Catalytic hydrogenation performance of ZIF-8 carbide for electrochemical reduction of carbon dioxide

doi:10.1016/j.cjche.2021.05.032

中国化学工程学报 ›› 2021, Vol. 39 ›› Issue (11): 144-153.DOI: 10.1016/j.cjche.2021.05.032

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Catalytic hydrogenation performance of ZIF-8 carbide for electrochemical reduction of carbon dioxide

Shuai Fan, Huiyuan Cheng, Manman Feng, Xuemei Wu, Zihao Fan, Dongwei Pan, Gaohong He

State Key Laboratory of Fine Chemicals, Research and Development Center of Membrane Science and Technology, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

收稿日期:2020-11-18 修回日期:2021-05-17 出版日期:2021-11-28 发布日期:2021-12-27
通讯作者: Xuemei Wu, Gaohong He
基金资助:
This work was financially supported by the National Natural Science Foundation of China (Joint Fund U1663223 and 21776034), Science Fund for Creative Research Groups of the National Natural Science Foundation of China (22021005), the National Key Research and Development Program of China (2016YFB0101203), Educational Department of Liaoning Province of China (LT2015007), Fundamental Research Funds for the Central Universities (DUT16TD19) and the Changjiang Scholar Program (T2012049).

Catalytic hydrogenation performance of ZIF-8 carbide for electrochemical reduction of carbon dioxide

Shuai Fan, Huiyuan Cheng, Manman Feng, Xuemei Wu, Zihao Fan, Dongwei Pan, Gaohong He

State Key Laboratory of Fine Chemicals, Research and Development Center of Membrane Science and Technology, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Received:2020-11-18 Revised:2021-05-17 Online:2021-11-28 Published:2021-12-27
Contact: Xuemei Wu, Gaohong He
Supported by:
This work was financially supported by the National Natural Science Foundation of China (Joint Fund U1663223 and 21776034), Science Fund for Creative Research Groups of the National Natural Science Foundation of China (22021005), the National Key Research and Development Program of China (2016YFB0101203), Educational Department of Liaoning Province of China (LT2015007), Fundamental Research Funds for the Central Universities (DUT16TD19) and the Changjiang Scholar Program (T2012049).

摘要/Abstract

摘要： The conversion of CO₂ electrocatalytic hydrogenation into energy-rich fuel is considered to be the most effective way to carbon recycle. Nitrogen-doping carbonized ZIF-8 is proposed as carrier of the earth-rich Sn catalyst to overcome the limit of electron transfer and CO₂ adsorption capacity of Sn. Hierarchically porous structure of Sn doped carbonized ZIF-8 is controlled by hydrothermal and carbonization conditions, which induces much higher specific surface area than that of the commercial Sn nanoparticle (1003.174 vs. 7.410 m²·g^-1). The shift of nitrogen peaks in X-ray Photoelectron Spectroscopy spectra indicates interaction between ZIF-8 and Sn, which induces the shift of electron cloud from Sn to the chemical nitrogen to enhance conductivity and regulate electron transfer from catalyst to CO₂. Lower mass transfer resistance and Warburg resistance are investigated through EIS, which significantly improves the catalytic activity for CO₂ reduction reaction (CO₂RR). Onset potential of the reaction is reduced from -0.74 V to less than -0.54 V vs. RHE. The total Faraday efficiency of HCOOH and CO reaches 68.9% at -1.14 V vs. RHE, which is much higher than that of the commercial Sn (45.0%) and some other Sn-based catalyst reported in the literature.

关键词: Carbon dioxide, Electrochemistry, Selective catalytic reduction, Electrochemical hydrogen pump, Nitrogen-doping carbonized ZIF-8

Abstract: The conversion of CO₂ electrocatalytic hydrogenation into energy-rich fuel is considered to be the most effective way to carbon recycle. Nitrogen-doping carbonized ZIF-8 is proposed as carrier of the earth-rich Sn catalyst to overcome the limit of electron transfer and CO₂ adsorption capacity of Sn. Hierarchically porous structure of Sn doped carbonized ZIF-8 is controlled by hydrothermal and carbonization conditions, which induces much higher specific surface area than that of the commercial Sn nanoparticle (1003.174 vs. 7.410 m²·g^-1). The shift of nitrogen peaks in X-ray Photoelectron Spectroscopy spectra indicates interaction between ZIF-8 and Sn, which induces the shift of electron cloud from Sn to the chemical nitrogen to enhance conductivity and regulate electron transfer from catalyst to CO₂. Lower mass transfer resistance and Warburg resistance are investigated through EIS, which significantly improves the catalytic activity for CO₂ reduction reaction (CO₂RR). Onset potential of the reaction is reduced from -0.74 V to less than -0.54 V vs. RHE. The total Faraday efficiency of HCOOH and CO reaches 68.9% at -1.14 V vs. RHE, which is much higher than that of the commercial Sn (45.0%) and some other Sn-based catalyst reported in the literature.

