Solubility measurement and thermodynamic properties of sulfamonomethoxine in pure solvents and sulfamonomethoxine hydrate in acetone + water binary solvent at different temperature

doi:10.1016/j.cjche.2020.10.037

中国化学工程学报 ›› 2021, Vol. 38 ›› Issue (10): 196-204.DOI: 10.1016/j.cjche.2020.10.037

• Chemical Engineering Thermodynamics • 上一篇下一篇

Solubility measurement and thermodynamic properties of sulfamonomethoxine in pure solvents and sulfamonomethoxine hydrate in acetone + water binary solvent at different temperature

Yanmin Shen, Wenju Liu, Paifeng Shi, Chao Wang

School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China

收稿日期:2020-08-10 修回日期:2020-09-26 出版日期:2021-10-28 发布日期:2021-12-02
通讯作者: Wenju Liu
基金资助:
The authors would like to thank the Doctoral Foundation of Henan University of Technology in China (2016BS025), the Science Foundation of Henan University of Technology in China (2017RCJH09, 2017QNJH29), Science Foundation of Henan Province in China (202102310208) for their financial assistance in this project.

Solubility measurement and thermodynamic properties of sulfamonomethoxine in pure solvents and sulfamonomethoxine hydrate in acetone + water binary solvent at different temperature

Yanmin Shen, Wenju Liu, Paifeng Shi, Chao Wang

School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China

Received:2020-08-10 Revised:2020-09-26 Online:2021-10-28 Published:2021-12-02
Contact: Wenju Liu
Supported by:
The authors would like to thank the Doctoral Foundation of Henan University of Technology in China (2016BS025), the Science Foundation of Henan University of Technology in China (2017RCJH09, 2017QNJH29), Science Foundation of Henan Province in China (202102310208) for their financial assistance in this project.

摘要/Abstract

摘要： The experimental solubility of sulfamonomethoxine in six different pure solvents (methanol, ethanol, 1-propanol, l-butanol, ethyl acetate and acetone) and sulfamonomethoxine hydrate in acetone + water mixture solvents were measured from 294.55 K to 362.15 K by a laser dynamic method under atmospheric pressure. Experimental results indicated that the solubility data of sulfamonomethoxine increased with temperature increasing in pure solvents and the solubility followed this order: acetone > methanol > ethanol > ethyl acetate > 1-propanol > 1-butanol, but solubility in ethyl acetate was not affected significantly by temperature. In acetone + water mixture solvent, the solubility of sulfamonomethoxine hydrate increased with temperature and the acetone concentration. Thermodynamic equations were applied to correlate solubility data of sulfamonomethoxine and sulfamonomethoxine hydrate including the modified Apelblat equation, λh equation, Wilson equation, NRTL equation, Van’t Hoff-Jouyban Acree equation and modified Apel-Jouyban-Acree equation. Furthermore, thermodynamic properties ΔG_d, ΔH_d and ΔS_d of sulfamonomethoxine and sulfamonomethoxine hydrate in dissolution process were obtained and discussed with the modified Van’t Hoff equation and Gibbs equation.

关键词: Solubility, Sulfamonomethoxine, Sulfamonomethoxine hydrate, Thermodynamic properties

Abstract: The experimental solubility of sulfamonomethoxine in six different pure solvents (methanol, ethanol, 1-propanol, l-butanol, ethyl acetate and acetone) and sulfamonomethoxine hydrate in acetone + water mixture solvents were measured from 294.55 K to 362.15 K by a laser dynamic method under atmospheric pressure. Experimental results indicated that the solubility data of sulfamonomethoxine increased with temperature increasing in pure solvents and the solubility followed this order: acetone > methanol > ethanol > ethyl acetate > 1-propanol > 1-butanol, but solubility in ethyl acetate was not affected significantly by temperature. In acetone + water mixture solvent, the solubility of sulfamonomethoxine hydrate increased with temperature and the acetone concentration. Thermodynamic equations were applied to correlate solubility data of sulfamonomethoxine and sulfamonomethoxine hydrate including the modified Apelblat equation, λh equation, Wilson equation, NRTL equation, Van’t Hoff-Jouyban Acree equation and modified Apel-Jouyban-Acree equation. Furthermore, thermodynamic properties ΔG_d, ΔH_d and ΔS_d of sulfamonomethoxine and sulfamonomethoxine hydrate in dissolution process were obtained and discussed with the modified Van’t Hoff equation and Gibbs equation.

Key words: Solubility, Sulfamonomethoxine, Sulfamonomethoxine hydrate, Thermodynamic properties

Yanmin Shen, Wenju Liu, Paifeng Shi, Chao Wang. Solubility measurement and thermodynamic properties of sulfamonomethoxine in pure solvents and sulfamonomethoxine hydrate in acetone + water binary solvent at different temperature[J]. 中国化学工程学报, 2021, 38(10): 196-204.

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Solubility measurement and thermodynamic properties of sulfamonomethoxine in pure solvents and sulfamonomethoxine hydrate in acetone + water binary solvent at different temperature

Solubility measurement and thermodynamic properties of sulfamonomethoxine in pure solvents and sulfamonomethoxine hydrate in acetone + water binary solvent at different temperature

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