Enhanced activation of peroxymonosulfate by Fe/N co-doped ordered mesoporous carbon with dual active sites for efficient removal of m-cresol

doi:10.1016/j.cjche.2023.06.026

中国化学工程学报 ›› 2024, Vol. 65 ›› Issue (1): 130-144.DOI: 10.1016/j.cjche.2023.06.026

• Full Length Article • 上一篇下一篇

Enhanced activation of peroxymonosulfate by Fe/N co-doped ordered mesoporous carbon with dual active sites for efficient removal of m-cresol

Donghui Li¹, Wenzhe Wu¹, Xue Ren¹, Xixi Zhao¹, Hongbing Song¹, Meng Xiao¹, Quanhong Zhu¹, Hengjun Gai², Tingting Huang¹

1 College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
2 School of Chemical & Environmental Engineering, China University of Mining & Technology-Beijing, Beijing 100083, China

收稿日期:2023-02-19 修回日期:2023-06-14 出版日期:2024-01-28 发布日期:2024-04-17
通讯作者: Hengjun Gai,E-mail:hjgai@126.com;Tingting Huang,E-mail:huangtingting@qust.edu.cn
基金资助:
The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (22108145 and 21978143), the Shandong Province Natural Science Foundation (ZR2020QB189), State Key Laboratory of Heavy Oil Processing (SKLHOP202203008) and the Talent Foundation funded by Province and Ministry Co-construction Collaborative Innovation Center of Eco-chemical Engineering (STHGYX2201).

Enhanced activation of peroxymonosulfate by Fe/N co-doped ordered mesoporous carbon with dual active sites for efficient removal of m-cresol

Donghui Li¹, Wenzhe Wu¹, Xue Ren¹, Xixi Zhao¹, Hongbing Song¹, Meng Xiao¹, Quanhong Zhu¹, Hengjun Gai², Tingting Huang¹

1 College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
2 School of Chemical & Environmental Engineering, China University of Mining & Technology-Beijing, Beijing 100083, China

Received:2023-02-19 Revised:2023-06-14 Online:2024-01-28 Published:2024-04-17
Contact: Hengjun Gai,E-mail:hjgai@126.com;Tingting Huang,E-mail:huangtingting@qust.edu.cn
Supported by:
The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (22108145 and 21978143), the Shandong Province Natural Science Foundation (ZR2020QB189), State Key Laboratory of Heavy Oil Processing (SKLHOP202203008) and the Talent Foundation funded by Province and Ministry Co-construction Collaborative Innovation Center of Eco-chemical Engineering (STHGYX2201).

摘要/Abstract

摘要： The novel Fe-N co-doped ordered mesoporous carbon with high catalytic activity in m-cresol removal was prepared by urea-assisted impregnation and simple pyrolysis method. During the preparation of the Fe-NC catalyst, the complexation of N elements in urea could anchor Fe, and the formation of C₃N₄ during urea pyrolysis could also prevent migration and aggregation of Fe species, which jointly improve the dispersion and stability of Fe. The FeN₄ sites and highly dispersed Fe nanoparticles synergistically trigger the dual-site peroxymonosulfate (PMS) activation for highly efficient m-cresol degradation, while the ordered mesoporous structure of the catalyst could improve the mass transfer rate of the catalytic process, which together promote catalytic degradation of m-cresol by PMS activation. Reactive oxygen species (ROS) analytic experiments demonstrate that the system degrades m-cresol by free radical pathway mainly based on SO₄^-· and ·OH, and partially based on ·OH as the active components, and a possible PMS activation mechanism by 5Fe-50 for m-cresol degradation was proposed. This study can provide theoretical guidance for the preparation of efficient and stable catalysts for the degradation of organic pollutants by activated PMS.

