Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution

Chinese Journal of Chemical Engineering ›› 2012, Vol. 20 ›› Issue (2): 254-261.

• CATALYSIS, KINETICS AND REACTION ENGINEERING • 上一篇下一篇

Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution

程媛¹, 谢伟淼¹, 姚国新¹, 胡素绢¹, 李国华^1,2,3

1. School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, China;
2. State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Hangzhou 310032, China;
3. Research Center of Nanoscience and Technology, Zhejiang University of Technology, Hangzhou 310032, China

收稿日期:2010-06-09 修回日期:2011-09-06 出版日期:2012-04-28 发布日期:2012-05-02
通讯作者: LI Guohua
基金资助:
Supported by the National Natural Science Foundation of China (21173193);the Natural Science Foundation of Zhejiang Province (Y4080209, Y406094);the Science Plan of Zhejiang Province (2007F70039)

Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution

CHENG Yuan¹, XIE Weimiao¹, YAO Guoxin¹, HU Sujuan¹, LI Guohua^1,2,3

1. School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, China;
2. State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Hangzhou 310032, China;
3. Research Center of Nanoscience and Technology, Zhejiang University of Technology, Hangzhou 310032, China

Received:2010-06-09 Revised:2011-09-06 Online:2012-04-28 Published:2012-05-02
Supported by:
Supported by the National Natural Science Foundation of China (21173193);the Natural Science Foundation of Zhejiang Province (Y4080209, Y406094);the Science Plan of Zhejiang Province (2007F70039)

摘要/Abstract

摘要： Tungsten carbide and zeolite nanocomposite was prepared by combining a mechanochemical approach with a reduction and carbonization approach,using natural zeolite and ammonia metatungstate as precursors.The sample was characterized by X-ray diffraction and scanning electron microscope.The results showed that the crystal phase of the sample is composed of zeolite,monotungsten carbide and bitungsten carbide.The mass percentage and the crystallite diameter of tungsten carbide change along with the reacted time.Its electrocatalytic activity was measured with a microelectrode system with three electrodes.The results show that its electrocatalytic property is related to its crystal phase and the mass percentage of tungsten carbide,and its electrocatalytic activity is connected with the property of electrolyte,in which it is measured.Synergistic effect between tungsten carbide and zeolite is found during electrocatalysis.

关键词: tungsten carbide, zeolite, nanocomposite, electrocatalytic activity, synergistic effect

Abstract: Tungsten carbide and zeolite nanocomposite was prepared by combining a mechanochemical approach with a reduction and carbonization approach,using natural zeolite and ammonia metatungstate as precursors.The sample was characterized by X-ray diffraction and scanning electron microscope.The results showed that the crystal phase of the sample is composed of zeolite,monotungsten carbide and bitungsten carbide.The mass percentage and the crystallite diameter of tungsten carbide change along with the reacted time.Its electrocatalytic activity was measured with a microelectrode system with three electrodes.The results show that its electrocatalytic property is related to its crystal phase and the mass percentage of tungsten carbide,and its electrocatalytic activity is connected with the property of electrolyte,in which it is measured.Synergistic effect between tungsten carbide and zeolite is found during electrocatalysis.

Key words: tungsten carbide, zeolite, nanocomposite, electrocatalytic activity, synergistic effect

程媛, 谢伟淼, 姚国新, 胡素绢, 李国华. Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution[J]. Chinese Journal of Chemical Engineering, 2012, 20(2): 254-261.

CHENG Yuan, XIE Weimiao, YAO Guoxin, HU Sujuan, LI Guohua. Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution[J]. Chin.J.Chem.Eng., 2012, 20(2): 254-261.

