SCI和EI收录∣中国化工学会会刊

›› 2008, Vol. 16 ›› Issue (3): 441-445.

• • 上一篇    下一篇

Performance of Nanofiltration and Reverse Osmosis Membranes in Metal Effluent Treatment

刘飞妮1, 张国亮1, 孟琴2, 章宏梓2   

  1. 1. College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310014, China;
    2. College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China
  • 收稿日期:2007-09-24 修回日期:2008-03-20 出版日期:2008-06-28 发布日期:2008-06-28
  • 通讯作者: ZHANG Guoliang ,E-mail:guoliangz@zjut.edu.cn
  • 基金资助:
    Supported by the National Natural Science Foundation of China (20476096,20776133);Zhejiang Provincial Bureau of Science & Technology (2005C33040);Bureau of Education (Key Discipline of Environmental Engineering 56310503014)

Performance of Nanofiltration and Reverse Osmosis Membranes in Metal Effluent Treatment

LIU Feini1, ZHANG Guoliang1, MENG Qin2, ZHANG Hongzi2   

  1. 1. College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310014, China;
    2. College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2007-09-24 Revised:2008-03-20 Online:2008-06-28 Published:2008-06-28
  • Supported by:
    Supported by the National Natural Science Foundation of China (20476096,20776133);Zhejiang Provincial Bureau of Science & Technology (2005C33040);Bureau of Education (Key Discipline of Environmental Engineering 56310503014)

摘要: The performance of different nanofiltration(NF)and reverse osmosis(RO)membranes was studied in treating the toxic metal effluent from metallurgical industry.The characteristics and filtration behavior of the processes including the wastewater flux,salt rejection and ion rejection versus operating pressure were evaluated.Then the wastewater flux of RO membrane was compared with theoretical calculation using mass transfer models,and good consistency was observed.It was found that a high rejection rate more than 95% of metal ions and a low Chemical Oxygen Demand(COD)value of 10 mg·L-1 in permeate could be achieved using the RO composite membrane,while the NF rejection of the salt could be up to 78.9% and the COD value in the permeate was 35 mg·L-1. The results showed that the product water by both NF and RO desalination satisfied the State Reutilization Qualification,but NF would be more suitable for large-scale industrial practice,which offered significantly higher permeate flux at low operating pressure.

关键词: nanofiltration, reverse osmosis, metal effluent, reuse

Abstract: The performance of different nanofiltration(NF)and reverse osmosis(RO)membranes was studied in treating the toxic metal effluent from metallurgical industry.The characteristics and filtration behavior of the processes including the wastewater flux,salt rejection and ion rejection versus operating pressure were evaluated.Then the wastewater flux of RO membrane was compared with theoretical calculation using mass transfer models,and good consistency was observed.It was found that a high rejection rate more than 95% of metal ions and a low Chemical Oxygen Demand(COD)value of 10 mg·L-1 in permeate could be achieved using the RO composite membrane,while the NF rejection of the salt could be up to 78.9% and the COD value in the permeate was 35 mg·L-1. The results showed that the product water by both NF and RO desalination satisfied the State Reutilization Qualification,but NF would be more suitable for large-scale industrial practice,which offered significantly higher permeate flux at low operating pressure.

Key words: nanofiltration, reverse osmosis, metal effluent, reuse