Measurement and Correlation of Solubilities of Adipic Acid in Different Solvents

›› 2009, Vol. 17 ›› Issue (3): 473-477.

Measurement and Correlation of Solubilities of Adipic Acid in Different Solvents

毛治博, 孙晓波, 栾向海, 王钰, 刘国际

College of Chemical Engineering, Zhengzhou University, Zhengzhou 450002, China

收稿日期:2008-12-05 修回日期:2009-03-02 出版日期:2009-06-28 发布日期:2009-06-28
通讯作者: LIU Guoji,E-mail:guojiliu@zzu.edu.cn
基金资助:
Supported by the Natural Science Foundation of Henan Province (0511021700)

Measurement and Correlation of Solubilities of Adipic Acid in Different Solvents

MAO Zhibo, SUN Xiaobo, LUAN Xianghai, WANG Yu, LIU Guoji

College of Chemical Engineering, Zhengzhou University, Zhengzhou 450002, China

Received:2008-12-05 Revised:2009-03-02 Online:2009-06-28 Published:2009-06-28
Supported by:
Supported by the Natural Science Foundation of Henan Province (0511021700)

摘要/Abstract

摘要： Using a simple and reliable apparatus, the solubilities of adipic acid in water, ethanol, chloroform, n-butanol and acetone are determined by the analytic method. The results are correlated with λh equation, Apelblat equation, and UNIFAC equation. The solubilities calculated by these models are in good agreement with experimental data, so that the models can meet the requirements of engineering design.

关键词: solubility, adipic acid, correlation

Abstract: Using a simple and reliable apparatus, the solubilities of adipic acid in water, ethanol, chloroform, n-butanol and acetone are determined by the analytic method. The results are correlated with λh equation, Apelblat equation, and UNIFAC equation. The solubilities calculated by these models are in good agreement with experimental data, so that the models can meet the requirements of engineering design.

Key words: solubility, adipic acid, correlation

毛治博, 孙晓波, 栾向海, 王钰, 刘国际. Measurement and Correlation of Solubilities of Adipic Acid in Different Solvents[J]. , 2009, 17(3): 473-477.

MAO Zhibo, SUN Xiaobo, LUAN Xianghai, WANG Yu, LIU Guoji. Measurement and Correlation of Solubilities of Adipic Acid in Different Solvents[J]. , 2009, 17(3): 473-477.

参考文献

1 Chen, G.S., Zhou, Y.M., Wang, X., “Marketing situation and developing trend of adipic acid”, Jiangsu Chemical Industry, 33(3), 69-71(2005).(in Chinese)
2 Shen, X.J., “Separation and purification of glutaric acid from mixed dicarboxylic acid”, Guangxi Chemical Industry, 27(4), 34-35(1998).(in Chinese)
3 Yu, S.J., “Study on separation of mixture of binary acids by extraction-crystallization method”, Journal of Liaoyang Petrochemical College, 16(2), 13-15(2000).(in Chinese)
4 Glew, G.N., Hildebrand, H.J., “The solubility and partial molar volume of iodine in perfluoro-n-heptane”, J. Phys. Chem.,(60), 616-618(1956).
5 Zvaigzne, A.I., “Solubility of anthracene in binary alkane+ 3-methyl-butanol solvent mixture”, J. Chem. Eng. Data, 39, 706-710(1994).
6 Shao, J., Zeng, Z.X., Xue, W.L., Wu, C., “Experimental measurement and correlation of the solubility of methyl-acetyl-naphthalene in n-heptane, n-octane, and n-dodecane”, Chin. J. Chem. Eng., 14(6), 780-783(2006).
7 Hei, E.C., Liu, H.L., “Determination of the solubilities of 2,4-dichlorobenzaldehyde in organic solvents”, Chin. J. Chem. Eng., 3(3), 160-162(1995).
8 Jia, Q.Z., Ma, P.S., Ma, S.N., Wang, C., “Solid-liquid equilibria of benzoic acid derivatives in 1-octanol”, Chin. J. Chem. Eng., 15(5), 710-714(2007).
9 Dong, Y., Ma, P.S., Xu, W., “Study on the solubility of maleic anhydride in 1, 2-cyclohexanedicarboxylic acid diisobutyl ester and diethyl ester”, J. Chem. Eng. Chinese Univ., 14(2), 160-163(2000).
10 Jiang, Q., Gao, G.H., Yu, Y.X., Qin, Y., “Solubility of sodium dimethyl sophthalate-sulfonate in water and in water+methanol containing sodium sulfate”, J. Chem. Eng. Data, 45, 292-294(2000).
11 Chang, H., Ma, P.S., Xia, S.Q., Bai, P., “Solubility of methane in the mixture of ethanol+hexane at high pressures”, Chin. J. Chem. Eng., 13(1), 144-148(2005).
12 Stephen, H., Stephen, T., Solubilities of Inorganic and Organic Compounds, Pergamon Press, New York, 451(1963).
13 Fan, L.H., Ma, P.S., Xiang, Z.L., “Study on crystallization thermodynamics of adipic acid”, Petrochemical Technology, 35(3), 245-249(2006).
14 Buchowski, H., Kslazcak, A., Pletrzyk, S., “Solvent activity along a saturation line and solubility of hydrogen-bonding solids”, J. Phys. Chem., 84, 975-979(1980).
15 Apelblat, A., Manzurala, E., “Solubilities of o-acetylsalicylic, 3,5-dinitrosalicylic, and p-toluic acid, and magnesium-DL-aspartate in water from T=(278 to 348)K”, J. Chem. Thermodyn., 31, 85-91(1999).
16 Apelblat, A., Manzurola, E., “Solubilities of manganese, cadmium, mercury and ead acetates in water from T=278.15 K to 340.15 K”, J. Chem. Thermodyn, 33, 147-153(2001).
17 Stanley, M.W., Phase Equilibria in Chemical Engineering, Butterworth, New York, 397-400(1985).
18 Fredenslund, A., Jones, R.L., Prausnitz, J.M., “Group-contribution estimation of activity coefficients in nonideal liquid mixtures”, AIChE J., 21(6), 1086-1099(1975).
19 Nelder, J.A., Mead, R., “A simplex method for function minimization”, Compu. J, 7(2), 308-313(1965).
20 Wang, F.A., Jiang, D.G., Index of Chemical Engineering Data, Chemical Industry Press, Beijing, 289-308(1995).

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Measurement and Correlation of Solubilities of Adipic Acid in Different Solvents

Measurement and Correlation of Solubilities of Adipic Acid in Different Solvents

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