SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (7): 1666-1673.DOI: 10.1016/j.cjche.2019.03.012

• Biotechnology and Bioengineering • 上一篇    下一篇

Co-pyrolysis of bituminous coal and biomass in a pressured fluidized bed

Yong Huang1,2,3,4,5,6, Ningbo Wang2, Qiaoxia Liu2, Wusheng Wang2, Xiaoxun Ma1,3,4,5,6   

  1. 1 School of Chemical Engineering, Northwest University, 229 North Taibai Road, Xi'an 710069, China;
    2 Hydrocarbon High-efficiency Utilization Technology Research Center of Yanchang Petroleum(Group) Co. Ltd., Xi'an 710075, China;
    3 Chemical Engineering Research Center of the Ministry of Education(MOE) for Advanced Use Technology of Shanbei Energy, Xi'an 710069, China;
    4 Shaanxi Research Center of Engineering Technology for Clean Coal Conversion, Xi'an 710069, China;
    5 Collaborative Innovation Center for Development of Energy and Chemical Industry in Northern Shaanxi, Xi'an 710069, China;
    6 International Scientific and Technological Cooperation Base of the Ministry of Science and Technology(MOST) for Clean Utilization of Hydrocarbon Resources, Xi'an 710069, China
  • 收稿日期:2018-10-08 出版日期:2019-07-28 发布日期:2019-10-14
  • 通讯作者: Xiaoxun Ma

Co-pyrolysis of bituminous coal and biomass in a pressured fluidized bed

Yong Huang1,2,3,4,5,6, Ningbo Wang2, Qiaoxia Liu2, Wusheng Wang2, Xiaoxun Ma1,3,4,5,6   

  1. 1 School of Chemical Engineering, Northwest University, 229 North Taibai Road, Xi'an 710069, China;
    2 Hydrocarbon High-efficiency Utilization Technology Research Center of Yanchang Petroleum(Group) Co. Ltd., Xi'an 710075, China;
    3 Chemical Engineering Research Center of the Ministry of Education(MOE) for Advanced Use Technology of Shanbei Energy, Xi'an 710069, China;
    4 Shaanxi Research Center of Engineering Technology for Clean Coal Conversion, Xi'an 710069, China;
    5 Collaborative Innovation Center for Development of Energy and Chemical Industry in Northern Shaanxi, Xi'an 710069, China;
    6 International Scientific and Technological Cooperation Base of the Ministry of Science and Technology(MOST) for Clean Utilization of Hydrocarbon Resources, Xi'an 710069, China
  • Received:2018-10-08 Online:2019-07-28 Published:2019-10-14
  • Contact: Xiaoxun Ma

摘要: An experimental study on co-pyrolysis of bituminous coal and biomass was performed in a pressured fluidized bed reactor. The blend ratio of biomass in the mixture was varied between 0 and 100 wt%, and the temperature was over a range of 550-650℃ under 1.0 MPa pressure with different atmospheres. On the basis of the individual pyrolysis behavior of bituminous coal and biomass, the influences of the biomass blending ratio, temperature, pressure and atmosphere on the product distribution were investigated. The results indicated that there existed a synergetic effect in the co-pyrolysis of bituminous coal and biomass in this pressured fluidized bed reactor, especially when the condition of bituminous coal and biomass blend ratio of 70:30 (w/w), 600℃, and 0.3 MPa was applied. The addition of biomass influenced the tar and char yields and gas and tar composition during co-pyrolysis. The tar yields were higher than the calculated values from individual pyrolysis of each fuel, and consequently the char yields were lower. The experimental results showed that the composition of the gaseous products was not in accordance with those of their individual fuel. The improvement of composition in tar also indicated synergistic effect in the co-pyrolysis.

关键词: Bituminous coal, Biomass, Co-pyrolysis, Pressured fluidized bed, Synergistic effect

Abstract: An experimental study on co-pyrolysis of bituminous coal and biomass was performed in a pressured fluidized bed reactor. The blend ratio of biomass in the mixture was varied between 0 and 100 wt%, and the temperature was over a range of 550-650℃ under 1.0 MPa pressure with different atmospheres. On the basis of the individual pyrolysis behavior of bituminous coal and biomass, the influences of the biomass blending ratio, temperature, pressure and atmosphere on the product distribution were investigated. The results indicated that there existed a synergetic effect in the co-pyrolysis of bituminous coal and biomass in this pressured fluidized bed reactor, especially when the condition of bituminous coal and biomass blend ratio of 70:30 (w/w), 600℃, and 0.3 MPa was applied. The addition of biomass influenced the tar and char yields and gas and tar composition during co-pyrolysis. The tar yields were higher than the calculated values from individual pyrolysis of each fuel, and consequently the char yields were lower. The experimental results showed that the composition of the gaseous products was not in accordance with those of their individual fuel. The improvement of composition in tar also indicated synergistic effect in the co-pyrolysis.

Key words: Bituminous coal, Biomass, Co-pyrolysis, Pressured fluidized bed, Synergistic effect