SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (10): 2102-2111.DOI: 10.1016/j.cjche.2018.09.010

• Process Systems Engineering and Process Safety • 上一篇    下一篇

Investigation on and industrial application of degrading of methanol feed in methanol to propylene process

Lixiang Jiang1,2,3, Chufu Li4, Ming Xu4, Aihua Xing4, Rui Feng1, Jianjun Wu1   

  1. 1 China University of Mining and Technology, Xuzhou 221116, China;
    2 China Energy Investment Corporation Limited, Beijing 100011, China;
    3 Shenhua Ningmei Coal Group Coal Chemical Industry Company, Yinchuan 750411, China;
    4 National Institute of Clean-and-Low-Carbon Energy, Beijing 102209, China
  • 收稿日期:2018-06-16 修回日期:2018-08-20 出版日期:2018-10-28 发布日期:2018-11-14
  • 通讯作者: Ming Xu,E-mail address:xuming@nicenergy.com
  • 基金资助:

    Supported by the National Key R&D Program of China (2017YFB0601902).

Investigation on and industrial application of degrading of methanol feed in methanol to propylene process

Lixiang Jiang1,2,3, Chufu Li4, Ming Xu4, Aihua Xing4, Rui Feng1, Jianjun Wu1   

  1. 1 China University of Mining and Technology, Xuzhou 221116, China;
    2 China Energy Investment Corporation Limited, Beijing 100011, China;
    3 Shenhua Ningmei Coal Group Coal Chemical Industry Company, Yinchuan 750411, China;
    4 National Institute of Clean-and-Low-Carbon Energy, Beijing 102209, China
  • Received:2018-06-16 Revised:2018-08-20 Online:2018-10-28 Published:2018-11-14
  • Contact: Ming Xu,E-mail address:xuming@nicenergy.com
  • Supported by:

    Supported by the National Key R&D Program of China (2017YFB0601902).

摘要: At present, methanol to propylene (MTP) technology developed by Lurgi Company is adopted for commercial plants and refined methanol with the purity ≥ 99.85 wt% is required as the feed of MTP unit in Lurgi's technology. Therefore, high energy cost for refined methanol production is one of the bottlenecks to improve the economy of MTP technology. Reducing the grade of feed refined methanol may be an effective method to save energy and reduce operation costs in MTP process. In this work, experiments and process simulation were carried out to investigate the influence and feasibility of degrading the methanol feed. Experiments were conducted to investigate the influence of crude methanol feed on conversion and selectivity of MTP reaction as well as the performance of ZSM-5 catalyst. The experimental results showed that degrading the methanol feed had no obvious influence on the conversion and selectivity of MTP reactions and the catalyst deactivation was caused by the carbon accumulation and metals deposition on the active sites. The process simulation results showed that the influence on the conversion and selectivity as well as the stream load of MTP process was negligible if 98mol% methanol was used as feed. Finally, industrial experiments were conducted by adjusting the operation parameters to degrade of feed methanol of the commercial 500 kt·a-1 MTP unit of Ningmei Group in China. The results of industrial application illustrated that annually 180 kt fuel coal and 150 kt desalted water as well as1770 MW·h-1 electricity would be saved when the water content increased from 0.01% to 0.4%. This work has identified the feasibility to improve MTP technology by degrading the methanol feed.

关键词: MTP, Methanol, Distillation, Simulation and optimization, Energy saving

Abstract: At present, methanol to propylene (MTP) technology developed by Lurgi Company is adopted for commercial plants and refined methanol with the purity ≥ 99.85 wt% is required as the feed of MTP unit in Lurgi's technology. Therefore, high energy cost for refined methanol production is one of the bottlenecks to improve the economy of MTP technology. Reducing the grade of feed refined methanol may be an effective method to save energy and reduce operation costs in MTP process. In this work, experiments and process simulation were carried out to investigate the influence and feasibility of degrading the methanol feed. Experiments were conducted to investigate the influence of crude methanol feed on conversion and selectivity of MTP reaction as well as the performance of ZSM-5 catalyst. The experimental results showed that degrading the methanol feed had no obvious influence on the conversion and selectivity of MTP reactions and the catalyst deactivation was caused by the carbon accumulation and metals deposition on the active sites. The process simulation results showed that the influence on the conversion and selectivity as well as the stream load of MTP process was negligible if 98mol% methanol was used as feed. Finally, industrial experiments were conducted by adjusting the operation parameters to degrade of feed methanol of the commercial 500 kt·a-1 MTP unit of Ningmei Group in China. The results of industrial application illustrated that annually 180 kt fuel coal and 150 kt desalted water as well as1770 MW·h-1 electricity would be saved when the water content increased from 0.01% to 0.4%. This work has identified the feasibility to improve MTP technology by degrading the methanol feed.

Key words: MTP, Methanol, Distillation, Simulation and optimization, Energy saving