Key words: Carbon dioxide, Electrochemistry, Selective catalytic reduction, Electrochemical hydrogen pump, Nitrogen-doping carbonized ZIF-8

Shuai Fan, Huiyuan Cheng, Manman Feng, Xuemei Wu, Zihao Fan, Dongwei Pan, Gaohong He. Catalytic hydrogenation performance of ZIF-8 carbide for electrochemical reduction of carbon dioxide[J]. 中国化学工程学报, 2021, 39(11): 144-153.

参考文献

[1] C. Le Quéré, R. Moriarty, R.M. Andrew, J.G. Canadell, S. Sitch, J.I. Korsbakken, P. Friedlingstein, G.P. Peters, R.J. Andres, T.A. Boden, R.A. Houghton, J.I. House, R.F. Keeling, P. Tans, A. Arneth, D.C.E. Bakker, L. Barbero, L. Bopp, J. Chang, F. Chevallier, L.P. Chini, P. Ciais, M. Fader, R.A. Feely, T. Gkritzalis, I. Harris, J. Hauck, T. Ilyina, A.K. Jain, E. Kato, V. Kitidis, K. Klein Goldewijk, C. Koven, P. Landschützer, S.K. Lauvset, N. Lefèvre, A. Lenton, I.D. Lima, N. Metzl, F. Millero, D.R. Munro, A. Murata, J.E.M.S. Nabel, S. Nakaoka, Y. Nojiri, K. O'Brien, A. Olsen, T. Ono, F.F. Pérez, B. Pfeil, D. Pierrot, B. Poulter, G. Rehder, C. Rödenbeck, S. Saito, U. Schuster, J. Schwinger, R. Séférian, T. Steinhoff, B.D. Stocker, A.J. Sutton, T. Takahashi, B. Tilbrook, I.T. van der Laan-Luijkx, G.R. van der Werf, S. van Heuven, D. Vandemark, N. Viovy, A. Wiltshire, S. Zaehle, N. Zeng, Global Carbon Budgeet, Earth Syst. Sci. Data 7(2015) (2015) 349-396.
[2] E.V. Kondratenko, G. Mul, J. Baltrusaitis, G.O. Larrazábal, J. Pérez-Ramírez, Status and perspectives of CO₂ conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes, Energ. Environ. Sci. 6(11) (2013) 3112.
[3] G.A. Ozin, Throwing new light on the reduction of CO₂, Adv. Mater. 27(11) (2015) 1957-1963.
[4] M. Aresta, A. Dibenedetto, A. Angelini, Catalysis for the valorization of exhaust carbon:from CO₂ to chemicals, materials, and fuels. technological use of CO₂, Chem. Rev. 114(2014) 1709-1742.
[5] M.D. Porosoff, B. Yan, J.G. Chen, Catalytic reduction of CO₂ by H₂ for synthesis of CO, methanol and hydrocarbons:Challenges and opportunities, Energ. Environ. Sci. 9(1) (2016) 62-73.
[6] M. Sheng, N. Jiang, S. Gustafson, B.o. You, D.H. Ess, Y. Sun, A nickel complex with a biscarbene pincer-type ligand shows high electrocatalytic reduction of CO₂ over H₂O, Dalton T. 44(37) (2015) 16247-16250.
[7] J. Wu, Y. Huang, W. Ye, Y. Li, CO₂ Reduction:From the Electrochemical to Photochemical Approach, Adv. Sci. 4(2017) 1700194.
[8] J. Qiao, Y. Liu, F. Hong, J. Zhang, A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels, Chem. Soc. Rev. 43(2) (2014) 631- 675.
[9] R.J. Lim, M. Xie, M.A. Sk, J.-M. Lee, A. Fisher, X. Wang, K.H. Lim, A review on the electrochemical reduction of CO₂ in fuel cells, metal electrodes and molecular catalysts, Catal. Today 233(2014) 169-180.
[10] S. Hosseini, S. kheawhom, S. Masoudi Soltani, M.K. Aroua, H. Moghaddas, R. Yusoff, Improvement of product selectivity in bicarbonate reduction into formic acid on a tin-based catalyst by integrating nano-diamond particles, Process Saf. Environ. 116(2018) 494-505.
[11] A. Del Castillo, M. Alvarez-Guerra, J. Solla-Gullón, A. Sáez, V. Montiel, A. Irabien, Sn nanoparticles on gas diffusion electrodes:Synthesis, characterization and use for continuous CO₂ electroreduction to formate, J. CO₂ Util. 18(2017) 222-228.
[12] C. Zhao, J. Wang, Electrochemical reduction of CO₂ to formate in aqueous solution using electro-deposited Sn catalysts, Chem. Eng. J. 293(2016) 161- 170.
