SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2024, Vol. 73 ›› Issue (9): 176-188.DOI: 10.1016/j.cjche.2024.05.025

• • 上一篇    下一篇

Thermal conductivity of hydrate and effective thermal conductivity of hydrate-bearing sediment

Cunning Wang1, Xingxun Li1, Qingping Li2, Guangjin Chen1, Changyu Sun1   

  1. 1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing, Beijing 102249, China;
    2. State Key Laboratory of Natural Gas Hydrate, CNOOC Research Institute Co., Ltd., Beijing 100027, China
  • 收稿日期:2023-11-23 修回日期:2024-05-25 接受日期:2024-05-27 出版日期:2024-11-21 发布日期:2024-07-04
  • 通讯作者: Xingxun Li,E-mail:lixingxun@cup.edu.cn
  • 基金资助:
    This work was supported by the National Natural Science Foundation of China (U19B2005, 21808238, U20B6005, 22127812), the State Key Laboratory of Heavy Oil Processing, China University of Petroleum and the National Key Research and Development Program of China (2021YFC2800902).

Thermal conductivity of hydrate and effective thermal conductivity of hydrate-bearing sediment

Cunning Wang1, Xingxun Li1, Qingping Li2, Guangjin Chen1, Changyu Sun1   

  1. 1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing, Beijing 102249, China;
    2. State Key Laboratory of Natural Gas Hydrate, CNOOC Research Institute Co., Ltd., Beijing 100027, China
  • Received:2023-11-23 Revised:2024-05-25 Accepted:2024-05-27 Online:2024-11-21 Published:2024-07-04
  • Contact: Xingxun Li,E-mail:lixingxun@cup.edu.cn
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (U19B2005, 21808238, U20B6005, 22127812), the State Key Laboratory of Heavy Oil Processing, China University of Petroleum and the National Key Research and Development Program of China (2021YFC2800902).

摘要: The research on the thermal property of the hydrate has recently made great progress, including the understanding of hydrate thermal conductivity and effective thermal conductivity (ETC) of hydrate-bearing sediment. The thermal conductivity of hydrate is of great significance for the hydrate-related field, such as the natural gas hydrate exploitation and prevention of the hydrate plugging in oil or gas pipelines. In order to obtain a comprehensive understanding of the research progress of the hydrate thermal conductivity and the ETC of hydrate-bearing sediment, the literature on the studies of the thermal conductivity of hydrate and the ETC of hydrate-bearing sediment were summarized and reviewed in this study. Firstly, experimental studies of the reported measured values and the temperature dependence of the thermal conductivity of hydrate were discussed and reviewed. Secondly, the studies of the experimental measurements of the ETC of hydrate-bearing sediment and the effects of temperature, porosity, hydrate saturation, water saturation, thermal conductivity of porous medium, phase change, and other factors on the ETC of hydrate-bearing sediment were discussed and reviewed. Thirdly, the research progress of modeling on the ETC of the hydrate-bearing sediment was reviewed. The thermal conductivity determines the heat transfer capacity of the hydrate reservoir and directly affects the hydrate exploitation efficiency. Future efforts need to be devoted to obtain experimental data of the ETC of hydrate reservoirs and establish models to accurately predict the ETC of hydrate-bearing sediment.

关键词: Hydrate, Thermal conductivity, Hydrate-bearing sediment, Preparation method, Effective thermal conductivity, Model

Abstract: The research on the thermal property of the hydrate has recently made great progress, including the understanding of hydrate thermal conductivity and effective thermal conductivity (ETC) of hydrate-bearing sediment. The thermal conductivity of hydrate is of great significance for the hydrate-related field, such as the natural gas hydrate exploitation and prevention of the hydrate plugging in oil or gas pipelines. In order to obtain a comprehensive understanding of the research progress of the hydrate thermal conductivity and the ETC of hydrate-bearing sediment, the literature on the studies of the thermal conductivity of hydrate and the ETC of hydrate-bearing sediment were summarized and reviewed in this study. Firstly, experimental studies of the reported measured values and the temperature dependence of the thermal conductivity of hydrate were discussed and reviewed. Secondly, the studies of the experimental measurements of the ETC of hydrate-bearing sediment and the effects of temperature, porosity, hydrate saturation, water saturation, thermal conductivity of porous medium, phase change, and other factors on the ETC of hydrate-bearing sediment were discussed and reviewed. Thirdly, the research progress of modeling on the ETC of the hydrate-bearing sediment was reviewed. The thermal conductivity determines the heat transfer capacity of the hydrate reservoir and directly affects the hydrate exploitation efficiency. Future efforts need to be devoted to obtain experimental data of the ETC of hydrate reservoirs and establish models to accurately predict the ETC of hydrate-bearing sediment.

Key words: Hydrate, Thermal conductivity, Hydrate-bearing sediment, Preparation method, Effective thermal conductivity, Model