A facile preparation of hausmannite as a high-performance catalyst for toluene combustion

doi:10.1016/j.cjche.2021.02.026

中国化学工程学报 ›› 2022, Vol. 44 ›› Issue (4): 392-401.DOI: 10.1016/j.cjche.2021.02.026

A facile preparation of hausmannite as a high-performance catalyst for toluene combustion

Qi Liu, Gao Cheng, Ming Sun, Weixiong Yu, Xiaohong, Zeng, Shichang Tang, Yongfeng li, Lin Yu

School of Chemical Engineering and Light Industry, Key Laboratory of Clean Chemistry Technology of Guangdong Regular Higher Education, Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong University of Technology, Guangzhou 510006, China

收稿日期:2020-12-09 修回日期:2021-02-07 出版日期:2022-04-28 发布日期:2022-06-18
通讯作者: Lin Yu,E-mail:gych@gdut.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos. 21306026, 21576054), Natural Science Foundation of Guangdong Province (No. 2018A030310563), and the Foundation of Higher Education of Guangdong Province (2018KZDXM031).

A facile preparation of hausmannite as a high-performance catalyst for toluene combustion

Qi Liu, Gao Cheng, Ming Sun, Weixiong Yu, Xiaohong, Zeng, Shichang Tang, Yongfeng li, Lin Yu

School of Chemical Engineering and Light Industry, Key Laboratory of Clean Chemistry Technology of Guangdong Regular Higher Education, Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong University of Technology, Guangzhou 510006, China

Received:2020-12-09 Revised:2021-02-07 Online:2022-04-28 Published:2022-06-18
Contact: Lin Yu,E-mail:gych@gdut.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 21306026, 21576054), Natural Science Foundation of Guangdong Province (No. 2018A030310563), and the Foundation of Higher Education of Guangdong Province (2018KZDXM031).

摘要/Abstract

摘要： Mesoporous transition metal oxide catalysts are well-used in the elimination of volatile organic compounds. In this study, we developed an efficient method for the preparation of mesoporous-Mn₃O₄ (m-Mn₃O₄) without the use of templates or surfactants. In this method, KCl protects oxygen defects on the surface of fresh Mn₃O₄ crystallites. m-Mn₃O₄ shows higher ameliorative catalytic activity than bulk-Mn₃O₄ (b-Mn₃O₄) and calcined-Mn₃O₄ (c-Mn₃O₄), achieving toluene catalytic oxidation of T₁₀ and T₉₀ (the temperature at a conversion rate of about 10% and 90%) at 191 ℃ and 230 ℃, respectively (WHSV = 40,000 ml·g^-1·h^-1). Based on various characterizations, the prepared m-Mn₃O₄ has large specific surface area and abundant oxygen defects, and thus can provide more surface active sites, which give it superior toluene combustion activity.

关键词: Catalysis, Nanomaterials, Environment, Toluene, Solvents, Mn₃O₄

Abstract: Mesoporous transition metal oxide catalysts are well-used in the elimination of volatile organic compounds. In this study, we developed an efficient method for the preparation of mesoporous-Mn₃O₄ (m-Mn₃O₄) without the use of templates or surfactants. In this method, KCl protects oxygen defects on the surface of fresh Mn₃O₄ crystallites. m-Mn₃O₄ shows higher ameliorative catalytic activity than bulk-Mn₃O₄ (b-Mn₃O₄) and calcined-Mn₃O₄ (c-Mn₃O₄), achieving toluene catalytic oxidation of T₁₀ and T₉₀ (the temperature at a conversion rate of about 10% and 90%) at 191 ℃ and 230 ℃, respectively (WHSV = 40,000 ml·g^-1·h^-1). Based on various characterizations, the prepared m-Mn₃O₄ has large specific surface area and abundant oxygen defects, and thus can provide more surface active sites, which give it superior toluene combustion activity.

Key words: Catalysis, Nanomaterials, Environment, Toluene, Solvents, Mn₃O₄

Qi Liu, Gao Cheng, Ming Sun, Weixiong Yu, Xiaohong, Zeng, Shichang Tang, Yongfeng li, Lin Yu. A facile preparation of hausmannite as a high-performance catalyst for toluene combustion[J]. 中国化学工程学报, 2022, 44(4): 392-401.

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A facile preparation of hausmannite as a high-performance catalyst for toluene combustion

A facile preparation of hausmannite as a high-performance catalyst for toluene combustion

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