimization, characterization, and adsorption mechanism for methylene blue dye removal, Diam. Relat. Mater. 129(2022)109389.
[6] N.A.M. Hanafi, A.S. Abdulhameed, A.H. Jawad, Z.A. Alothman, T.A. Yousef, O.K. Al Duaij, N.S. Alsaiari, Optimized removal process and tailored adsorption mechanism of crystal violet and methylene blue dyes by activated carbon derived from mixed orange peel and watermelon rind using microwaveinduced ZnCl₂ activation, Biomass Convers. Biorefin. 12(2022)1-13.
[7] N.N. Tran, M. Escrib a-Gelonch, M.M. Sarafraz, Q.H. Pho, S. Sagadevan, V. Hessel, Process technology and sustainability assessment of wastewater treatment, Ind. Eng. Chem. Res. 62(3)(2023)1195-1214.
[8] H.M. Solayman, M.A. Hossen, A.A. Aziz, N.Y. Yahya, K.H. Leong, L.C. Sim, M.U. Monir, K. Zoh, Performance evaluation of dye wastewater treatment technologies:A review, J. Environ. Chem. Eng. 11(2023)109610.
[9] S.W. Lin, H.S. Qi, P.Y. Hou, K. Liu, Resource recovery from textile wastewater:Dye, salt, and water regeneration using solar-driven interfacial evaporation, J. Clean. Prod. 391(2023)136148.
[10] A.S. Abdulhameed, A.H. Jawad, E. Kashi, K.A. Radzun, Z.A. Alothman, L.D. Wilson, Insight into adsorption mechanism, modeling, and desirability function of crystal violet and methylene blue dyes by microalgae:Box-Behnken design application, Algal Res. 67(2022)102864.
[11] A.N. Amjah, A.S. Abdulhameed, A.H. Jawad, Z.A. Alothman, L.D. Wilson, Activated carbon from noodles food waste via microwave-assisted KOH for optimized brilliant green dye removal, Biomass Convers. Biorefin. 8(2023)1-13.
[12] M. Gayathiri, T. Pulingam, K.T. Lee, K. Sudesh, Activated carbon from biomass waste precursors:Factors affecting production and adsorption mechanism, Chemosphere 294(2022)133764.
[13] Y. Xia, H.F. Zuo, J.L. Lv, S.Y. Wei, Y.X. Yao, Z.G. Liu, Q.Q. Lin, Y.L. Yu, W.J. Yu, Y.X. Huang, Preparation of multi-layered microcapsule-shaped activated biomass carbon with ultrahigh surface area from bamboo parenchyma cells for energy storage and cationic dyes removal, J. Clean. Prod. 396(2023)136517.
[14] S. Moosavi, C.W. Lai, S. Gan, G. Zamiri, O. Akbarzadeh Pivehzhani, M.R. Johan, Application of efficient magnetic particles and activated carbon for dye removal from wastewater, ACS Omega 5(33)(2020)20684-20697.
[15] N. Muttil, S. Jagadeesan, A. Chanda, M. Duke, S.K. Singh, Production, types, and applications of activated carbon derived from waste tyres:An overview, Appl. Sci. 13(1)(2022)257.
[16] M.K. Uddin, N.N. Abd Malek, A.H. Jawad, S. Sabar, Pyrolysis of rubber seed pericarp biomass treated with sulfuric acid for the adsorption of crystal violet and methylene green dyes:An optimized process, Int. J. Phytoremediation 25(4)(2023)393-402.
[17] S. Sangon, A.J. Hunt, T.M. Attard, P. Mengchang, Y. Ngernyen, N. Supanchaiyamat, Valorisation of waste rice straw for the production of highly effective carbon based adsorbents for dyes removal, J. Clean. Prod. 172(2018)1128-1139.
[18] Y.F. Mi, S. Zhang, Y.F. Zhao, G.J. Sun, Z.H. Cao, Pyrrolic N and persistent free radical synergistically promote catalytic degradation of dyes via Fe₂O₃/activated biochar derived from Taihu blue algae, Colloids Surf., A 667(2023)131393.
[19] Z. Lin, R. Wang, S. Tan, K. Zhang, Q. Yin, Z. Zhao, P. Gao, Nitrogen-doped hydrochar prepared by biomass and nitrogen-containing wastewater for dye adsorption:Effect of nitrogen source in wastewater on the adsorption performance of hydrochar, J. Environ. Manag. 334(2023)117503.