关键词: Degradation, Peroxymonosulfate, Fe(II)/Fe(III)/FeN₄, Ordered mesopores carbon, Catalyst, Radical

Abstract: The novel Fe-N co-doped ordered mesoporous carbon with high catalytic activity in m-cresol removal was prepared by urea-assisted impregnation and simple pyrolysis method. During the preparation of the Fe-NC catalyst, the complexation of N elements in urea could anchor Fe, and the formation of C₃N₄ during urea pyrolysis could also prevent migration and aggregation of Fe species, which jointly improve the dispersion and stability of Fe. The FeN₄ sites and highly dispersed Fe nanoparticles synergistically trigger the dual-site peroxymonosulfate (PMS) activation for highly efficient m-cresol degradation, while the ordered mesoporous structure of the catalyst could improve the mass transfer rate of the catalytic process, which together promote catalytic degradation of m-cresol by PMS activation. Reactive oxygen species (ROS) analytic experiments demonstrate that the system degrades m-cresol by free radical pathway mainly based on SO₄^-· and ·OH, and partially based on ·OH as the active components, and a possible PMS activation mechanism by 5Fe-50 for m-cresol degradation was proposed. This study can provide theoretical guidance for the preparation of efficient and stable catalysts for the degradation of organic pollutants by activated PMS.

Key words: Degradation, Peroxymonosulfate, Fe(II)/Fe(III)/FeN₄, Ordered mesopores carbon, Catalyst, Radical

Donghui Li, Wenzhe Wu, Xue Ren, Xixi Zhao, Hongbing Song, Meng Xiao, Quanhong Zhu, Hengjun Gai, Tingting Huang. Enhanced activation of peroxymonosulfate by Fe/N co-doped ordered mesoporous carbon with dual active sites for efficient removal of m-cresol[J]. 中国化学工程学报, 2024, 65(1): 130-144.

