CO2 absorption performance in a rotating disk reactor using DBU-glycerol as solvent

doi:10.1016/j.cjche.2019.03.031

摘要/Abstract

摘要： Gas-liquid mass transfer of rotating disk reactor was studied in CO₂ absorption using 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU)-glycerol solution as solvent. Effects of the rotating disk structure and various operation parameters on the CO₂ absorption rate and CO₂ removal efficiency were investigated. The rotating disk with optimal holes is conducive to mass transfer of CO₂ and the formation of thin liquid film at the opening increases the gas-liquid contact area. With the increase of rotating speed, the liquid flow pattern on the rotating disk surface changes from thin film flow to separated streams and creates extra liquid lines attached to the rim of the disk, which leads to a very complicated change on the CO₂ absorption rate and CO₂ removal efficiency. The overall gas-phase mass transfer coefficient increases 138% as the rotating speed increasing from 250 to 1400 r·min^-1. Increasing temperature from 298 to 338 K can enhance the CO₂ absorption rate due to lowering the viscosity of the solvent. The rate-determined step for the absorption is focused on the gas side. The rotating disk reactor can effectively enhance the absorption of CO₂ with viscous DBU-glycerol solvents.

关键词: Gas-liquid flow, Carbon dioxide, Rotating disk reactor, Absorption rate, Viscosity

Abstract: Gas-liquid mass transfer of rotating disk reactor was studied in CO₂ absorption using 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU)-glycerol solution as solvent. Effects of the rotating disk structure and various operation parameters on the CO₂ absorption rate and CO₂ removal efficiency were investigated. The rotating disk with optimal holes is conducive to mass transfer of CO₂ and the formation of thin liquid film at the opening increases the gas-liquid contact area. With the increase of rotating speed, the liquid flow pattern on the rotating disk surface changes from thin film flow to separated streams and creates extra liquid lines attached to the rim of the disk, which leads to a very complicated change on the CO₂ absorption rate and CO₂ removal efficiency. The overall gas-phase mass transfer coefficient increases 138% as the rotating speed increasing from 250 to 1400 r·min^-1. Increasing temperature from 298 to 338 K can enhance the CO₂ absorption rate due to lowering the viscosity of the solvent. The rate-determined step for the absorption is focused on the gas side. The rotating disk reactor can effectively enhance the absorption of CO₂ with viscous DBU-glycerol solvents.

Key words: Gas-liquid flow, Carbon dioxide, Rotating disk reactor, Absorption rate, Viscosity

Hualing Duan, Kun Zhu, Houfang Lu, Changjun Liu, Kejing Wu, Yingying Liu, Bin Liang. CO₂ absorption performance in a rotating disk reactor using DBU-glycerol as solvent[J]. 中国化学工程学报, 2020, 28(1): 104-113.

Hualing Duan, Kun Zhu, Houfang Lu, Changjun Liu, Kejing Wu, Yingying Liu, Bin Liang. CO₂ absorption performance in a rotating disk reactor using DBU-glycerol as solvent[J]. Chinese Journal of Chemical Engineering, 2020, 28(1): 104-113.