参考文献

1 Burstein,G.T.,Barnett,C.J.,Kucernak,R.J.,“Anodic oxidation of methanol using a new base electrocatalyst”,Electrochem.Soc,143 (7),129-134(1996).
2 Fleischmann,R.,Boehm,H.,“Hydrogen oxidation on different tungsten carbide materials”,Electrochim.Acta,20(10),1123-1128 (1977).
3 Sajo,P.N.,Fernandes,J.B.,“Ammonolysis of ethanol on pure and zinc oxide modified HZSM-5 zeolites”,Appl.Catal.A Gen.,205,195-199(2001).
4 Levy,R.B.,Boudar,M.T.,“Platinum-like behavior of tungsten carbide in surface catalysis”,Science,181,547-548(1973).
5 BÕhm,H.,“New non-noble metal anode catalysts for acid fuel cells”,Nature,227,484-485(1970).
6 Xue,H.X.,Song,G.X.,Wang,L.,Chen,J.M.,“Studies of n-pentane reaction on tungsten carbides promoted S₂O₈^2-/ZrO₂ solid superacid catalysts”,Acta Chem.,61,208-212(2004).(in Chinese)
7 Zhang,Y.F.,Lin,W.,Wang,W.F.,Li,J.Q.,“A first principle study on the phase stability and chemical bonding of the 3d transition metal carbides”,Acta Chem.,62,1041-1048(2004).(in Chinese)
8 Xiao,T.,Hanif,A.,York,A.P.E.,Sloan,J.,Green,M.L.H.,“Conversion of n-heptane to LPG and aromatics over Mo2C and W2C catalysts supported on ZSM-5”,Phys.Chem.Chem.Phys.,4(14),3522-3529(2002).
9 Wang,G.J.,Liu,R.Z.,“New type catalyst-molybdenum carbide and tungsten carbide”,Journal of Qingdao University,16(3),51-53 (2001).(in Chinese)
10 Zhu,L.Z.,Cheng,Y.F.,Zhang,Q.Y.,“The catalytic property of (Ni-Co)-WC composite electrode for hydrogen evolution reaction”,Appl.Chem.,16(4),52-54(1999).(in Chinese)
11 Ma,C.A.,Yang,W.Z.,Zhou,Y.H.,Cha,Q.X.,“Research on the waterproof gas-diffusion electrode of tungsten carbide”,J.Phys.Chem.,6(5),622-627(1990).(in Chinese)
12 Palanker,V.S.,Gajyev,R.A.,Sokolsky,D.V.,“Electrocatalytic activity of some carbonized nickel,tungsten and molybdenum compounds”,Electrochim.Acta,22,133-136(1977).
13 Baresel,D.,Gellert,W.,Heidemeyer,J.,Scharner,P.A.,“Electrocatalytic and corrosion behaviour of tungsten carbide in near-neutral pH electrolytes”,Angew.Chem.Int.Ed.,10,194-195(1971).
14 Ramôa,R.F.,Alvarez,F.,Henrigues,C.F.,Lemos,J.,Lopes,M., Ribeiro M.F.,“Structure-activity relationship in zeolites”,J.Mol. Catal.A,96,245-270(1995).
15 Sarbak,Z.,“Structural properties and HDS activity of NiMo catalysts supported on lanthana modified zeolite type X and Y”,Catal. Today,65,293-299(2001).
16 Krishna,K.,Seijger,G.B.F.,van den Bleek,C.M.,Calis,H.P.A., “Preparation of ceria-zeolite catalysts by different techniques and its effect on selective catalytic reduction of NO with NH3 at high space velocities”,Chem.Comm.,2030-2031(2002).
17 Kovacheva,P.,Predoeva,A.,Arishtirova,K.,Vassilev,S.,“Oxidative methylation of toluene with methane using X zeolite catalyst modified with alkali earth oxides”,Appl.Catal.A Gen.,223,121-128 (2002).
18 Kubička,D.,Kumar,N.,M?ki-Arvela,P.,Tiitta,M.,Niemi,V.,Karhu, H.,Salmi,T.,Murzin,D.Y.,“Ring opening of decalin over zeolites: II.Activity and selectivity of platinum-modified zeolites”,J.Catal.,227,313-327(2004).
19 Li,G.H.,Zheng,Y.F.,Ma,C.A.,Li,M.C.,“Preparation of zeolite-supported tungsten carbide and its electrocatalytic property”, Chinese Journal of Catalysis,26(6),443-445(2005).(in Chinese)
20 Ma,C.A.,Huang,Y.,Tong,S.P.,Zhang,W.M.,“The catalytic behavior of tungsten carbide for the electroreduction of p-nitrophenol”, Appl.Chem.,21(7),721-724(2005).
21 Li,G.H.,Ma,C.A.,Zheng,Y.F.,Zhang,W.M.,“Preparation and electrocatalytic activity of hollow global tungsten carbide with mesoporosity”,Micropor.Mesopor.Mater.,85,234-839(2005).