参考文献

[1] H.Q. Chu, X.Q. Liu, J.Y. Ma, T. Li, H.F. Fan, X.F. Zhou, Y.L. Zhang, E.C. Li, X.W. Zhang, Two-stage aNO_xic-oxic (A/O) system for the treatment of coking wastewater:Full-scale performance and microbial community analysis, Chem. Eng. J. 417(2021)129204.
[2] P.W. Han, C.H. Xu, Y.M. Wang, C.L. Sun, H.Z. Wei, H.B. Jin, Y. Zhao, L. Ma, The high catalytic activity and strong stability of 3% Fe/AC catalysts for catalytic wet peroxide oxidation of m-cresol:The role of surface functional groups and FeO_x particles, Chin. J. Chem. Eng. 44(2022)105-114.
[3] Z.S. Ncanana, V.S.R. Rajasekhar Pullabhotla, Oxidative degradation of m-cresol using ozone in the presence of pure γ-Al₂O₃, SiO₂ and V₂O₅ catalysts, J. Environ. Chem. Eng. 7(3)(2019)103072.
[4] J. Carbajo, A. Bahamonde, M. Faraldos, Photocatalyst performance in wastewater treatment applications:Towards the role of TiO₂ properties, Mol. Catal. 434(2017)167-174.
[5] W.X. Zhang, L.H. Ding, J.Q. Luo, M.Y. Jaffrin, B. Tang, Membrane fouling in photocatalytic membrane reactors (PMRs) for water and wastewater treatment:A critical review, Chem. Eng. J. 302(2016)446-458.
[6] S.F. Tang, Z.T. Wang, D.L. Yuan, C. Zhang, Y.D. Rao, Z.B. Wang, K. Yin, Ferrous ion-tartaric acid chelation promoted calcium peroxide fenton-like reactions for simulated organic wastewater treatment, J. Clean. Prod. 268(2020)122253.
[7] X.H. Li, S. Chen, I. Angelidaki, Y.F. Zhang, Bio-electro-Fenton processes for wastewater treatment:Advances and prospects, Chem. Eng. J. 354(2018)492-506.
[8] N.K. Pandey, H.B. Li, L. Chudal, B. Bui, E. Amador, M.B. Zhang, H.M. Yu, M.L. Chen, X. Luo, W. Chen, Exploration of copper-cysteamine nanoparticles as an efficient heterogeneous Fenton-like catalyst for wastewater treatment, Mater. Today Phys. 22(2022)100587.
[9] L.L. Qian, S.Z. Wang, D.H. Xu, Y. Guo, X.Y. Tang, L.S. Wang, Treatment of municipal sewage sludge in supercritical water:A review, Water Res. 89(2016)118-131.
[10] X.D. Tan, H.Q. Li, X.R. Li, W.J. Sun, C.Y. Jin, L.L. Chen, H.Z. Wei, C.L. Sun, A novel isophorone wastewater treatment technology-wet electrocatalytic oxidation and its degradation mechanism study, J. Hazard. Mater. 389(2020)122035.
[11] T. Hammedi, M. Triki, M.G. Alvarez, R.J. Chimentao, Z. Ksibi, A. Ghorbel, J. Llorca, F. Medina, Total degradation of p-hydroxybenzoic acid by Ru-catalysed wet air oxidation:A model for wastewater treatment, Environ.. Chem. Lett. 13(4)(2015)481-486.
[12] W.L. Shi, Y.N. Liu, W. Sun, Y.Z. Hong, X.Y. Li, X. Lin, F. Guo, J.Y. Shi, Improvement of synergistic effect photocatalytic/peroxymonosulfate activation for degradation of amoxicillin using carbon dots anchored on rod-like CoFe₂O₄, Chin. J. Chem. Eng. 52(2022)136-145.
[13] L. Yang, Y. Jiao, D.Y. Jia, Y.Z. Li, C.H. Liao, Role of oxygen vacancies and Sr sites in SrCo_0.8Fe_0.2O₃ perovskite on efficient activation of peroxymonosulfate towards the degradation of aqueous organic pollutants, Chin. J. Chem. Eng. 40(2021)269-277.
[14] J.H. Wei, F. Li, L.N. Zhou, D.D. Han, J.B. Gong, Strategies for enhancing peroxymonosulfate activation by heterogenous metal-based catalysis:A review, Chin. J. Chem. Eng. 50(2022)12-28.