[20] R.A. Rashid, A.H. Jawad, M.A.M. Ishak, N.N. Kasim, KOH-activated carbon developed from biomass waste:Adsorption equilibrium, kinetic and thermodynamic studies for methylene blue uptake, Desalination Water Treat. 57(56)(2016)27226-27236.
[21] A.H. Jawad, A.S. Abdulhameed, Statistical modeling of methylene blue dye adsorption by high surface area mesoporous activated carbon from bamboo chip using KOH-assisted thermal activation, Energy Ecol. Environ. 5(6)(2020)456-469.
[22] H. Jawad Ali, M.Z. Sahb, M.I.M. Azlan, I. Khudzir, Large surface area activated carbon from low-rank coal via microwave-assisted KOH activation for methylene blue adsorption, Desalination Water Treat. 110(2018)239-249.
[23] A.N. Abdulhameed, N.N.M.F. Hum, S. Rangabhashiyam, A.H. Jawad, L.D. Wilson, Z.M. Yaseen, A.A. Al-Kahtani, Z.A. ALOthman, Statistical modeling and mechanistic pathway for methylene blue dye removal by high surface area and mesoporous grass-based activated carbon using Ki₂CO₃ activator, J. Environ. Chem. Eng. 9(2021)105530.
[24] Q.H. Wang, Z.Y. Lai, C.M. Luo, J. Zhang, X.D. Cao, J. Liu, J. Mu, Honeycomb-like activated carbon with microporous nanosheets structure prepared from waste biomass cork for highly efficient dye wastewater treatment, J. Hazard Mater. 416(2021)125896.
[25] W. Chen, M. Gong, K.X. Li, M.W. Xia, Z.Q. Chen, H.Y. Xiao, Y. Fang, Y.Q. Chen, H. P. Yang, H.P. Chen, Insight into KOH activation mechanism during biomass pyrolysis:Chemical reactions between O-containing groups and KOH, Appl. Energy 278(2020)115730.
[26] B.G. Liu, R. Shi, R.F. Chen, C.H. Wang, K. Zhou, Y.D. Ren, Z. Zeng, Y.Y. Liu, L.Q. Li, Optimized synthesis of nitrogen-doped carbon with extremely high surface area for adsorption and supercapacitor, Appl. Surf. Sci. 538(2021)147961.
[27] M. Bora, J. Tamuly, S. Maria Benoy, S. Hazarika, D. Bhattacharjya, B.K. Saikia, Highly scalable and environment-friendly conversion of low-grade coal to activated carbon for use as electrode material in symmetric supercapacitor, Fuel 329(2022)125385.
[28] C. Wen, T.Y. Liu, D.P. Wang, Y.Q. Wang, H.P. Chen, G.Q. Luo, Z.J. Zhou, C.K. Li, M. H. Xu, Biochar as the effective adsorbent to combustion gaseous pollutants:Preparation, activation, functionalization and the adsorption mechanisms, Prog. Energy Combust. Sci. 99(2023)101098.
[29] Y. Gao, Q.Y. Yue, B.Y. Gao, A.M. Li, Insight into activated carbon from different kinds of chemical activating agents:A review, Sci. Total Environ. 746(2020)141094.
[30] R. Shokrani Havigh, H. Mahmoudi Chenari, A comprehensive study on the effect of carbonization temperature on the physical and chemical properties of carbon fibers, Sci. Rep. 12(2022)10704.
[31] L. He, W.Y. Zhang, K. Zhao, S. Liu, Y. Zhao, Core-shell Cu@Cu₂O nanoparticles embedded in 3D honeycomb-like N-doped graphitic carbon for photocatalytic CO₂ reduction, J. Mater. Chem. A 10(9)(2022)4758-4769.
[32] J. Serafin, B. Dziejarski, O.F. Cruz Jr., J. Srenscek-Nazzal, Design of highly microporous activated carbons based on walnut shell biomass for H₂ and CO₂ storage, Carbon 201(2023)633-647.
[33] S. Cheng, W.B. Meng, B.L. Xing, C.L. Shi, Q. Wang, D.P. Xia, Y.H. Nie, G.Y. Yi, C.X. Zhang, H.Y. Xia, Efficient removal of heavy metals from aqueous solutions by Mg/Fe bimetallic oxide-modified biochar:Experiments and DFT investigations, J. Clean. Prod. 403(2023)136821.
[34] S. Cheng, M. Meng, B. Xing, C. Shi, Y. Nie, D. Xia, G. Yi, C. Zhang, H. Xia, Preparation of valuable pyrolysis products from poplar waste under different temperatures by pyrolysis:Evaluation of pyrolysis products, Bioresour. Technol. 364(2022)128011.
