Column adsorption of Cu(Ⅱ) by polymer-supported nano-iron oxides in the presence of sulfate:Experimental and mathematical modeling

doi:10.1016/j.cjche.2017.01.011

›› 2017, Vol. 25 ›› Issue (9): 1163-1169.DOI: 10.1016/j.cjche.2017.01.011

• Separation Science and Engineering • 上一篇下一篇

Column adsorption of Cu(Ⅱ) by polymer-supported nano-iron oxides in the presence of sulfate:Experimental and mathematical modeling

Hui Qiu^1,2, Xiaolin Zhang², Zhe Xu²

1 Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET), School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China;
2 State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

收稿日期:2016-10-26 修回日期:2017-01-24 出版日期:2017-09-28 发布日期:2017-10-11
通讯作者: Xiaolin Zhang,E-mail:XLZhang@nju.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (21607080), the Natural Science Foundation of Jiangsu Province (BK20160946) and Jiangsu Higher Education Institution NSF (16KJB610011).

Column adsorption of Cu(Ⅱ) by polymer-supported nano-iron oxides in the presence of sulfate:Experimental and mathematical modeling

Hui Qiu^1,2, Xiaolin Zhang², Zhe Xu²

1 Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET), School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China;
2 State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

Received:2016-10-26 Revised:2017-01-24 Online:2017-09-28 Published:2017-10-11
Supported by:
Supported by the National Natural Science Foundation of China (21607080), the Natural Science Foundation of Jiangsu Province (BK20160946) and Jiangsu Higher Education Institution NSF (16KJB610011).

摘要/Abstract

摘要： Polymer-supported hydrous iron oxides (HFOs) are promising for heavy metals removal from aqueous systems. The ubiquitous inorganic ligands, e.g., sulfate, are expected to exert considerable impacts on pollutants removal by these hybrid sorbents. Herein, we obtained a hybrid sorbent HFO-PS by encapsulating nanosized HFO into macroporous polystyrene (PS) resin. Both batch and column sorption experiments of Cu(Ⅱ) by HFO-PS were carried out in the presence of sulfate. Obviously, the presence of sulfate is favorable for Cu(Ⅱ) sorption onto HFO-PS. The performances of column Cu(Ⅱ) removal were fitted and predicted with Adams-Bohart, Clark, Thomas and BDST models. Thomas model is suggested best-fit to predict the breakthrough curves. Besides, a linear correlation is observed between breakthrough time and column length based on BDST model, which might be useful for predicting the breakthrough time for Cu(Ⅱ) removal by HFO-PS.

关键词: Composite, Nanotechnology, Waste water, Hydrous iron oxide, Fixed-bed adsorption, Thomas model

Abstract: Polymer-supported hydrous iron oxides (HFOs) are promising for heavy metals removal from aqueous systems. The ubiquitous inorganic ligands, e.g., sulfate, are expected to exert considerable impacts on pollutants removal by these hybrid sorbents. Herein, we obtained a hybrid sorbent HFO-PS by encapsulating nanosized HFO into macroporous polystyrene (PS) resin. Both batch and column sorption experiments of Cu(Ⅱ) by HFO-PS were carried out in the presence of sulfate. Obviously, the presence of sulfate is favorable for Cu(Ⅱ) sorption onto HFO-PS. The performances of column Cu(Ⅱ) removal were fitted and predicted with Adams-Bohart, Clark, Thomas and BDST models. Thomas model is suggested best-fit to predict the breakthrough curves. Besides, a linear correlation is observed between breakthrough time and column length based on BDST model, which might be useful for predicting the breakthrough time for Cu(Ⅱ) removal by HFO-PS.

Key words: Composite, Nanotechnology, Waste water, Hydrous iron oxide, Fixed-bed adsorption, Thomas model

Hui Qiu, Xiaolin Zhang, Zhe Xu. Column adsorption of Cu(Ⅱ) by polymer-supported nano-iron oxides in the presence of sulfate:Experimental and mathematical modeling[J]. , 2017, 25(9): 1163-1169.