参考文献

[1] F.M. Baena-Moreno, M. Rodríguez-Galán, F. Vega, et al., Carbon capture and utilization technologies:A literature review and recent advances, Energy Sources Part A 41(2019) 1403-1433.
[2] J. Tollefson, CO₂ emissions set to spike in 2017, Nature 551(2017) 283.
[3] E.I. Koytsoumpa, C. Bergins, E. Kakaras, The CO₂ economy:Review of CO₂ capture and reuse technologies, J. Supercrit. Fluids 132(2018) 3-16.
[4] B. Zhao, F.Z. Liu, Z. Cui, et al., Enhancing the energetic efficiency of MDEA/PZ-based CO₂ capture technology for a 650 MW power plant:Process improvement, Appl. Energy 185(2017) 362-375.
[5] P.G. Jessop, D.J. Heldebrant, X.W. Li, et al., Green chemistry:reversible nonpolar-topolar solvent, Nature. 436(2005) 1102.
[6] L.J. Fu, Y.Y. Liu, H.F. Lu, et al., Reactivity of hydroxyls and stability of DBU/C₃-alcohol/CO₂ ionic compounds, CIESC J. 66(2015) 4163-4169.
[7] S. Lin, H.F. Lu, Y.Y. Liu, et al., Density studies of 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU)-glycerol and CO₂-DBU-glycerol solutions at temperatures between 288.15 K and 328.15 K, J. Chem. Thermodyn. 123(2018) 8-16.
[8] Y.Y. Liu, S. Lin, H.F. Lu, et al., Studies on surface tension of 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU)-glycerol and CO₂-DBU-glycerol solutions at temperatures from 288.1 K to 323.1 K, J. Chem. Thermodyn. 125(2018) 32-40.
[9] D.J. Heldebrant, C.R. Yonker, P.G. Jessop, et al., Organic liquid CO₂ capture agents with high gravimetric CO₂ capacity, Energy Environ. Sci. 1(2008) 487-493.
[10] P.M. Mathias, K. Afshar, F. Zheng, et al., Improving the regeneration of CO₂-binding organic liquids with a polarity change, Energy Environ. Sci. 6(2013) 2233-2242.
[11] D.J. Heldebrant, P.K. Koech, J.E. Rainbolt, et al., Performance of single-component CO₂-binding organic liquids (CO₂BOLs) for post combustion CO₂ capture, Chem. Eng. J. 171(2011) 794-800.
[12] A. Ostonen, E. Sapei, P. Uusi-Kyyny, et al., Measurements and modeling of CO₂ solubility in 1,8-diazabicyclo-[5.4.0] -undec-7-ene-glycerol solutions, Fluid Phase Equilib. 374(2014) 25-36.
[13] I. Anugwom, P. Mäki-Arvela, P. Virtanen, et al., Switchable ionic liquids (SILs) based on glycerol and acid gases, RSC Adv. 1(2011) 452-457.
[14] S. Lin, Study on thermodynamical properties of 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU)-glycerol and CO₂-DBU-glycerol solutions, (M. Thesis) Sichuan Univ., Chengdu, 2018.
[15] Y.S. Chen, C.C. Lin, H.S. Liu, Mass transfer in a rotating packed bed with viscous Newtonian and non-Newtonian fluids, Ind. Eng. Chem. Res. 44(2005) 1043-1051.
[16] L.L. Zhang, J.X. Wang, Y. Xiang, et al., Absorption of carbon dioxide with ionic liquid in a rotating packed bed contactor:Mass transfer study, Ind. Eng. Chem. Res. 50(2011) 6957-6964.
[17] C.Y. Chiang, Y.S. Chen, M.S. Liang, et al., Absorption of ethanol into water and glycerol/water solution in a rotating packed bed, J. Taiwan Inst. Chem. Eng. 40(2009) 418-423.
[18] B.T. Zhao, W.W. Tao, M. Zhong, et al., Process, performance and modeling of CO₂ capture by chemical absorption using high gravity:A review, Renew. Sust. Energ. Rev. 65(2016) 44-56.
[19] M.H. Wang, A.S. Joel, C. Ramshaw, et al., Process intensification for post-combustion CO₂ capture with chemical absorption:A critical review, Appl. Energy 158(2015) 275-291.
[20] Q.F. Jian, X.H. Deng, S.J. Deng, Experimental studies on gas-liquid two phase fluid dynamics performance in rotating bed using wave form disk plate, Chem. Eng. 26(1998) 6-9.