[1]	Baoyu Liu, Feng Xiong, Jianwen Zhang, Manna Wang, Yi Huang, Yanxiong Fang, Jinxiang Dong. Enhanced ortho-selective t–butylation of phenol over sulfonic acid functionalized mesopore MTW zeolites[J]. 中国化学工程学报, 2023, 60(8): 1-7.
[2]	Yingli Li, Zhishuncheng Li, Guangfei Qu, Rui Li, Shuaiyu Liang, Junhong Zhou, Wei Ji, Huiming Tang. Mechanism, behaviour and application of iron nitrate modified carbon nanotube composites for the adsorption of arsenic in aqueous solutions[J]. 中国化学工程学报, 2023, 60(8): 26-36.
[3]	Wenwen Zhang, Zhigang Xue, Liyun Cui, Haoliang Gao, Di Zhao, Rongfei Zhou, Weihong Xing. Synthesis of an IMF zeolite membrane for the separation of xylene isomer[J]. 中国化学工程学报, 2023, 60(8): 205-211.
[4]	Hammad Saulat, Jianhua Yang, Tao Yan, Waseem Raza, Wensen Song, Gaohong He. Tungsten incorporated mobil-type eleven zeolite membranes: Facile synthesis and tuneable wettability for highly efficient separation of oil/water mixtures[J]. 中国化学工程学报, 2023, 60(8): 242-252.
[5]	Meihua Zhu, Xingguo An, Tian Gui, Ting Wu, Yuqin Li, Xiangshu Chen. Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane[J]. 中国化学工程学报, 2023, 59(7): 176-181.
[6]	Tingjun Fu, Ran Wang, Kun Ren, Liangliang Zhang, Zhong Li. Intensified shape selectivity and alkylation reaction for the two-step conversion of methanol aromatization to p-xylene[J]. 中国化学工程学报, 2023, 59(7): 240-250.
[7]	Wei Wang, Romain Lemaire, Ammar Bensakhria, Denis Luart. Thermogravimetric analysis and kinetic modeling of the co-pyrolysis of a bituminous coal and poplar wood[J]. 中国化学工程学报, 2023, 58(6): 53-68.
[8]	Yafei Su, Xuke Zhang, Hui Li, Donglai Peng, Yatao Zhang. In-situ incorporation of halloysite nanotubes with 2D zeolitic imidazolate framework-L based membrane for dye/salt separation[J]. 中国化学工程学报, 2023, 58(6): 103-111.
[9]	Bin Gao, Junwen Chen, Qi Zuo, Hongyan Wang, Wenlin Li. The critical role of Zr in controlling the activity of Pd/Beta on the hydrogenation of phenol to cyclohexanone[J]. 中国化学工程学报, 2023, 57(5): 79-87.
[10]	Shiyong Xing, Yan Cui, Tiefeng Wang, Jinwei He, Minghan Han. Elucidating the effect of oxides on the zeolite catalyzed alkylation of benzene with 1-dodecene[J]. 中国化学工程学报, 2023, 56(4): 126-135.
[11]	Iltaf Khan, Chunjuan Wang, Shoaib Khan, Jinyin Chen, Aftab Khan, Sayyar Ali Shah, Aihua Yuan, Sohail Khan, Mehwish K. Butt, Humaira Asghar. Bio-capped and green synthesis of ZnO/g-C₃N₄ nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation[J]. 中国化学工程学报, 2023, 56(4): 215-224.
[12]	Xingzhong Li, Kunlin Yu, Zibo He, Bo Liu, Rongfei Zhou, Weihong Xing. Improved SSZ-13 thin membranes fabricated by seeded-gel approach for efficient CO₂ capture[J]. 中国化学工程学报, 2023, 56(4): 273-280.
[13]	Jiaxin Wu, Chenxiao Wang, Xianliang Meng, Haichen Liu, Ruizhi Chu, Guoguang Wu, Weisong Li, Xiaofeng Jiang, Deguang Yang. Enhancement of catalytic and anti-carbon deposition performance of SAPO-34/ZSM-5/quartz films in MTA reaction by Si/Al ratio regulation[J]. 中国化学工程学报, 2023, 56(4): 314-324.
[14]	Miaomiao Zhao, Degang Ma, Yu Ye. Adsorption, separation and recovery properties of blocky zeolite-biochar composites for remediation of cadmium contaminated soil[J]. 中国化学工程学报, 2023, 54(2): 272-279.
[15]	Huan Xiang, Huiping Zhang, Pengfei Liu, Ying Yan. Adsorption dynamics of ethane from air in structured fixed beds with different microfibrous composites[J]. 中国化学工程学报, 2023, 53(1): 14-24.

Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution

Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价