参考文献

[1] I. Ali, New generation adsorbents for water treatment, Chem. Rev. 112(2012) 5073-5091.
[2] D.J. Cain, M.N. Croteau, C.C. Fuller, Dietary bioavailability of Cu adsorbed to colloidal hydrous ferric oxide, Environ. Sci. Technol. 47(2013) 2869-2876.
[3] C. Dai, Y.D. Hu, Fe (Ⅲ) hydroxide nucleation and growth on quartz in the presence of Cu (Ⅱ), Pb (Ⅱ), and Cr (Ⅲ):Metal hydrolysis and adsorption, Environ. Sci. Technol. 49(2015) 292-300.
[4] S. Dulnee, A.C. Scheinost, Surface reaction of snⅡ on goethite (α-FeOOH):Surface complexation, redox reaction, reductive dissolution, and phase transformation, Environ. Sci. Technol. 48(2014) 9341-9348.
[5] H. Foerstendorf, N. Jordan, K. Heim, Probing the surface speciation of uranium (VI) on iron (hydr) oxides by in situ ATR FT-IR spectroscopy, J. Colloid Interface Sci. 416(2014) 133-138.
[6] A.V. Vitela-Rodriguez, J.R. Rangel-Mendez, Arsenic removal by modified activated carbons with iron hydro (oxide) nanoparticles, J. Environ. Manag. 114(2013) 225-231.
[7] R.Y. Li, L.B. Zhang, P. Wang, Rational design of nanomaterials for water treatment, Nano 7(2015) 17167-17194.
[8] H. Qiu, C. Liang, X.L. Zhang, M.D. Chen, Y.X. Zhao, T. Tao, Z.W. Xu, G. Liu, Fabrication of a biomass-based hydrous zirconium oxide nanocomposite for preferable phosphate removal and recovery, ACS Appl. Mater. Interfaces 7(2015) 20835-20844.
[9] S.J. Tesh, T.B. Scott, Nano-composites for water remediation:A review, Adv. Mater. 26(2014) 6056-6068.
[10] L.C. Oliveira, D.I. Petkowicz, A. Smaniotto, S.B. Pergher, Magnetic zeolites:A new adsorbent for removal of metallic contaminants from water, Water Res. 38(2004) 3699-3704.
[11] S.F. Lim, Y.M. Zheng, S.W. Zou, J.P. Chen, Characterization of copper adsorption onto an alginate encapsulated magnetic sorbent by a combined FT-IR, XPS, and mathematical modeling study, Environ. Sci. Technol. 42(2008) 2551-2556.
[12] J.A. Arcibar-Orozco, M. Avalos-Borja, J.R. Rangel-Mendez, Effect of phosphate on the particle size of ferric oxyhydroxides anchored onto activated carbon:As (V) removal from water, Environ. Sci. Technol. 46(2012) 9577-9583.
[13] O. Hakami, Y. Zhang, C.J. Banks, Thiol-functionalised mesoporous silica-coated magnetite nanoparticles for high efficiency removal and recovery of Hg from water, Water Res. 46(2012) 3913-3922.
[14] H. Qiu, S.J. Zhang, B.C. Pan, W.M. Zhang, L. Lv, Oxalate-promoted dissolution of hydrous ferric oxide immobilized within nanoporous polymers:Effect of ionic strength and visible light irradiation, Chem. Eng. J. 232(2013) 167-173.
[15] M. Hua, Y.N. Jiang, B. Wu, B.C. Pan, X. Zhao, Q.X. Zhang, Oxalate-promoted dissolution of hydrous ferric oxide immobilized within nanoporous polymers:Effect of ionic strength and visible light irradiation, ACS Appl. Mater. Interfaces 5(2013) 12135-12142.
[16] B.C. Pan, F.C. Han, G.Z. Nie, B. Wu, K. He, L. Lv, New strategy to enhance phosphate removal from water by hydrous manganese oxide, Environ. Sci. Technol. 48(2014) 5101-5107.
[17] L. Cumbal, A.K. SenGupta, Arsenic removal using polymer-supported hydrated iron (Ⅲ) oxide nanoparticles:Role of Donnan membrane effect, Environ. Sci. Technol. 39(2005) 6508-6515.
[18] G.Z. Nie, B.C. Pan, S.J. Zhang, B.J. Pan, Surface chemistry of nanosized hydrated ferric oxide encapsulated inside porous polymer:Modeling and experimental studies, J. Phys. Chem. C 117(2013) 6201-6209.
[19] M. Komárek, A. Vaněk, V. Ettler, Chemical stabilization of metals and arsenic in contaminated soils using oxides-A review, Environ. Pollut. 172(2013) 9-22.