[13] R.G. Grim, Z. Huang, M.T. Guarnieri, J.R. Ferrell, L. Tao, J.A. Schaidle, Transforming the carbon economy:Challenges and opportunities in the convergence of low-cost electricity and reductive CO₂ utilization, Energ. Environ. Sci. 13(2020) 472-494.
[14] G.K.S. Prakash, F.A. Viva, G.A. Olah, Electrochemical reduction of CO₂ over SnNafion^® coated electrode for a fuel-cell-like device, J. Power Sources 223(2013) 68-73.
[15] Q. Wang, H. Dong, H. Yu, Development of rolling tin gas diffusion electrode for carbon dioxide electrochemical reduction to produce formate in aqueous electrolyte, J. Power Sources 271(2014) 278-284.
[16] Q. Wang, H. Dong, H. Yu, Fabrication of a novel tin gas diffusion electrode for electrochemical reduction of carbon dioxide to formic acid, RSC Adv. 4(104) (2014) 59970-59976.
[17] E. Irtem, T. Andreu, A. Parra, M.D. Hernández-Alonso, S. García-Rodríguez, J.M. Riesco-García, G. Penelas-Pérez, J.R. Morante, Low-energy formate production from CO₂ electroreduction using electrodeposited tin on GDE, J. Mater. Chem. A 4(35) (2016) 13582-13588.
[18] R. Zhang, W. Lv, G. Li, L. Lei, Electrochemical reduction of CO₂ on SnO₂/nitrogen-doped multiwalled carbon nanotubes composites in KHCO₃ aqueous solution, Mater. Lett. 141(2015) 63-66.
[19] N. Kornienko, Y. Zhao, C.S. Kley, C. Zhu, D. Kim, S. Lin, C.J. Chang, O.M. Yaghi, P. Yang, Metal-organic frameworks for electrocatalytic reduction of carbon dioxide, J. Am. Chem. Soc. 137(44) (2015) 14129-14135.
[20] R.L. Dongwei Du, H. Wang, J. Humphreys, S. Tao, Achieving both high selectivity and current density for CO₂ reduction to formate on nanoporous tin foam electrocatalysts, ChemistrySelect 1(2016) 1711-1715.
[21] Z. Bian, A. Li, R. He, H. Song, X. Chen, J. Zhou, Z. Ma, Metal-organic frameworktemplated porous SnO/C polyhedrons for high-performance lithium-ion batteries, Electrochim. Acta 289(2018) 389-396.
[22] J.W. Maina, C. Pozo-Gonzalo, J.A. Schütz, J. Wang, L.F. Dumée, Tuning CO₂ conversion product selectivity of metal organic frameworks derived hybrid carbon photoelectrocatalytic reactors, Carbon 148(2019) 80-90.
[23] J.W. Maina, J.A. Schütz, L. Grundy, E. Des Ligneris, Z. Yi, L. Kong, C. PozoGonzalo, M. Ionescu, L.F. Dumée, Inorganic nanoparticles/metal organic framework hybrid membrane reactors for efficient photocatalytic conversion of CO₂, ACS Appl. Mater. Interfaces 9(40) (2017) 35010-35017.
[24] S. Hu, M. Liu, F. Ding, C. Song, G. Zhang, X. Guo, Hydrothermally stable MOFs for CO₂ hydrogenation over iron-based catalyst to light olefins, J. CO₂ Util. 15(2016) 89-95.
[25] K. Gong, F. Du, Z. Xia, M. Durstock, L. Dai, Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction, Science 323(5915) (2009) 760-764.
[26] C. Liang, Z. Li, S. Dai, Mesoporous carbon materials:Synthesis and modification, Angew. Chem. Int. Ed. Engl. 47(20) (2008) 3696-3717.
[27] S. Gadipelli, Z.X. Guo, Tuning of ZIF-Derived carbon with high activity, nitrogen functionality, and yield-A case for superior CO₂ capture, ChemSusChem 8(12) (2015) 2123-2132.
[28] Z.-H. Sheng, L. Shao, J.-J. Chen, W.-J. Bao, F.-B. Wang, X.-H. Xia, W.-J. Bao, F.-B. Wang, X.-H. Xia, Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis, ACS Nano 5(6) (2011) 4350-4358.
