Ceramic Supported PDMS and PEGDA Composite Membranes for CO2 Separation

doi:10.1016/S1004-9541(13)60478-4

摘要/Abstract

摘要： Composite membranes have attracted increasing attentions owing to their potential applications for CO₂ separation. In this work, ceramic supported polydimethylsiloxane (PDMS) and poly (ethylene glycol) diacrylate (PEGDA) composite membranes were prepared. The microstructure and physicochemical properties of the composite membranes were characterized. Preparation conditions were systematically optimized. The gas separation performance of the as-prepared membranes was studied by pure gas and binary gas permeation measurement of CO₂, N₂ and H₂. Experiments showed that PDMS, as silicone rubber, exhibited larger permeance and lower separation factors. Conversely, PEGDA composite membrane presented smaller gas permeance but higher ideal selectivity for CO₂/N₂. Compared to the performance of those membranes using polymeric supports or freestanding membranes, the two kinds of ceramic supported composite membranes exhibited higher gas permeance and acceptable selectivity. Therefore, the ceramic supported composite membrane can be expected as a candidate for CO₂ separation from light gases.

关键词: polydimethylsiloxane, PEGDA, ceramic support, composite membrane, CO₂ separation

Abstract: Composite membranes have attracted increasing attentions owing to their potential applications for CO₂ separation. In this work, ceramic supported polydimethylsiloxane (PDMS) and poly (ethylene glycol) diacrylate (PEGDA) composite membranes were prepared. The microstructure and physicochemical properties of the composite membranes were characterized. Preparation conditions were systematically optimized. The gas separation performance of the as-prepared membranes was studied by pure gas and binary gas permeation measurement of CO₂, N₂ and H₂. Experiments showed that PDMS, as silicone rubber, exhibited larger permeance and lower separation factors. Conversely, PEGDA composite membrane presented smaller gas permeance but higher ideal selectivity for CO₂/N₂. Compared to the performance of those membranes using polymeric supports or freestanding membranes, the two kinds of ceramic supported composite membranes exhibited higher gas permeance and acceptable selectivity. Therefore, the ceramic supported composite membrane can be expected as a candidate for CO₂ separation from light gases.

Key words: polydimethylsiloxane, PEGDA, ceramic support, composite membrane, CO₂ separation

刘赛男, 刘公平, 卫旺, 相里粉娟, 金万勤. Ceramic Supported PDMS and PEGDA Composite Membranes for CO₂ Separation[J]. Chinese Journal of Chemical Engineering, 2013, 21(4): 348-356.

LIU Sainan, LIU Gongping, WEI Wang, XIANGLI Fenjuan, JIN Wanqin . Ceramic Supported PDMS and PEGDA Composite Membranes for CO₂ Separation[J]. Chin.J.Chem.Eng., 2013, 21(4): 348-356.

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Ceramic Supported PDMS and PEGDA Composite Membranes for CO₂ Separation

Ceramic Supported PDMS and PEGDA Composite Membranes for CO₂ Separation

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