[35] H.J. Xue, X.M. Wang, Q. Xu, F. Dhaouadi, L. Sellaoui, M.K. Seliem, A. Ben Lamine, H. Belmabrouk, A. Bajahzar, A. Bonilla-Petriciolet, Z.C. Li, Q. Li, Adsorption of methylene blue from aqueous solution on activated carbons and composite prepared from an agricultural waste biomass:A comparative study by experimental and advanced modeling analysis, Chem. Eng. J. 430(2022)132801.
[36] O.D. Caicedo Salcedo, D.P. Vargas, L. Giraldo, J.C. Moreno-Pirajan, Study of mercury[Hg (II)] adsorption from aqueous solution on functionalized activated carbon, ACS Omega 6(18)(2021)11849-11856.
[37] J.N. Ding, Y.J. Tang, S.S. Zheng, S.T. Zhang, H.G. Xue, Q.Q. Kong, H. Pang, The synthesis of MOF derived carbon and its application in water treatment, Nano Res. 15(8)(2022)6793-6818.
[38] C. Karaman, O. Karaman, P.L. Show, H. Karimi-Maleh, N. Zare, Congo red dye removal from aqueous environment by cationic surfactant modified-biomass derived carbon:Equilibrium, kinetic, and thermodynamic modeling, and forecasting via artificial neural network approach, Chemosphere 290(2022)133346.
[39] H.M. El-Bery, M. Saleh, R.A. El-Gendy, M.R. Saleh, S.M. Thabet, High adsorption capacity of phenol and methylene blue using activated carbon derived from lignocellulosic agriculture wastes, Sci. Rep. 12(2022)5499.
[40] A.H. Jawad, A. Saud Abdulhameed, L.D. Wilson, S.S.A. Syed-Hassan, Z.A. Alothman, M.R. Khan, High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption:Optimization and mechanism study, Chin. J. Chem. Eng. 32(2021)281-290.
[41] Z. Heidarinejad, O. Rahmanian, M. Fazlzadeh, M. Heidari, Enhancement of methylene blue adsorption onto activated carbon prepared from Date Press Cake by low frequency ultrasound, J. Mol. Liq. 264(2018)591-599.
[42] L. Li, Y. Lv, J. Wang, C. Jia, Z. Zhan, Z. Dong, L. Liu, X. Zhu, Enhance pore structure of cyanobacteria-based porous carbon by polypropylene to improve adsorption capacity of methylene blue, Bioresour. Technol. 343(2021)126101.
[43] F. Jiang, D. Cao, S. Hu, Y. Wang, Y. Zhang, X. Huang, H. Zhao, C. Wu, J. Li, Y. Ding, K. Liu, High-pressure carbon dioxide-hydrothermal enhance yield and methylene blue adsorption performance of banana pseudo-stem activated carbon, Bioresour. Technol. 354(2022)127137.
[44] Y.L. Zhang, G.Z. Ji, C.J. Li, X.X. Wang, A.M. Li, Templating synthesis of hierarchical porous carbon from heavy residue of tire pyrolysis oil for methylene blue removal, Chem. Eng. J. 390(2020)124398.
[45] P. Cheng, X.H. Wang, J. Markus, M. Abdul Wahab, S. Chowdhury, R.J. Xin, S.M. Alshehri, Y. Bando, Y. Yamauchi, Y.V. Kaneti, Carbon nanotube-decorated hierarchical porous nickel/carbon hybrid derived from nickel-based metalorganic framework for enhanced methyl blue adsorption, J. Colloid Interface Sci. 638(2023)220-230.
[46] Q.N. Han, J. Wang, B.A. Goodman, J.K. Xie, Z.G. Liu, High adsorption of methylene blue by activated carbon prepared from phosphoric acid treated eucalyptus residue, Powder Technol. 366(2020)239-248.
[47] W.T. Zhao, H. Zhang, Q.D. He, L. Han, T.Y. Wang, F. Guo, W.B. Wang, Controllable synthesis of porous silicate@carbon heterogeneous composite from Coal Gangue waste as eco-friendly superior scavenger of dyes, J. Clean. Prod. 363(2022)132466.
[48] A. Nasrullah, A.H. Bhat, A. Naeem, M.H. Isa, M. Danish, High surface area mesoporous activated carbon-alginate beads for efficient removal of methylene blue, Int. J. Biol. Macromol. 107(2018)1792-1799.