[21] W.Z. Jiao, Y.Z. Liu, G.S. Qi, Gas pressure drop and mass transfer characteristics in a cross-flow rotating packed bed with porous plate packing, Ind. Eng. Chem. Res. 49(2010) 3732-3740.
[22] F. Haseidl, J. Pottbäcker, O. Hinrichsen, Gas-liquid mass transfer in a rotor-stator spinning disc reactor:Experimental study and correlation, Chem. Eng. Process. Process Intensif. 104(2016) 181-189.
[23] C.C. Lin, C.R. Chu, Feasibility of carbon dioxide absorption by NaOH solution in a rotating packed bed with blade packings, Int. J. Greenh. Gas Control 42(2015) 117-123.
[24] C.C. Lin, Y.W. Kuo, Mass transfer performance of rotating packed beds with blade packings in absorption of CO₂ into MEA solution, Int. J. Heat Mass Transf. 97(2016) 712-718.
[25] N. El Hadri, D.V. Quang, E.L.V. Goetheer, et al., Aqueous amine solution characterization for post-combustion CO₂ capture process, Appl. Energy 185(2017) 1433-1449.
[26] M. Zhang, H.F. Lu, B. Liang, et al., Reaction progress and kinetics of CO₂ with glycerol in the presence of DBU, Chem. Ind. Eng. Prog. 35(2016) 3078-3085.
[27] P. Eisenklam, On ligament formation from spinning discs and cups, Chem. Eng. Sci. 19(1964) 693-694.
[28] B. Bizjan, Š. Brane, M. Hočevar, et al., Ligament-type liquid disintegration by a spinning wheel, Chem. Eng. Sci. 116(2014) 172-182.
[29] D.X. Wang, X. Ling, H. Peng, et al., Experimental investigation of ligament formation dynamics of thin viscous liquid film at spinning disk edge, Ind. Eng. Chem. Res. 55(2016) 9267-9275.
[30] Y. Ouyang, H.K. Zou, X.Y. Gao, et al., Computational fluid dynamics modeling of viscous liquid flow characteristics and end effect in rotating packed bed, Chem. Eng. Process. Process Intensif. 123(2018) 185-194.
[31] S. Munjal, M.P. Dudukovć, P. Ramachandran, Mass-transfer in rotating packed beds-I. Development of gas-liquid and liquid-solid mass-transfer correlations, Chem. Eng. Sci. 44(1989) 2245-2256.
[32] K. Guo, A study on liquid flowing inside the higee rotor, (Ph. D. Thesis) Beijing University of Chemical Technology, Beijing, 1996.
[33] C.C. Lin, Y.H. Lin, C.S. Tan, Evaluation of alkanolamine solutions for carbon dioxide removal in cross-flow rotating packed beds, J. Hazard. Mater. 175(2010) 344-351.
[34] M.P. Sheng, B.C. Sun, F.M. Zhang, et al., Mass-transfer characteristics of the CO₂ absorption process in a rotating packed bed, Energy Fuel 30(2016) 4215-4220.
[35] T.N. Borhani, E. Oko, M.H. Wang, Process modelling and analysis of intensified CO₂ capture using monoethanolamine (MEA) in rotating packed bed absorber, J. Clean. Prod. 204(2018) 1124-1142.
[36] Z. Idris, N.B. Kummamuru, D.A. Eimer, Viscosity measurement of unloaded and CO₂-loaded aqueous monoethanolamine at higher concentrations, J. Mol. Liq. 243(2017) 638-645.
[37] M.P. Sheng, C.X. Xie, X.F. Zeng, et al., Intensification of CO₂ capture using aqueous diethylenetriamine (DETA) solution from simulated flue gas in a rotating packed bed, Fuel 234(2018) 1518-1527.
[38] C.H. Yu, T.W. Wu, C.S. Tan, CO₂ capture by piperazine mixed with non-aqueous solvent diethylene glycol in a rotating packed bed, Int. J. Greenh. Gas Control 19(2013) 503-509.
[39] J. Lee, T. Kolawole, P. Attidekou, Carbon capture from a simulated flue gas using a rotating packed bed adsorber and mono ethanol amine (MEA), Energy Procedia 114(2017) 1834-1840.

