Removal of Cu2+ from Aqueous Solutions Using Na-A Zeolite from Oil Shale Ash

doi:10.1016/S1004-9541(13)60529-7

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (9): 974-982.DOI: 10.1016/S1004-9541(13)60529-7

Removal of Cu²⁺ from Aqueous Solutions Using Na-A Zeolite from Oil Shale Ash

包维维¹, 刘璐¹, 邹海峰¹, 甘树才¹, 徐学纯², 季桂娟¹, 高桂梅¹, 郑克岩¹

1 College of Chemistry, Jilin University, Changchun 130012, China;
2 College of Earth Science, Jilin University, Changchun 130026, China

收稿日期:2012-08-22 修回日期:2012-12-03 出版日期:2013-09-28 发布日期:2013-10-01
通讯作者: ZOU Haifeng, GAN Shucai
基金资助:
Supported by the National Innovative Projects with Cooperation in terms of Production, Study and Research (OSR-05), and the National Science and Technology Major Projects (2008ZX05018-005)

Removal of Cu²⁺ from Aqueous Solutions Using Na-A Zeolite from Oil Shale Ash

BAO Weiwei¹, LIU Lu¹, ZOU Haifeng¹, GAN Shucai¹, XU Xuechun², JI Guijuan¹, GAO Guimei¹, Zheng Keyan¹

1 College of Chemistry, Jilin University, Changchun 130012, China;
2 College of Earth Science, Jilin University, Changchun 130026, China

Received:2012-08-22 Revised:2012-12-03 Online:2013-09-28 Published:2013-10-01
Contact: ZOU Haifeng, GAN Shucai
Supported by:
Supported by the National Innovative Projects with Cooperation in terms of Production, Study and Research (OSR-05), and the National Science and Technology Major Projects (2008ZX05018-005)

摘要/Abstract

摘要： Na-A zeolite was synthesized using oil shale ash (OSA), which is a solid by-product of oil shale processing. The samples were characterized by various techniques, such as scanning electron microscopy, X-ray diffraction and Brunauer Emmet Teller method. The batch isothermal equilibrium adsorption experiments were performed to evaluate the ability of Na-A zeolite for removal of Cu(II) from aqueous solutions. The effects of operating parameters, such as concentration of copper solutions, adsorbent dosages, pH value of solutions and temperature, on the adsorption efficiency were investigated. The equilibrium adsorption data were fitted with Langmuir and Freundlich models. The maximum adsorption capacity of Na-A zeolite obtained from the Langmuir adsorption isotherm is 156.7 mg·g^-1 of Cu(II). The increase of pH level in the adsorption process suggests that the uptake of heavy metals on the zeolite follows an ion exchange mechanism. The batch kinetic data fit the pseudo-second order equation well. The thermodynamic parameters, such as changes in Gibbs free energy (DG), enthalpy (DH) and entropy (DS), are used to predict the nature of the adsorption process. The negative DG values at different temperatures confirm that the adsorption processes are spontaneous.

关键词: oil shale ash, zeolite, copper removal, adsorption isotherm

Abstract: Na-A zeolite was synthesized using oil shale ash (OSA), which is a solid by-product of oil shale processing. The samples were characterized by various techniques, such as scanning electron microscopy, X-ray diffraction and Brunauer Emmet Teller method. The batch isothermal equilibrium adsorption experiments were performed to evaluate the ability of Na-A zeolite for removal of Cu(II) from aqueous solutions. The effects of operating parameters, such as concentration of copper solutions, adsorbent dosages, pH value of solutions and temperature, on the adsorption efficiency were investigated. The equilibrium adsorption data were fitted with Langmuir and Freundlich models. The maximum adsorption capacity of Na-A zeolite obtained from the Langmuir adsorption isotherm is 156.7 mg·g^-1 of Cu(II). The increase of pH level in the adsorption process suggests that the uptake of heavy metals on the zeolite follows an ion exchange mechanism. The batch kinetic data fit the pseudo-second order equation well. The thermodynamic parameters, such as changes in Gibbs free energy (DG), enthalpy (DH) and entropy (DS), are used to predict the nature of the adsorption process. The negative DG values at different temperatures confirm that the adsorption processes are spontaneous.

Key words: oil shale ash, zeolite, copper removal, adsorption isotherm

包维维, 刘璐, 邹海峰, 甘树才, 徐学纯, 季桂娟, 高桂梅, 郑克岩. Removal of Cu²⁺ from Aqueous Solutions Using Na-A Zeolite from Oil Shale Ash[J]. Chinese Journal of Chemical Engineering, 2013, 21(9): 974-982.

BAO Weiwei, LIU Lu, ZOU Haifeng, GAN Shucai, XU Xuechun, JI Guijuan, GAO Guimei, Zheng Keyan. Removal of Cu²⁺ from Aqueous Solutions Using Na-A Zeolite from Oil Shale Ash[J]. Chin.J.Chem.Eng., 2013, 21(9): 974-982.

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Removal of Cu²⁺ from Aqueous Solutions Using Na-A Zeolite from Oil Shale Ash

Removal of Cu²⁺ from Aqueous Solutions Using Na-A Zeolite from Oil Shale Ash

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