[20] M.A.G. Hinkle, Z.M. Wang, D.E. Giammar, J.G. Catalano, Interaction of Fe (Ⅱ) with phosphate and sulfate on iron oxide surfaces, Geochim. Cosmochim. Acta 158(2015) 130-146.
[21] M.A. Ali, D.A. Dzombak, Interactions of copper, organic acids, and sulfate in goethite suspensions, Geochim. Cosmochim. Acta 60(1996) 5045-5053.
[22] D.A. Beattie, J.K. Chapelet, M. Grafe, W.M. Skinner, E. Smith, Interactions of copper, organic acids, and sulfate in goethite suspensions, Environ. Sci. Technol. 42(2008) 9191-9196.
[23] Z.M. Jiang, L. Lv, W.M. Zhang, Q. Du, B.C. Pan, L. Yang, Q.X. Zhang, Nitrate reduction using nanosized zero-valent iron supported by polystyrene resins:Role of surface functional groups, Water Res. 45(2011) 2191-2198.
[24] H. Qiu, S.J. Zhang, B.C. Pan, W.M. Zhang, L. Lv, Effect of sulfate on Cu (Ⅱ) sorption to polymer-supported nano-iron oxides:Behavior and XPS study, J. Colloid Interface Sci. 366(2012) 37-43.
[25] C.F. Baes, R.E. Mesmer, The Hydrolysis of Cations, Wiley, New York, 1976.
[26] G. Bohart, E. Adams, Some aspects of the behavior of charcoal with respect to chlorine. 1, J. Am. Chem. Soc. 42(1920) 523-544.
[27] R.M. Clark, Evaluating the cost and performance of field-scale granular activated carbon systems, Environ. Sci. Technol. 21(1987) 573-580.
[28] V.C. Srivastava, B. Prasad, I.M. Mishra, I.D. Mall, M.M. Swamy, Prediction of breakthrough curves for sorptive removal of phenol by bagasse fly ash packed bed, Ind. Eng. Chem. Res. 47(2008) 1603-1613.
[29] H.C. Thomas, Heterogeneous ion exchange in a flowing system, J. Am. Chem. Soc. 66(1944) 1664-1666.
[30] C.B. Lopes, E. Pereira, Z. Lin, P. Pato, M. Otero, C.M. Silva, J. Rocha, A.C. Duarte, Fixedbed removal of Hg²⁺ from contaminated water by microporous titanosilicate ETS-4:Experimental and theoretical breakthrough curves, Microporous Mesoporous Mater. 145(2011) 32-40.
[31] G.M. Walker, L.R. Weatherley, Adsorption of acid dyes on to granular activated carbon in fixed beds, Water Res. 31(1997) 2093-2101.
[32] N. Savage, M.S. Diallo, Nanomaterials and water purification:Opportunities and challenges, J. Nanopart. Res. 7(2005) 331-342.
[33] B.J. Pan, J. Wu, B.C. Pan, L. Lv, W.M. Zhang, L.L. Xiao, X.S. Wang, X.C. Tao, S.R. Zheng, Development of polymer-based nanosized hydrated ferric oxides (HFOs) for enhanced phosphate removal from waste effluents, Water Res. 43(2009) 4421-4429.
[34] A.C. Scheinost, S. Abend, K.I. Pandya, D.L. Sparks, Kinetic controls on Cu and Pb sorption by ferrihydrite, Environ. Sci. Technol. 35(2001) 1090-1096.
[35] K. Yang, B.S. Xing, Adsorption of organic compounds by carbon nanomaterials in aqueous phase:Polanyi theory and its application, Chem. Rev. 110(2010) 5989-6008.
[36] A. Sperlich, A. Werner, A. Genz, G. Amy, E. Worch, M. Jekel, Breakthrough behavior of granular ferric hydroxide (GFH) fixed-bed adsorption filters:Modeling and experimental approaches, Water Res. 39(2005) 1190-1198.
[37] J.Y. Song, W.H. Zou, Y.Y. Bian, F.Y. Su, R.P. Han, Adsorption characteristics of methylene blue by peanut husk in batch and column modes, Desalination 265(2011) 119-125.
[38] J.L. Sotelo, G. Ovejero, A. Rodríguez, S. Álvarez, J. García, Removal of atenolol and isoproturon in aqueous solutions by adsorption in a fixed-bed column, Ind. Eng. Chem. Res. 51(2012) 5045-5055.
[39] W.X. Zhang, L. Dong, H. Yan, H.J. Li, Z.W. Jiang, X.W. Kan, H. Yang, A.M. Li, R.S. Cheng, Removal of methylene blue from aqueous solutions by straw based adsorbent in a fixed-bed column, Chem. Eng. J. 173(2011) 429-436.