[29] F. Gai, D. Zhu, Y. Wu, X. Zhao, C. Liang, Z. Liu, Y. Liu, T. Wang, Tailored N-doped porous carbons via a MOF assembly process for high-performance CO₂ uptake, Mater. Adv. 2(2) (2021) 692-699.
[30] Q. Wang, W. Xia, W. Guo, L.i. An, D. Xia, R. Zou, Functional zeolitic-imidazolateframework-templated porous carbon materials for CO₂ capture and enhanced capacitors, Chem. Asian J. 8(8) (2013) 1879-1885.
[31] F. Xu, M. Minniti, P. Barone, A. Sindona, A. Bonanno, A. Oliva, Nitrogen doping of single walled carbon nanotubes by low energy N₂+ ion implantation, Carbon 46(2008) 1489-1496.
[32] Q. Wang, Y. Ji, Y. Lei, Y. Wang, Y. Wang, Y. Li, S. Wang, Pyridinic-N-dominated doped defective graphene as a superior oxygen electrocatalyst for ultrahighenergy-density Zn-Air batteries, ACS Energy Lett. 3(5) (2018) 1183-1191.
[33] D. Guo, R. Shibuya, C. Akiba, S. Saji, T. Kondo, J. Nakamura, Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts, Science 351(6271) (2016) 361-365.
[34] K.K. Yoshio Hori, S. Suzuki, Production of CO and CH₄ in electrochemical reduction of CO₂ at metal electrodes in aqueous hydrogencarbonate solution, Chem. Lett. (1985) 1695-1698.
[35] T.A.F. Koleli, N. Palamut, A.M. Gizir, R. Aydin, C.H. Hamann, Electrochemical reduction of CO₂ at Pb- and Sn-electrodes in a fixed-bed reactor in aqueous K₂CO₃ and KHCO₃ media, J. Appl. Electrochem. 33(2003) 447-450.
[36] Y. Chen, M.W. Kanan, Tin oxide dependence of the CO₂ reduction efficiency on tin electrodes and enhanced activity for tin/tin oxide thin-film catalysts, J. Am. Chem. Soc. 134(4) (2012) 1986-1989.
[37] F. Li, L. Chen, G.P. Knowles, D.R. MacFarlane, J. Zhang, Hierarchical mesoporous SnO₂ nanosheets on carbon cloth:A robust and flexible electrocatalyst for CO₂ reduction with high efficiency and selectivity, Angew. Chem. Int. Ed. Engl. 56(2017) 505-509.
[38] H. Hu, L. Gui, W. Zhou, J. Sun, J. Xu, Q. Wang, B. He, L. Zhao, Partially reduced Sn/SnO₂ porous hollow fiber:A highly selective, efficient and robust electrocatalyst towards carbon dioxide reduction, Electrochim. Acta 285(2018) 70-77.
[39] B. Kumar, V. Atla, J.P. Brian, S. Kumari, T.Q. Nguyen, M. Sunkara, J.M. Spurgeon, Reduced SnO₂ porous nanowires with a high density of grain boundaries as catalysts for efficient electrochemical CO₂ -into-HCOOH conversion, Angew. Chem. Int. Ed. Engl. 56(13) (2017) 3645-3649.
[40] F. Li, L. Chen, M. Xue, T. Williams, Y. Zhang, D.R. MacFarlane, J. Zhang, Towards a better Sn:Efficient electrocatalytic reduction of CO₂ to formate by Sn/SnS₂ derived from SnS₂ nanosheets, Nano Energy 31(2017) 270-277.
[41] D.H. Won, C.H. Choi, J. Chung, M.W. Chung, E.-H. Kim, S.I. Woo, Rational design of a hierarchical tin dendrite electrode for efficient electrochemical reduction of CO₂, ChemSusChem 8(18) (2015) 3092-3098.
[42] S. Zhang, P. Kang, T.J. Meyer, Nanostructured tin catalysts for selective electrochemical reduction of carbon dioxide to formate, J. Am. Chem. Soc. 136(5) (2014) 1734-1737.
[43] S. Bashir, S.S. Hossain, S.U. Rahman, S. Ahmed, A.-A. Amir, M.M. Hossain, Electrocatalytic reduction of carbon dioxide on SnO₂/MWCNT in aqueous electrolyte solution, J. CO₂ Util. 16(2016) 346-353.

Catalytic hydrogenation performance of ZIF-8 carbide for electrochemical reduction of carbon dioxide

Catalytic hydrogenation performance of ZIF-8 carbide for electrochemical reduction of carbon dioxide

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