SCI和EI收录∣中国化工学会会刊

›› 2015, Vol. 23 ›› Issue (3): 516-519.DOI: 10.1016/j.cjche.2014.07.003

• 催化、动力学与反应工程 • 上一篇    下一篇

Carbon nanotubes loaded with vanadium oxide for reduction NO with NH3 at low temperature

Shuli Bai1,2, Shengtao Jiang1, Huanying Li3, Yujiang Guan1   

  1. 1 College of Life Science, Taizhou University, Taizhou 318000, China;
    2 Zhejiang Provincial Key Laboratory of Plant Evolutionary Ecology and Conservation, Taizhou 318000, China;
    3 College of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000, China
  • 收稿日期:2013-12-27 修回日期:2014-07-28 出版日期:2015-03-28 发布日期:2015-04-03
  • 通讯作者: Shuli Bai, Huanying Li
  • 基金资助:
    Supported by the National Natural Science Foundation of China (21006065) and the Zhejiang Provincial Natural Science Foundation of China (Y5100009).

Carbon nanotubes loaded with vanadium oxide for reduction NO with NH3 at low temperature

Shuli Bai1,2, Shengtao Jiang1, Huanying Li3, Yujiang Guan1   

  1. 1 College of Life Science, Taizhou University, Taizhou 318000, China;
    2 Zhejiang Provincial Key Laboratory of Plant Evolutionary Ecology and Conservation, Taizhou 318000, China;
    3 College of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000, China
  • Received:2013-12-27 Revised:2014-07-28 Online:2015-03-28 Published:2015-04-03
  • Supported by:
    Supported by the National Natural Science Foundation of China (21006065) and the Zhejiang Provincial Natural Science Foundation of China (Y5100009).

摘要: The catalytic activity of carbon nanotubes-supported vanadium oxide (V2O5/CNTs) catalysts in the selective catalytic reduction (SCR) of NO with NH3 at low temperatures (≤250℃) was investigated. The effects of V2O5 loading, reaction temperature, and presence of SO2 on the SCR activity were evaluated. The results show that V2O5/CNTs catalysts exhibit high activity for NO reduction with NH3 at low-temperatures. The catalysts also show very high stability in the presence of SO2.More interestingly, their activities are significantly promoted instead of being poisoned by SO2. The promoting effect of SO2 is distinctly associatedwith V2O5 loading, particularly maximized at low V2O5 loading, which indicated the role of CNTs support in this effect. The promoting effect of SO2 at lowtemperatures suggests that V2O5/CNTs catalysts are promising catalyticmaterials for low-temperature SCR reactions.

关键词: Selective catalytic reduction, V2O5/CNTs catalyst, Flue gas, Physic-chemical property

Abstract: The catalytic activity of carbon nanotubes-supported vanadium oxide (V2O5/CNTs) catalysts in the selective catalytic reduction (SCR) of NO with NH3 at low temperatures (≤250℃) was investigated. The effects of V2O5 loading, reaction temperature, and presence of SO2 on the SCR activity were evaluated. The results show that V2O5/CNTs catalysts exhibit high activity for NO reduction with NH3 at low-temperatures. The catalysts also show very high stability in the presence of SO2.More interestingly, their activities are significantly promoted instead of being poisoned by SO2. The promoting effect of SO2 is distinctly associatedwith V2O5 loading, particularly maximized at low V2O5 loading, which indicated the role of CNTs support in this effect. The promoting effect of SO2 at lowtemperatures suggests that V2O5/CNTs catalysts are promising catalyticmaterials for low-temperature SCR reactions.

Key words: Selective catalytic reduction, V2O5/CNTs catalyst, Flue gas, Physic-chemical property