CO₂ absorption performance in a rotating disk reactor using DBU-glycerol as solvent

CO₂ absorption performance in a rotating disk reactor using DBU-glycerol as solvent

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Chaojie Li, Xianxin Fang, Meiling Sun, Jihai Duan, Weiwen Wang. Study on two-phase cloud dispersion from liquefied CO₂ release[J]. 中国化学工程学报, 2023, 60(8): 37-45.
[2]	Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang. Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling[J]. 中国化学工程学报, 2023, 59(7): 105-117.
[3]	Hongwei Liang, Wenling Li, Zisheng Feng, Jianming Chen, Guangwen Chu, Yang Xiang. Numerical simulation of gas-liquid flow in the bubble column using Wray-Agarwal turbulence model coupled with population balance model[J]. 中国化学工程学报, 2023, 58(6): 205-223.
[4]	Lusheng Zhai, Bo Xu, Haiyan Xia, Ningde Jin. Simultaneous measurement of velocity profile and liquid film thickness in horizontal gas-liquid slug flow by using ultrasonic Doppler method[J]. 中国化学工程学报, 2023, 58(6): 323-340.
[5]	Tatyana P. Adamova, Sergey S. Skiba, Andrey Yu. Manakov, Sergey Y. Misyura. Growth rate of CO₂ hydrate film on water–oil and water–gaseous CO₂ interface[J]. 中国化学工程学报, 2023, 56(4): 266-272.
[6]	Songsong Wang, Hong Li, Changyuan Tao, Renlong Liu, Yundong Wang, Zuohua Liu. Study on cavern evolution and performance of three mixers in agitation of yield-pseudoplastic fluids[J]. 中国化学工程学报, 2023, 55(3): 111-122.
[7]	Bowen Jiang, Jia Liu, Guoqiang Yang, Zhibing Zhang. Efficient conversion of CO₂ into cyclic carbonates under atmospheric by halogen and metal-free poly(ionic liquid)s[J]. 中国化学工程学报, 2023, 55(3): 202-211.
[8]	Mingdong Sun, Dongxin Pan, Tingting Ye, Jing Gu, Yu Zhou, Jun Wang. Ionic porous polyamide derived N-doped carbon towards highly selective electroreduction of CO₂[J]. 中国化学工程学报, 2023, 55(3): 212-221.
[9]	Mengge Shang, Jing Zhang, Jinqiang Sun, Shimo Yu, Feng Hua, Xiaoxu Xuan, Xun Sun, Serguei Filatov, Xibin Yi. Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption[J]. 中国化学工程学报, 2023, 54(2): 36-43.
[10]	Xianglin Liu, Minjie Xu, Chenxi Cao, Zixu Yang, Jing Xu. Effects of zinc on χ-Fe₅C₂ for carbon dioxide hydrogenation to olefins: Insights from experimental and density function theory calculations[J]. 中国化学工程学报, 2023, 54(2): 206-214.
[11]	Zhongyao Zhang, Ming Gao, Xiaopeng Chen, Xiaojie Wei, Jiezhen Liang, Chenghong Wu, Linlin Wang. The Joule–Thomson effect of (CO₂ + H₂) binary system relevant to gas switching reforming with carbon capture and storage (CCS)[J]. 中国化学工程学报, 2023, 54(2): 215-231.
[12]	Yifeng Chen, Hang Yu, Jingjing Chen, Xiaohua Lu, Xiaoyan Ji. Viscous behavior of 1-hexyl-methylimidazolium bis(trifluoromethylsulfonyl)imide/titanium dioxide/polyethylene glycol[J]. 中国化学工程学报, 2023, 54(2): 280-287.
[13]	Baodong Zhao, Yinglei Wang, Fulei Gao, Yajing Liu, Weixiao Liu, Feng Ding. Understanding the alkyl effect of geminal dinitropropyl ester energetic plasticizers on hydroxyl terminated polybutadiene (HTPB): Simultaneous tuning on low temperature behavior and processability[J]. 中国化学工程学报, 2023, 54(2): 364-371.
[14]	Vladimir S. Derevschikov, Janna V. Veselovskaya, Anton S. Shalygin, Dmitry A. Yatsenko, Andrey Z. Sheshkovas, Oleg N. Martyanov. Operating limits and features of direct air capture on K₂CO₃/ZrO₂ composite sorbent[J]. 中国化学工程学报, 2022, 46(6): 11-20.
[15]	Jipeng Dong, Fei Wang, Guanghui Chen, Shougui Wang, Cailin Ji, Fei Gao. Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture[J]. 中国化学工程学报, 2022, 46(6): 207-213.