Measurement methods of particle size distribution in emulsion polymerization

doi:10.1016/j.cjche.2021.03.007

中国化学工程学报 ›› 2021, Vol. 39 ›› Issue (11): 1-15.DOI: 10.1016/j.cjche.2021.03.007

• Reviews • 下一篇

Measurement methods of particle size distribution in emulsion polymerization

Shuaifeng Zhang^1,2, Qinghua Zhang^1,2, Jianzhuang Shang³, Zaisha Mao¹, Chao Yang^1,2

1 CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China;
3 China National Petroleum & Chemical Planning Institute, Beijing 100029, China

收稿日期:2020-12-20 修回日期:2021-03-02 出版日期:2021-11-28 发布日期:2021-12-27
通讯作者: Qinghua Zhang, Chao Yang
基金资助:
The National Key Research and Development Program (2020YFA0906804), the National Natural Science Foundation of China (22078325, 22035007, 91934301), the NSFC-EU project (31961133018) and the Special Project of Strategic Leading Science and Technology, CAS (XDC06010302) are gratefully acknowledged.

Measurement methods of particle size distribution in emulsion polymerization

Shuaifeng Zhang^1,2, Qinghua Zhang^1,2, Jianzhuang Shang³, Zaisha Mao¹, Chao Yang^1,2

1 CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China;
3 China National Petroleum & Chemical Planning Institute, Beijing 100029, China

Received:2020-12-20 Revised:2021-03-02 Online:2021-11-28 Published:2021-12-27
Contact: Qinghua Zhang, Chao Yang
Supported by:
The National Key Research and Development Program (2020YFA0906804), the National Natural Science Foundation of China (22078325, 22035007, 91934301), the NSFC-EU project (31961133018) and the Special Project of Strategic Leading Science and Technology, CAS (XDC06010302) are gratefully acknowledged.

摘要/Abstract

摘要： The particle size distribution of polymer always develops in emulsion polymerization systems, and certain key phenomena/mechanisms as well as properties of the final product are significantly affected by this distribution. This review mainly focuses on the measurement methods of particle size distribution rather than average particle size during the emulsion polymerization process, including the existing off-line, on-line, and in-line measurement methods. Moreover, the principle, resolution, performance, advantages, and drawbacks of various methods for evaluating particle size distribution are contrasted and illustrated. Besides, several possible development directions or solutions of the in-line measurement technology are explored

关键词: Particle size distribution, Emulsion polymerization, Off-line, On-line, In-line

Abstract: The particle size distribution of polymer always develops in emulsion polymerization systems, and certain key phenomena/mechanisms as well as properties of the final product are significantly affected by this distribution. This review mainly focuses on the measurement methods of particle size distribution rather than average particle size during the emulsion polymerization process, including the existing off-line, on-line, and in-line measurement methods. Moreover, the principle, resolution, performance, advantages, and drawbacks of various methods for evaluating particle size distribution are contrasted and illustrated. Besides, several possible development directions or solutions of the in-line measurement technology are explored

Key words: Particle size distribution, Emulsion polymerization, Off-line, On-line, In-line

Shuaifeng Zhang, Qinghua Zhang, Jianzhuang Shang, Zaisha Mao, Chao Yang. Measurement methods of particle size distribution in emulsion polymerization[J]. 中国化学工程学报, 2021, 39(11): 1-15.

Shuaifeng Zhang, Qinghua Zhang, Jianzhuang Shang, Zaisha Mao, Chao Yang. Measurement methods of particle size distribution in emulsion polymerization[J]. Chinese Journal of Chemical Engineering, 2021, 39(11): 1-15.

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Measurement methods of particle size distribution in emulsion polymerization

Measurement methods of particle size distribution in emulsion polymerization

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