[15] C.X. Yu, Z.K. Xiong, H.Y. Zhou, P. Zhou, H. Zhang, R.F. Huang, G. Yao, B. Lai, Marriage of membrane filtration and sulfate radical-advanced oxidation processes (SR-AOPs) for water purification:Current developments, challenges and prospects, Chem. Eng. J. 433(2022)133802.
[16] Y.J. Zhang, Q. Yang, J. Liang, Y.S. Luo, Q. Liu, Y.C. Yang, X.P. Sun, Fe-glycerate microspheres as a heterogeneous catalyst to activate peroxymonosulfate for efficient degradation of methylene blue, J. Phys. Chem. Solids 169(2022)110893.
[17] J.L. Yu, P.E. Savage, Phenol oxidation over CuO/Al₂O₃ in supercritical water, Appl. Catal. B 28(3-4)(2000)275-288.
[18] Y.H. Cao, B. Li, G.Y. Zhong, Y.H. Li, H.J. Wang, H. Yu, F. Peng, Catalytic wet air oxidation of phenol over carbon nanotubes:Synergistic effect of carboxyl groups and edge carbons, Carbon 133(2018)464-473.
[19] X.H. Tan, J. Bai, J.Y. Zheng, Y. Zhang, J.H. Li, T.S. Zhou, L.G. Xia, Q.J. Xu, B.X. Zhou, Photocatalytic fuel cell based on sulfate radicals converted from sulfates in situ for wastewater treatment and chemical energy utilization, Catal. Today 335(2019)485-491.
[20] Q.X. Zhao, Q.M. Mao, Y.Y. Zhou, J.H. Wei, X.C. Liu, J.Y. Yang, L. Luo, J.C. Zhang, H. Chen, H.B. Chen, L. Tang, Metal-free carbon materials-catalyzed sulfate radicalbased advanced oxidation processes:A review on heterogeneous catalysts and applications, Chemosphere 189(2017)224-238.
[21] Q. Yang, Y.C. Yang, Y.J. Zhang, L.C. Zhang, S.J. Sun, K. Dong, Y.S. Luo, J.Y. Wu, X. W. Kang, Q. Liu, M.S. Hamdy, X.P. Sun, Highly efficient activation of peroxymonosulfate by biomass juncus derived carbon decorated with cobalt nanoparticles for the degradation of ofloxacin, Chemosphere 311(2023)137020.
[22] Q. Yang, Y.J. Zhang, J. Liang, Y.S. Luo, Q. Liu, Y.C. Yang, X.P. Sun, Facile hydrothermal synthesis of co-glycerate as an efficient peroxymonosulfate activator for rhodamine B degradation, Colloids Surf. A 648(2022)129239.
[23] L. Ling, D.P. Zhang, C. Fan, C. Shang, A Fe (II)/citrate/UV/PMS process for carbamazepine degradation at a very low Fe (II)/PMS ratio and neutral pH:The mechanisms, Water Res. 124(2017)446-453.
[24] B. Sheng, F. Yang, Y.H. Wang, Z.H. Wang, Q. Li, Y.G. Guo, X.Y. Lou, J.S. Liu, Pivotal roles of MoS₂ in boosting catalytic degradation of aqueous organic pollutants by Fe (II)/PMS, Chem. Eng. J. 375(2019)121989.
[25] X.H. Long, Z.K. Xiong, R.F. Huang, Y.H. Yu, P. Zhou, H. Zhang, G. Yao, B. Lai, Sustainable Fe (III)/Fe (II) cycles triggered by co-catalyst of weak electrical current in Fe (III)/peroxymonosulfate system:Collaboration of radical and nonradical mechanisms, Appl. Catal. B 317(2022)121716.
[26] J.J. Zhao, H.X. Wei, P.S. Liu, A.R. Zhou, X. Lin, J. Zhai, Activation of peroxymonosulfate by metal-organic frameworks derived Co_1+xFe_2-xO₄ for organic dyes degradation:A new insight into the synergy effect of Co and Fe, J. Environ. Chem. Eng. 9(4)(2021)105412.
[27] H.X. Li, Y.Z. Yao, J. Zhang, J. Du, S.D. Xu, C.H. Wang, D. Zhang, J.H. Tang, H.T. Zhao, J. Zhou, Degradation of phenanthrene by peroxymonosulfate activated with bimetallic metal-organic frameworks:Kinetics, mechanisms, and degradation products, Chem. Eng. J. 397(2020)125401.
