Electrolytic Regeneration of Decarbonising Potassium Carbonate Solution

›› 2010, Vol. 18 ›› Issue (4): 538-543.

Electrolytic Regeneration of Decarbonising Potassium Carbonate Solution

刘娜, 赵兴雷, 王运东, 费维扬

State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

收稿日期:2009-12-08 修回日期:2010-03-29 出版日期:2010-08-28 发布日期:2010-08-28
通讯作者: WANG Yundong, E-mail:wangyd@tsinghua.edu.cn
基金资助:
Supported by the Specialized Research Fund for Doctoral Programme of Higher Education of MOE(200700033154,200800030095);the National Natural Science Foundation of China(20836008)

Electrolytic Regeneration of Decarbonising Potassium Carbonate Solution

LIU Na, ZHAO Xinglei, WANG Yundon, FEI Weiyang

State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2009-12-08 Revised:2010-03-29 Online:2010-08-28 Published:2010-08-28

摘要/Abstract

摘要： In this work,the regeneration mechanism of potassium carbonate solution after absorption of CO₂ using ion-exchange membrane electrolysis was presented.The solutions of potassium carbonate (K₂CO₃) and potassium bicarbonate (KHCO₃) were used to simulate the solution after absorbing CO₂.Experiments were carried out at various electrodes,temperatures and current densities.The results indicate that the membrane electrolysis can in-crease concentration ratio of K₂CO₃ and KHCO₃,and achieve 100% conversion.In thisprocess,not only CO₂ is desorbed from carbonate solution,but also hydrogen,as a byproduct,is generated at the cathode,which is the main contributor to reduce energy consumption.Thus,the membrane electrolysis is valuable in the regeneration of the K₂CO₃ absorbent.

关键词: membrane electrolysis, Benfield, regeneration, carbon dioxide

Abstract: In this work,the regeneration mechanism of potassium carbonate solution after absorption of CO₂ using ion-exchange membrane electrolysis was presented.The solutions of potassium carbonate (K₂CO₃) and potassium bicarbonate (KHCO₃) were used to simulate the solution after absorbing CO₂.Experiments were carried out at various electrodes,temperatures and current densities.The results indicate that the membrane electrolysis can in-crease concentration ratio of K₂CO₃ and KHCO₃,and achieve 100% conversion.In thisprocess,not only CO₂ is desorbed from carbonate solution,but also hydrogen,as a byproduct,is generated at the cathode,which is the main contributor to reduce energy consumption.Thus,the membrane electrolysis is valuable in the regeneration of the K₂CO₃ absorbent.

Key words: membrane electrolysis, Benfield, regeneration, carbon dioxide

刘娜, 赵兴雷, 王运东, 费维扬. Electrolytic Regeneration of Decarbonising Potassium Carbonate Solution[J]. , 2010, 18(4): 538-543.

LIU Na, ZHAO Xinglei, WANG Yundon, FEI Weiyang. Electrolytic Regeneration of Decarbonising Potassium Carbonate Solution[J]. , 2010, 18(4): 538-543.

参考文献

1 Song,C. S.,“Global challenges and strategies for control,conversion and utilization of CO₂ for sustainable development involving energy, catalysis,adsorption and chemical processing”,Catalysis Today,115,2-32(2006).
2 The Intergovernmental Panel on Climate Change(IPCC),“Climate change 2007—The physical science basis,summary for policymakers of the working group I report”,Cambridge University Press,Cambridge,4-10(2007).
3 UNFCC,“Kyoto Protocol to the united nations framework convention on climate change”,Journal of Environmental Law,10,215-224 (1998).
4 Yang,H.,Xu,Z.,Fan,M.,Gupta,R.,Slimane,R.B.,Bland,A.E.,Wright,I.,“Progress in carbon dioxide separation and capture:A review”,J.Environ.Sci.,20,14-27(2008).
5 Riemer,P.,“Green gas mitigation technologies,an overview of the CO₂ capture,storage and future activities of the IEA Greenhouse Gas R&D Programme”,Energy Conversion and Management,37,665-670(1996).
6 Abu-Zahra,M. R. M.,Schneiders,L.H.J.,Niederer,J.P.M.,Feron,P.H.M., Versteeg,G.F.,“CO₂ capture from power plants.Part I.A parametric study of the technical performance based on monoethanolamine”, International Journal Greenhouse Gas Control,1,37-46(2007).
7 Alstom,“Engineering feasibility and economics of CO₂ capture on an existing coal-fired power plant”,In:US DOE NETL Report PPL-01-CT-09,NETL,Pittsburgh(2001).
8 Kohl,A.L.,Gas Purification,5th edition,Gulf Publishing Company, Houston,Texas,USA(1997).
9 Lu,S.M.,Ma,Y.G.,Zhu,C.Y.,Shen,S.H.,“The enhancement of CO₂ chemical absorption by K₂CO₃ aqueous solution in the presence of activated carbon particles”,Chin.J.Chem.Eng.,15,842-846 (2007).
10 Aaron,D.,Tsouris,C.,“Separation of CO₂ from flue gas:A review”, Sep.Sci.Technol.,40,321-348(2005).
11 Tseng,P. C.,Savage,D. W.,“Carbon dioxide absorption into promoted carbonate solutions”,AIChE J.,34,922-931(1988).
12 Martin,F.J.,Kubic Jr.,W.L.,“A concept for producing car-bon-neutral synthetic fuel and chemicals”,Los Alamos National Laboratory,LA-UR-07-7897(2007). 13 Chapel,D. J.,Emest,J.,Mariz,C.,“Recovery of CO₂ from flue gases: commercial trends”,In:Canadian Society of Chemical Engineers Annual Meeting,Saskatchewan,Canada(1999).
14 Stucki,S. A.,Schuler,A.,Constantinecu,M.,“Coupled CO₂ recovery from the atmosphere and water electrolysis:feasibility of a new process for hydrogen storage”,International Journal of Hydrogen Energy,8,653-663(1995).
15 Koeppel,R.A.,Baiker,A.,“Copper/zirconia catalysts for the synthe-sis of methanol from carbon dioxide:Influence of preparation vari-ables on structural and catalytic properties of catalysts”,Appl.Catal. A:General,84,77-102(1992).

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Electrolytic Regeneration of Decarbonising Potassium Carbonate Solution

Electrolytic Regeneration of Decarbonising Potassium Carbonate Solution

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