Column adsorption of Cu(Ⅱ) by polymer-supported nano-iron oxides in the presence of sulfate:Experimental and mathematical modeling

Column adsorption of Cu(Ⅱ) by polymer-supported nano-iron oxides in the presence of sulfate:Experimental and mathematical modeling

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Yingli Li, Zhishuncheng Li, Guangfei Qu, Rui Li, Shuaiyu Liang, Junhong Zhou, Wei Ji, Huiming Tang. Mechanism, behaviour and application of iron nitrate modified carbon nanotube composites for the adsorption of arsenic in aqueous solutions[J]. 中国化学工程学报, 2023, 60(8): 26-36.
[2]	Bo Yu, Guang Fu, Xinpei Li, Libo Zhang, Jing Li, Hongtao Qu, Dongbin Wang, Qingfeng Dong, Mengmeng Zhang. Arsenic removal from acidic industrial wastewater by ultrasonic activated phosphorus pentasulfide[J]. 中国化学工程学报, 2023, 60(8): 46-52.
[3]	Jiahao Lu, Zhimeng Wang, Qi Zhang, Cheng Sun, Yanyan Zhou, Sijia Wang, Xiangyun Qiu, Shoudong Xu, Rentian Chen, Tao Wei. The effects of amino groups and open metal sites of MOFs on polymer-based electrolytes for all-solid-state lithium metal batteries[J]. 中国化学工程学报, 2023, 60(8): 80-89.
[4]	Yafei Su, Xuke Zhang, Hui Li, Donglai Peng, Yatao Zhang. In-situ incorporation of halloysite nanotubes with 2D zeolitic imidazolate framework-L based membrane for dye/salt separation[J]. 中国化学工程学报, 2023, 58(6): 103-111.
[5]	Shanghong Ma, Haitao Zhang, Jianbo Qu, Xiuzhong Zhu, Qingfei Hu, Jianyong Wang, Peng Ye, Futao Sai, Shiwei Chen. Preparation of waterborne polyurethane/β-cyclodextrin composite nanosponge by ion condensation method and its application in removing of dyes from wastewater[J]. 中国化学工程学报, 2023, 58(6): 124-136.
[6]	Jianhui Zhou, Xin Lai, Jianfeng Hu, Haijie Qi, Shan Liu, Zhengguo Zhang. Design of a graphene oxide@melamine foam/polyaniline@erythritol composite phase change material for thermal energy storage[J]. 中国化学工程学报, 2023, 58(6): 282-290.
[7]	Yanli Zhang, Zhengkun Hou, Dong Yao, Xiaomin Qiu, Hongru Zhang, Peizhe Cui, Yinglong Wang, Jun Gao, Zhaoyou Zhu, Limei Zhong. Energy, exergy, economic and environmental comprehensive analysis and multi-objective optimization of a sustainable zero liquid discharge integrated process for fixed-bed coal gasification wastewater[J]. 中国化学工程学报, 2023, 58(6): 341-354.
[8]	Linlin Su, Meijun Chen, Li Gong, Hua Yang, Chao Chen, Jun Wu, Ling Luo, Gang Yang, Lulu Long. Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties[J]. 中国化学工程学报, 2023, 57(5): 88-97.
[9]	Chi-Hui Tsou, Rui Zeng, Neng Wan, Manuel Reyes De Guzman, Xue-Fei Hu, Tao Yang, Chen Gao, Xiaomei Wei, Jia Yi, Li Lan, Rui-Tao Yang, Ya-Li Sun. Biological oyster shell waste enhances polyphenylene sulfide composites and endows them with antibacterial properties[J]. 中国化学工程学报, 2023, 57(5): 118-131.
[10]	Iltaf Khan, Chunjuan Wang, Shoaib Khan, Jinyin Chen, Aftab Khan, Sayyar Ali Shah, Aihua Yuan, Sohail Khan, Mehwish K. Butt, Humaira Asghar. Bio-capped and green synthesis of ZnO/g-C₃N₄ nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation[J]. 中国化学工程学报, 2023, 56(4): 215-224.
[11]	Chao Yang, Zhelin Su, Yeshuang Wang, Huiling Fan, Meisheng Liang, Zhaohui Chen. Insight into the effect of gel drying temperature on the structure and desulfurization performance of ZnO/SiO₂ adsorbents[J]. 中国化学工程学报, 2023, 56(4): 233-241.
[12]	Jiaxin Wu, Chenxiao Wang, Xianliang Meng, Haichen Liu, Ruizhi Chu, Guoguang Wu, Weisong Li, Xiaofeng Jiang, Deguang Yang. Enhancement of catalytic and anti-carbon deposition performance of SAPO-34/ZSM-5/quartz films in MTA reaction by Si/Al ratio regulation[J]. 中国化学工程学报, 2023, 56(4): 314-324.
[13]	Hongzhi Zhang, Huiyan Guo, Yang Liu, Chengxiang Shi, Lun Pan, Xiangwen Zhang, Ji-Jun Zou. Thixotropic composite hydrogels based on agarose and inorganic hybrid gellants[J]. 中国化学工程学报, 2023, 54(2): 240-247.
[14]	Qingyue Han, Suqing Wang, Wenhan Kong, Bing Ji, Haihui Wang. Composite polymer electrolyte reinforced by graphitic carbon nitride nanosheets for room-temperature all-solid-state lithium batteries[J]. 中国化学工程学报, 2023, 54(2): 257-263.
[15]	Aiqin Gao, Xiang Luo, Huanghuang Chen, Aiqin Hou, Hongjuan Zhang, Kongliang Xie. Design of the reactive dyes containing large planar multi-conjugated systems and their application in non-aqueous dyeing[J]. 中国化学工程学报, 2023, 54(2): 264-271.