[28] Y. Wang, L. Wu, Y.R. Zhou, Y.L. Zhang, S.P. Sun, W. Duo Wu, X.N. Wang, Z.X. Wu, Ternary FeS/c-Fe₂O₃@N/S-doped carbon nanohybrids dispersed in an ordered mesoporous silica for efficient peroxymonosulfate activation, Chem. Eng. J. 435(2022)135124.
[29] L.M. Yang, W.D. Chen, C.H. Sheng, H.L. Wu, N.T. Mao, H. Zhang, Fe/N-codoped carbocatalysts loaded on carbon cloth (CC) for activating peroxymonosulfate (PMS) to degrade methyl orange dyes, Appl. Surf. Sci. 549(2021)149300.
[30] U. Jeong, H. Kim, S. Ramesh, N.A. Dogan, S. Wongwilawan, S. Kang, J. Park, E.S. Cho, C.T. Yavuz, Rapid access to ordered mesoporous carbons for chemical hydrogen storage, Angew. Chem. Int. Ed. 60(41)(2021)22478-22486.
[31] Z.C. Luo, Z.Y. Yin, J.Q. Yu, Y. Yan, B. Hu, R.F. Nie, A.F. Kolln, X. Wu, R.K. Behera, M.D. Chen, L. Zhou, F.D. Liu, B. Wang, W.Y. Huang, S. Zhang, L. Qi, General synthetic strategy to ordered mesoporous carbon catalysts with single-atom metal sites for electrochemical CO₂ reduction, Small 18(16)(2022)2270078.
[32] D.D. He, K. Zhu, J. Huang, Y.Q. Shen, L.L. Lei, H.M. He, W.J. Chen, N, S co-doped magnetic mesoporous carbon nanosheets for activating peroxymonosulfate to rapidly degrade tetracycline:Synergistic effect and mechanism, J. Hazard. Mater. 424(2022)127569.
[33] G.L. Wang, S. Chen, X. Quan, H.T. Yu, Y.B. Zhang, Enhanced activation of peroxymonosulfate by nitrogen doped porous carbon for effective removal of organic pollutants, Carbon 115(2017)730-739.
[34] Y.B. Wang, M. Liu, X. Zhao, D. Cao, T. Guo, B. Yang, Insights into heterogeneous catalysis of peroxymonosulfate activation by boron-doped ordered mesoporous carbon, Carbon 135(2018)238-247.
[35] Y. Gao, T.W. Wu, C.D. Yang, C. Ma, Z.Y. Zhao, Z.H. Wu, S.J. Cao, W. Geng, Y. Wang, Y.Y. Yao, Y.N. Zhang, C. Cheng, Activity trends and mechanisms in peroxymonosulfate-assisted catalytic production of singlet oxygen over atomic metal-N-C catalysts, Angew. Chem. Int. Ed. 60(41)(2021)22513-22521.
[36] H.J. Zhang, H.H. Tao, Y. Jiang, Z. Jiao, M.H. Wu, B. Zhao, Ordered CoO/CMK-3 nanocomposites as the anode materials for lithium-ion batteries, J. Power Sources 195(9)(2010)2950-2955.
[37] V.K. Gupta, A. Nayak, Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe₂O₃ nanoparticles, Chem. Eng. J. 180(2012)81-90.
[38] Y.J. Zhang, Q. Yang, L.C. Yue, Q. Liu, Y.S. Luo, J.Y. Wu, X.W. Kang, S.J. Sun, Y.C. Yang, X.P. Sun, Biomass juncus derived carbon modified with Fe₃O₄ nanoparticles toward activating peroxymonosulfate for efficient degradation of tetracycline, J. Water Process. Eng. 51(2023)103324.
[39] S. Jun, S.H. Joo, R. Ryoo, M. Kruk, M. Jaroniec, Z. Liu, T. Ohsuna, O. Terasaki, Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure, J. Am. Chem. Soc. 122(43)(2000)10712-10713.
[40] A. Carrero, J. Calles, L. García-Moreno, A. Vizcaíno, Production of renewable hydrogen from glycerol steam reforming over bimetallic Ni-(Cu, Co, Cr) catalysts supported on SBA-15 silica, Catalysts 7(12)(2017)55.