[49] X.J. Qin, X.W. Zeng, S. Cheng, B.L. Xing, C.L. Shi, G.Y. Yi, Y.H. Nie, Q. Wang, C.X. Zhang, H.Y. Xia, Preparation of double functional carbon-based ZnO derived from rape straw for dye wastewater treatment, J. Water Process Eng. 52(2023)103588.
[50] S. Cheng, S.D. Zhao, B.L. Xing, C.L. Shi, W.B. Meng, C.X. Zhang, Z. Bo, Facile onepot green synthesis of magnetic separation photocatalyst-adsorbent and its application, J. Water Process Eng. 47(2022)102802.
[51] Y.F. Ma, M. Li, P. Li, L. Yang, L. Wu, F. Gao, X.B. Qi, Z.L. Zhang, Hydrothermal synthesis of magnetic sludge biochar for tetracycline and ciprofloxacin adsorptive removal, Bioresour. Technol. 319(2021)124199.
[52] E. R apo, S. Tonk, Factors affecting synthetic dye adsorption; desorption studies:A review of results from the last five years (2017-2021), Molecules 26(17)(2021)5419.
[53] F. Ullah, G.Z. Ji, M. Irfan, Y. Gao, F. Shafiq, Y. Sun, Q.U. Ain, A.M. Li, Adsorption performance and mechanism of cationic and anionic dyes by KOH activated biochar derived from medical waste pyrolysis, Environ. Pollut. 314(2022)120271.
[54] K. Jasri, A.S. Abdulhameed, A.H. Jawad, Z.A. Alothman, T.A. Yousef, O.K. Al Duaij, Mesoporous activated carbon produced from mixed wastes of oil palm frond and palm kernel shell using microwave radiation-assisted Ki₂CO₃ activation for methylene blue dye removal:Optimization by response surface methodology, Diam. Relat. Mater. 131(2023)109581.
[55] S. Singh, A.G. Anil, S. Khasnabis, V. Kumar, B. Nath, V. Adiga, T.S. Sunil Kumar Naik, S. Subramanian, V. Kumar, J. Singh, P.C. Ramamurthy, Sustainable removal of Cr (VI) using graphene oxide-zinc oxide nanohybrid:Adsorption kinetics, isotherms and thermodynamics, Environ. Res. 203(2022)111891.
[56] N. Abbasi, S.A. Khan, T.A. Khan, Statistically optimised sequestration of mefenamic acid from polluted water by acacia gum phthalate/pectin hydrogel:A novel multifunctional adsorbent material synthesised via microwaveassisted process, Chem. Eng. J. 466(2023)143296.
[57] R. Ahmad, M.O. Ejaz, Adsorption of methylene blue dye from aqueous solution onto synthesized bentonite/silvernanoparticles-alginate (Bent/AgNPs-Alg) bio-nanocomposite, Biomass Convers. Biorefin. 10(2022)1-16.
[58] K. Venkiteshwaran, E. Wells, B.K. Mayer, Kinetics, affinity, thermodynamics, and selectivity of phosphate removal using immobilized phosphate-binding proteins, Environ. Sci. Technol. 54(17)(2020)10885-10894.
[59] H. Molavi, A. Hakimian, A. Shojaei, M. Raeiszadeh, Selective dye adsorption by highly water stable metal-organic framework:Long term stability analysis in aqueous media, Appl. Surf. Sci. 445(2018)424-436.
[60] Y.J. Chi, Y.A. Xu, C.X. Xu, J.M. Tian, Y. Li, B.X. Gu, H.Y. Song, H. Zhang, Adsorptive removal of radioactive cesium from model nuclear wastewater over hydroxyl-functionalized mxene Ti₃C₂T_x, Ind. Eng. Chem. Res. 61(25)(2022)9054-9066.
[61] K.S. Obayomi, S.Y. Lau, A. Zahir, L. Meunier, J.H. Zhang, A.O. Dada, M. Rahman, Removing methylene blue from water:A study of sorption effectiveness onto nanoparticles-doped activated carbon, Chemosphere 313(2023)137533.

Ultra-high specific surface area activated carbon from Taihu cyanobacteria via KOH activation for enhanced methylene blue adsorption

Ultra-high specific surface area activated carbon from Taihu cyanobacteria via KOH activation for enhanced methylene blue adsorption

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Yong-Yi Zeng, Xin-Yi Xu, Jin-Xuan Xie, Wen-Li Chen, Lan Liu, Xin-Jian Yin, Bi-Shuang Chen. Lipase and photodecarboxylase coexpression: A potential strategy for alkane-based biodiesel production from natural triglycerides[J]. 中国化学工程学报, 2024, 67(3): 238-246.