[41] P. Arab, A. Badiei, A. Koolivand, G. Mohammadi Ziarani, Direct hydroxylation of benzene to phenol over Fe₃O₄ supported on nanoporous carbon, Chin. J. Catal. 32(1-2)(2011)258-263.
[42] H. Huwe, M. Fröba, Synthesis and characterization of transition metal and metal oxide nanoparticles inside mesoporous carbon CMK-3, Carbon 45(2)(2007)304-314.
[43] C.S. Feng, C. Chen, Y. Zhu, Q. Cao, C. Chen, C.Y. Jiang, Y.P. Wang, Degradation of ofloxacin using peroxymonosulfate activated by nitrogen-rich graphitized carbon microspheres:Structure and performance controllable study, J. Environ. Sci. 99(2021)10-20.
[44] M.Z. Li, C.L. Yan, R. Ramachandran, Y.C. Lan, H. Dai, H.Q. Shan, X.C. Meng, D.H. Cui, F. Wang, Z.X. Xu, Non-peripheral octamethyl-substituted cobalt phthalocyanine nanorods supported on N-doped reduced graphene oxide achieve efficient electrocatalytic CO₂ reduction to CO, Chem. Eng. J. 430(2022)133050.
[45] D.P. Xue, H.C. Xia, W.F. Yan, J.N. Zhang, S.C. Mu, Defect engineering on carbonbased catalysts for electrocatalytic CO₂ reduction, Nano Micro Lett. 13(1)(2020)1-23.
[46] K. Dong, J. Liang, Y.Y. Wang, Z.Q. Xu, Q. Liu, Y.L. Luo, T.S. Li, L. Li, X.F. Shi, A.M. Asiri, Q. Li, D.W. Ma, X.P. Sun, Honeycomb carbon nanofibers:A superhydrophilic O₂-Entrapping electrocatalyst enables ultrahigh mass activity for the two-electron oxygen reduction reaction, Angew. Chem. Int. Ed. 60(19)(2021)10583-10587.
[47] S.L. Huo, X. Song, Y.B. Zhao, W. Ni, H. Wang, K.X. Li, Insight into the significant contribution of intrinsic carbon defects for the high-performance capacitive desalination of brackish water, J. Mater. Chem. A 8(38)(2020)19927-19937.
[48] Y. Wang, L.P. Huang, Y.Q. Liu, D.C. Wei, H.L. Zhang, H. Kajiura, Y.M. Li, Minimizing purification-induced defects in single-walled carbon nanotubes gives films with improved conductivity, Nano Res. 2(11)(2009)865-871.
[49] Z.Y. Lin, G. Waller, Y. Liu, M.L. Liu, C.P. Wong, Facile synthesis of nitrogendoped graphene via pyrolysis of graphene oxide and urea, and its electrocatalytic activity toward the oxygen-reduction reaction, Adv. Energy Mater. 2(7)(2012)884-888.
[50] J.W. Lang, X.B. Yan, W.W. Liu, R.T. Wang, Q.J. Xue, Influence of nitric acid modification of ordered mesoporous carbon materials on their capacitive performances in different aqueous electrolytes, J. Power Sources 204(2012)220-229.
[51] H. Zhang, H.N. Guo, A.Y. Li, X.Y. Chang, S. Liu, D. Liu, Y.J. Wang, F. Zhang, H.T. Yuan, High specific surface area porous graphene grids carbon as anode materials for sodium ion batteries, J. Energy Chem. 31(2019)159-166.
[52] T. Yamashita, P. Hayes, Analysis of XPS spectra of Fe²⁺ and Fe³⁺ ions in oxide materials, Appl. Surf. Sci. 254(8)(2008)2441-2449.
[53] T. Zhang, J.D. Wu, Z. Wang, Z. Wei, J.H. Liu, X.Z. Gong, Transfer of molecular oxygen and electrons improved by the regulation of C-N/C=O for highly efficient 2e-ORR, Chem. Eng. J. 433(2022)133591.
[54] M.L. Sun, J.L. Peng, P. Zhou, C.S. He, Y. Du, Z.C. Pan, S.J. Su, F. Dong, Y. Liu, B. Lai, Insights into peroxymonosulfate activation under visible light:Sc₂O₃@C₃N₄ mediated photoexcited electron transfer, Chem. Eng. J. 435(2022)134836.