[2]	Siang Chen, Wenling Wu, Zhaoyang Niu, Deqi Kong, Wenbin Li, Zhongli Tang, Donghui Zhang. High adsorption selectivity of activated carbon and carbon molecular sieve boosting CO₂/N₂ and CH₄/N₂ separation[J]. 中国化学工程学报, 2024, 67(3): 282-297.
[3]	Xin Wan, Hui Jiang, Zhen Ye, Hang Zhou, Yimin Ma, Xuanrui Miao, Xun He, Kequan Chen. Viscosity reduction of tapioca starch by incorporating with molasses hydrocolloids[J]. 中国化学工程学报, 2023, 61(9): 165-172.
[4]	Wenming Hao, Basma I. Waisi, Timothy M. Vadas, Jeffrey R. McCutcheon. Chemically activated carbon nanofibers for adsorptive removal of bisphenol-A: Batch adsorption and breakthrough curve study[J]. 中国化学工程学报, 2023, 61(9): 248-259.
[5]	Yifan Jiang, Bingqi Xie, Jisong Zhang. Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction[J]. 中国化学工程学报, 2023, 60(8): 165-172.
[6]	Jian Han, Xinhua Liu, Shanwei Hu, Nan Zhang, Jingjing Wang, Bin Liang. Optimization of decoupling combustion characteristics of coal briquettes and biomass pellets in household stoves[J]. 中国化学工程学报, 2023, 59(7): 182-192.
[7]	Wende Tian, Jiawei Zhang, Zhe Cui, Haoran Zhang, Bin Liu. Microscopic mechanism study and process optimization of dimethyl carbonate production coupled biomass chemical looping gasification system[J]. 中国化学工程学报, 2023, 58(6): 291-305.
[8]	Qi Yang, Weikang Dai, Maoshuai Li, Jie Wei, Yi Feng, Cheng Yang, Wanxin Yang, Ying Zheng, Jie Ding, Mei-Yan Wang, Xinbin Ma. Enhanced selective hydrogenation of glycolaldehyde to ethylene glycol over Cu⁰-Cu⁺ sites[J]. 中国化学工程学报, 2023, 57(5): 141-150.
[9]	Mustapha Omenesa Idris, Claudia Guerrero-Barajas, Hyun-Chul Kim, Asim Ali Yaqoob, Mohamad Nasir Mohamad Ibrahim. Scalability of biomass-derived graphene derivative materials as viable anode electrode for a commercialized microbial fuel cell: A systematic review[J]. 中国化学工程学报, 2023, 55(3): 277-292.
[10]	Ahmed M. Elgarahy, M.G. Eloffy, Eric Guibal, Huda M. Alghamdi, Khalid Z. Elwakeel. Use of biopolymers in wastewater treatment: A brief review of current trends and prospects[J]. 中国化学工程学报, 2023, 64(12): 292-320.
[11]	Aaron Albert Aryee, Chenping Gao, Runping Han, Lingbo Qu. Synthesis of a novel magnetic biomass-MOF composite for the efficient removal of phosphates: Adsorption mechanism and characterization study[J]. 中国化学工程学报, 2023, 62(10): 202-216.
[12]	Huan Xiang, Huiping Zhang, Pengfei Liu, Ying Yan. Adsorption dynamics of ethane from air in structured fixed beds with different microfibrous composites[J]. 中国化学工程学报, 2023, 53(1): 14-24.
[13]	Yadong Li, Yuanhui Shen, Zhaoyang Niu, Junpeng Tian, Donghui Zhang, Zhongli Tang, Wenbin Li. Process analysis of temperature swing adsorption and temperature vacuum swing adsorption in VOCs recovery from activated carbon[J]. 中国化学工程学报, 2023, 53(1): 346-360.
[14]	Shutong Pang, Hualiang An, Xinqiang Zhao, Yanji Wang. Influence of Ca/P ratio on the catalytic performance of hydroxyapatite for decarboxylation of itaconic acid to methacrylic acid[J]. 中国化学工程学报, 2023, 53(1): 402-408.
[15]	Xing Su, Ning Qiao, Bao-Chang Sun. A route for the study on mass transfer enhancement by adding particles in liquid phase[J]. 中国化学工程学报, 2022, 48(8): 158-165.