[55] C.H. Liu, Y. Wu, K.A. Sun, J.J. Fang, A.J. Huang, Y. Pan, W.C. Cheong, Z.W. Zhuang, Z.B. Zhuang, Q.H. Yuan, H.L. Xin, C. Zhang, J.W. Zhang, H. Xiao, C. Chen, Y.D. Li, Constructing FeN₄/graphitic nitrogen atomic interface for high-efficiency electrochemical CO₂ reduction over a broad potential window, Chem 7(5)(2021)1297-1307.
[56] C.Y. Duan, M.L. Ding, Y. Feng, M.J. Cao, J.F. Yao, ZIF-L-derived ZnO/N-doped carbon with multiple active sites for efficient catalytic CO₂ cycloaddition, Sep. Purif. Technol. 285(2022)120359.
[57] L.J. Peng, Y.N. Shang, B.Y. Gao, X. Xu, Co₃O₄ anchored in N, S heteroatom codoped porous carbons for degradation of organic contaminant:Role of pyridinic N-Co binding and high tolerance of chloride, Appl. Catal. B 282(2021)119484.
[58] S.Z. Wang, J.L. Wang, Peroxymonosulfate activation by Co₉S₈@S and N co-doped biochar for sulfamethoxazole degradation, Chem. Eng. J. 385(2020)123933.
[59] X.G. Duan, H.Q. Sun, S.B. Wang, Metal-free carbocatalysis in advanced oxidation reactions, Acc. Chem. Res. 51(3)(2018)678-687.
[60] Y.W. Gao, T. Li, Y. Zhu, Z.H. Chen, J.Y. Liang, Q.Y. Zeng, L. Lyu, C. Hu, Highly nitrogen-doped porous carbon transformed from graphitic carbon nitride for efficient metal-free catalysis, J. Hazard. Mater. 393(2020)121280.
[61] Z.Y. Zhu, H.F. Tang, Y. Du, Y.F. Wei, Y.Q. Chen, W.J. Yang, D.Y. Zhang, Z.R. Li, C.B. Liu, Filter-membrane treatment of continuous-flow tetracycline through photocatalysis-assisted peroxydisulfate oxidation, AlChE. J. 68(6)(2022) -17654.
[62] Z. Boutamine, O. Hamdaoui, S. Merouani, Probing the radical chemistry and the reaction zone during the sono-degradation of endocrine disruptor 2-pheNO_xyethanol in water, Ultrason. Sonochem. 41(2018)521-526.
[63] S.S. Liu, X. Zhao, Y.B. Wang, H.X. Shao, M. Qiao, Y. Wang, S. Zhao, Peroxymonosulfate enhanced photoelectrocatalytic degradation of phenol activated by Co₃O₄ loaded carbon fiber cathode, J. Catal. 355(2017)167-175.
[64] S.Q. Liu, Z.C. Zhang, F. Huang, Y.Z. Liu, L. Feng, J. Jiang, L.Q. Zhang, F. Qi, C. Liu, Carbonized polyaniline activated peroxymonosulfate (PMS) for phenol degradation:Role of PMS adsorption and singlet oxygen generation, Appl. Catal. B 286(2021)119921.
[65] Y. Feng, C.Z. Liao, L.J. Kong, D.L. Wu, Y.M. Liu, P.H. Lee, K. Shih, Facile synthesis of highly reactive and stable Fe-doped g-C₃N₄ composites for peroxymonosulfate activation:A novel nonradical oxidation process, J. Hazard. Mater. 354(2018)63-71.
[66] C.X. Li, C.B. Chen, Y.J. Wang, X.Z. Fu, S. Cui, J.Y. Lu, J. Li, H.Q. Liu, W.W. Li, T.C. Lau, Insights on the pH-dependent roles of peroxymonosulfate and chlorine ions in phenol oxidative transformation, Chem. Eng. J. 362(2019)570-575.
[67] Y. Lei, C.S. Chen, J. Ai, H. Lin, Y.H. Huang, H. Zhang, Selective decolorization of cationic dyes by peroxymonosulfate:Non-radical mechanism and effect of chloride, RSC Adv. 6(2)(2016)866-871.
[68] X. He, K.E. O'Shea, Selective oxidation of H1-antihistamines by unactivated peroxymonosulfate (PMS):Influence of inorganic anions and organic compounds, Water Res. 186(2020)116401.
[69] Y. Liu, H.G. Guo, Y.L. Zhang, X. Cheng, P. Zhou, J. Deng, J.Q. Wang, W. Li, Highly efficient removal of trimethoprim based on peroxymonosulfate activation by carbonized resin with Co doping:Performance, mechanism and degradation pathway, Chem. Eng. J. 356(2019)717-726.
[70] Y.K. Liu, T. Qiu, Y.L. Wu, S.Y. Wang, M. Liu, W.B. Dong, Remediation of soil contaminated with ibuprofen by persulfate activated with Gallic acid and ferric iron, Chem. Eng. J. 426(2021)127653.
[71] M.S. Alam, B.S.M. Rao, E. Janata, OH reactions with aliphatic alcohols:Evaluation of kinetics by direct optical absorption measurement. A pulse radiolysis study, Radiat. Phys. Chem. 67(6)(2003)723-728.
[72] P. Liang, C. Zhang, X.G. Duan, H.Q. Sun, S.M. Liu, M.O. Tade, S.B. Wang, N-doped graphene from metal-organic frameworks for catalytic oxidation of p-hydroxylbenzoic acid:N-functionality and mechanism, ACS Sustainable Chem. Eng. 5(3)(2017)2693-2701.
[73] E.M. Rodríguez, G. Márquez, M. Tena, P.M. Álvarez, F.J. Beltrán, Determination of main species involved in the first steps of TiO₂ photocatalytic degradation of organics with the use of scavengers:the case of ofloxacin, Appl. Catal. B 178(2015)44-53.
[74] P. Sun, H. Liu, M.B. Feng, L. Guo, Z.C. Zhai, Y.S. Fang, X.S. Zhang, V.K. Sharma, Nitrogen-sulfur co-doped industrial graphene as an efficient peroxymonosulfate activator:Singlet oxygen-dominated catalytic degradation of organic contaminants, Appl. Catal. B 251(2019)335-345.
[75] Z.Y. Guan, S.Y. Zuo, F. Yang, B.Y. Zhang, H.M. Xu, D.S. Xia, M.Z. Huang, D.Y. Li, The polarized electric field on Fe-N-C-S promotes non-radical process of peroxymonosulfate degrade diclofenac sodium, Colloids Surf.. A 621(2021)126608.
[76] C.Y. Guo, C.F. Chen, J.Y. Lu, D. Fu, C.Z. Yuan, X.L. Wu, K.N. Hui, J.R. Chen, Stable and recyclable Fe₃C@CN catalyst supported on carbon felt for efficient activation of peroxymonosulfate, J. Colloid Interface Sci. 599(2021)219-226.
[77] W.X. Qin, G.D. Fang, Y.J. Wang, D.M. Zhou, Mechanistic understanding of polychlorinated biphenyls degradation by peroxymonosulfate activated with CuFe₂O₄ nanoparticles:Key role of superoxide radicals, Chem. Eng. J. 348(2018)526-534.
[78] P.P. Fu, Q.S. Xia, H.M. Hwang, P.C. Ray, H.T. Yu, Mechanisms of nanotoxicity:Generation of reactive oxygen species, J. Food Drug Anal. 22(1)(2014)64-75.
[79] S.A. Liu, D. Liu, Y.L. Sun, P.Y. Xiao, H.J. Lin, J.R. Chen, X.L. Wu, X.G. Duan, S.B. Wang, Enzyme-mimicking single-atom FeN₄ sites for enhanced photo-Fentonlike reactions, Appl. Catal. B 310(2022)121327.
[80] T. Yang, S.S. Fan, Y. Li, Q. Zhou, Fe-N/C single-atom catalysts with high density of Fe-N_x sites toward peroxymonosulfate activation for high-efficient oxidation of bisphenol A:Electron-transfer mechanism, Chem. Eng. J. 419(2021)129590.

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Enhanced activation of peroxymonosulfate by Fe/N co-doped ordered mesoporous carbon with dual active sites for efficient removal of m-cresol

Enhanced activation of peroxymonosulfate by Fe/N co-doped ordered mesoporous carbon with dual active sites for efficient removal of m-cresol

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